File name: Pandora120s1_Davos_20241004_L2Fit_fout2c5d20240814p1-8.txt File generation date: 20241127T223735.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v5d20240814.txt Level 1 file used: Pandora120s1_Davos_20241004_L1_smca1c5d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20241004 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1159 305.2573 305.3987 305.5401 305.6814 305.8228 305.9641 306.1054 306.2467 306.3880 306.5293 306.6706 306.8118 306.9531 307.0943 307.2356 307.3768 307.5180 307.6592 307.8004 307.9415 308.0827 308.2239 308.3650 308.5061 308.6473 308.7884 308.9295 309.0706 309.2116 309.3527 309.4938 309.6348 309.7758 309.9169 310.0579 310.1989 310.3399 310.4808 310.6218 310.7627 310.9037 311.0446 311.1855 311.3265 311.4674 311.6082 311.7491 311.8900 312.0308 312.1717 312.3125 312.4533 312.5941 312.7349 312.8757 313.0165 313.1573 313.2980 313.4388 313.5795 313.7202 313.8609 314.0016 314.1423 314.2830 314.4237 314.5643 314.7050 314.8456 314.9862 315.1268 315.2674 315.4080 315.5486 315.6891 315.8297 315.9702 316.1108 316.2513 316.3918 316.5323 316.6728 316.8133 316.9537 317.0942 317.2346 317.3750 317.5155 317.6559 317.7963 317.9366 318.0770 318.2174 318.3577 318.4981 318.6384 318.7787 318.9190 319.0593 319.1996 319.3399 319.4801 319.6204 319.7606 319.9008 320.0410 320.1813 320.3214 320.4616 320.6018 320.7420 320.8821 321.0222 321.1624 321.3025 321.4426 321.5827 321.7227 321.8628 322.0029 322.1429 322.2829 322.4230 322.5630 322.7030 322.8430 322.9829 323.1229 323.2629 323.4028 323.5427 323.6827 323.8226 323.9625 324.1023 324.2422 324.3821 324.5219 324.6618 324.8016 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241004T094918.8Z 9043.409245 1155 1 46.93 2 54.38 155.23 68.74 142.17 0.00 1 0.00 1 0 17 1.575e-02 6.649e-03 1.636e-02 4.679e-03 2.619958e-01 2.293375e-03 3.290875e-03 -6.000000e+00 8.700790e-03 225.62 -2.00 3.62 -2.00 317.57 0.00e+00 3.785927e-04 3.242525e-04 5.999695e-05 -6.000000e+00 3.534476e-04 272.46 -2.00 20.00 -2.00 317.25 0.00e+00 1.712 0.000 302.00 328.00 3 6.5449e+00 6.0446e-03 1.9850e-02 -6.0000e+00 2.1689e-02 6.1681e-02 6.7919e-03 1.3725e-02 -6.0000e+00 2.3718e-02 -6.7527e-03 4.2586e-03 6.8947e-03 -6.0000e+00 1.3958e-02 -6.0402e-04 2.1687e-03 2.0076e-03 -6.0000e+00 5.8964e-03 1.2964e-04 2.0140e-04 1.2885e-04 2.1048e-05 -6.0000e+00 3.9802e-04 9.2255e-03 0.0000e+00 11 8 0 10 0 0 99.94 14.51 0.44 0.00923 0.01074 16 3 1 8 0 2932.730 14.98 14.51 11.24 20.14 20.35 28.7 800.75 12 -127 -9212 -2073 -3050 1172 3718 -1822 5207 -8089 967 757 900 -1161 1756 -542 206 2822 3478 2255 -611 -990 896 -337 -854 -58 1288 -917 -628 2320 -412 2072 -3005 -979 -1506 -1599 -1301 457 809 -1033 -2228 -1085 -1042 675 -1008 -703 -1110 -821 -298 164 426 951 449 465 406 1148 997 902 556 1304 1227 629 2347 528 -649 694 -418 -169 12 671 606 612 215 567 302 -1043 -1674 -998 -1512 -839 -820 -1753 -1231 -791 -254 -157 -242 698 322 1036 567 -384 627 -155 -235 169 1143 484 -144 -641 -204 -708 -453 -1485 -887 -677 -914 433 144 642 383 495 -154 -279 -572 -179 -354 127 -202 145 -424 153 315 428 522 362 1001 166 1496 399 -132 418 106 -188 23 -15 141 66 -628 -217 -306 -448 1 -14 -1085 -202 -268 99 339 -200 581 -1036 110 93 128 -194 321 -108 42 582 736 500 -138 -223 207 -84 -224 -15 322 -229 -148 546 -108 579 -947 -288 -412 -456 -424 176 371 -509 -1172 -582 -567 382 -579 -398 -612 -440 -156 89 248 586 293 315 280 803 700 619 375 885 886 499 1860 437 -538 514 -297 -124 10 584 556 564 193 505 242 -755 -1130 -681 -1168 -729 -792 -1728 -1255 -854 -294 -192 -307 883 397 1176 624 -385 590 -154 -258 194 1441 663 -197 -824 -238 -817 -533 -1820 -1146 -908 -1283 628 223 1053 642 799 -231 -383 -734 -226 -467 180 -306 224 -650 227 446 573 665 461 1262 214 2049 582 -197 629 167 -314 40 -27 259 121 -1137 -375 -507 -724 SS 20241004T095033.6Z 9043.410111 1156 1 49.84 2 54.29 155.60 68.62 142.46 0.00 1 0.00 1 0 17 9.491e-03 5.458e-03 9.533e-03 2.847e-03 2.576210e-01 1.388226e-03 3.204534e-03 -6.000000e+00 5.242579e-03 225.62 -2.00 3.62 -2.00 317.46 0.00e+00 1.030169e-04 1.914003e-04 5.827666e-05 -6.000000e+00 2.129697e-04 272.46 -2.00 20.00 -2.00 317.13 0.00e+00 1.709 0.000 302.00 328.00 3 5.8987e+00 3.6526e-03 1.9602e-02 -6.0000e+00 1.3069e-02 4.7512e-02 4.1095e-03 1.3417e-02 -6.0000e+00 1.4291e-02 -1.8580e-03 2.5573e-03 6.7340e-03 -6.0000e+00 8.4101e-03 -3.6646e-03 1.2962e-03 1.9512e-03 -6.0000e+00 3.5528e-03 2.5188e-04 2.6512e-04 7.8197e-05 2.0193e-05 -6.0000e+00 2.3983e-04 9.3879e-03 0.0000e+00 11 1 0 11 8 0 99.96 14.52 0.08 0.00939 0.01138 26 5 1 8 0 1916.640 15.01 14.52 11.24 20.14 20.35 28.7 800.97 1447 -762 -2593 -932 -1885 990 1926 1636 -622 -1586 721 -1330 -2049 240 -520 299 -689 -1497 -260 2160 468 1754 -367 766 -197 553 -2422 190 203 1326 83 2825 1462 -2643 -1832 -2778 -1346 -122 -44 -623 -1251 -598 -1660 -373 -901 -856 -213 -364 -510 179 -106 710 876 903 1414 884 813 793 1000 624 1452 877 1521 944 41 -114 -890 477 509 270 410 -118 -156 257 207 110 -873 -69 -424 -1114 -591 -1783 -1444 -977 -384 -250 -168 228 139 698 533 -163 869 632 -55 53 975 -112 -162 -162 -431 -218 -20 -776 -1224 -554 -562 -6 101 180 -61 373 -295 -103 153 166 370 161 -217 -248 271 385 347 480 47 263 1029 375 535 213 -75 -117 131 97 40 129 98 -201 -230 34 -681 -354 149 -84 -287 -95 -175 89 191 186 -79 -204 88 -179 -320 42 -104 63 -150 -342 -61 509 111 409 -91 201 -55 156 -671 47 48 316 22 784 440 -791 -503 -802 -439 -47 -21 -326 -695 -340 -968 -213 -518 -486 -116 -194 -269 97 -62 439 569 608 965 621 573 545 673 427 1049 695 1292 827 34 -85 -635 347 423 251 400 -116 -150 230 166 79 -585 -47 -324 -972 -569 -1867 -1567 -1061 -446 -308 -214 291 172 799 587 -163 817 624 -60 62 1236 -154 -222 -208 -505 -251 -24 -950 -1597 -747 -791 -9 158 283 -98 606 -447 -142 196 210 488 228 -332 -389 416 573 496 648 61 337 1304 486 746 314 -113 -179 207 163 66 222 172 -356 -396 57 -1145 -579 SS 20241004T102154.2Z 9043.431877 1291 1 49.79 2 52.49 165.07 65.81 149.96 0.00 1 0.00 1 0 17 9.955e-03 5.591e-03 7.923e-03 2.443e-03 2.472181e-01 1.199035e-03 3.110671e-03 -6.000000e+00 5.499113e-03 225.62 -2.00 3.62 -2.00 317.50 0.00e+00 4.980784e-05 1.643981e-04 5.386306e-05 -6.000000e+00 2.233823e-04 272.46 -2.00 20.00 -2.00 317.17 0.00e+00 1.639 0.000 302.00 328.00 3 5.3618e+00 3.1537e-03 1.8858e-02 -6.0000e+00 1.3708e-02 4.2010e-02 3.5440e-03 1.2948e-02 -6.0000e+00 1.4990e-02 -2.8948e-04 2.1923e-03 6.5025e-03 -6.0000e+00 8.8214e-03 -5.0376e-03 1.1057e-03 1.8930e-03 -6.0000e+00 3.7268e-03 4.6578e-04 2.3765e-04 6.7635e-05 1.9891e-05 -6.0000e+00 2.5155e-04 8.8562e-03 0.0000e+00 10 0 0 10 0 0 99.99 14.57 0.20 0.00886 0.01064 101 21 1 8 0 492.840 15.01 14.57 11.45 20.14 20.46 28.7 801.87 -603 -2503 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