File name: Pandora120s1_Davos_20241117_L2Fit_fwvt1c4d20240814p1-8.txt File generation date: 20241119T083305.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v4d20240814.txt Level 1 file used: Pandora120s1_Davos_20241117_L1_smca1c4d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20241117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0962 492.2181 492.3399 492.4618 492.5836 492.7054 492.8272 492.9490 493.0708 493.1925 493.3143 493.4360 493.5577 493.6794 493.8010 493.9227 494.0443 494.1659 494.2875 494.4091 494.5307 494.6522 494.7738 494.8953 495.0168 495.1383 495.2597 495.3812 495.5026 495.6240 495.7454 495.8668 495.9882 496.1096 496.2309 496.3522 496.4735 496.5948 496.7161 496.8373 496.9585 497.0798 497.2010 497.3221 497.4433 497.5645 497.6856 497.8067 497.9278 498.0489 498.1700 498.2910 498.4120 498.5331 498.6541 498.7750 498.8960 499.0170 499.1379 499.2588 499.3797 499.5006 499.6215 499.7423 499.8631 499.9840 500.1048 500.2255 500.3463 500.4670 500.5878 500.7085 500.8292 500.9499 501.0705 501.1912 501.3118 501.4324 501.5530 501.6736 501.7942 501.9147 502.0352 502.1557 502.2762 502.3967 502.5172 502.6376 502.7581 502.8785 502.9989 503.1192 503.2396 503.3599 503.4803 503.6006 503.7209 503.8411 503.9614 504.0816 504.2019 504.3221 504.4423 504.5624 504.6826 504.8027 504.9229 505.0430 505.1631 505.2831 505.4032 505.5232 505.6432 505.7632 505.8832 506.0032 506.1232 506.2431 506.3630 506.4829 506.6028 506.7227 506.8425 506.9623 507.0822 507.2020 507.3217 507.4415 507.5613 507.6810 507.8007 507.9204 508.0401 508.1598 508.2794 508.3990 508.5186 508.6382 508.7578 508.8774 508.9969 509.1164 509.2360 509.3554 509.4749 509.5944 509.7138 509.8332 509.9527 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241117T081439.6Z 9087.343514 281 1 13.16 2 76.36 138.70 87.51 307.49 0.00 1 0.00 1 0 8 2.631e-03 2.610e-03 1.438e-04 1.436e-04 7.852700e+02 7.478825e+00 6.875041e+01 -6.000000e+00 1.344716e+02 266.22 -2.00 20.00 -2.00 505.25 0.00e+00 4.866868e-04 3.767200e-06 2.788008e-05 -6.000000e+00 7.051118e-05 266.22 -2.00 20.00 -2.00 500.44 0.00e+00 3.350365e-01 2.813365e-03 6.948115e-03 -6.000000e+00 5.189673e-02 221.28 -2.00 3.62 -2.00 502.04 0.00e+00 4.147 0.001 489.00 513.00 1 8.5314e-03 2.1438e-04 4.9516e-03 -6.0000e+00 3.9542e-03 2.0348e-04 5.6179e-05 3.0833e-04 -6.0000e+00 1.0366e-03 1.1602e+00 1.2423e-04 1.3239e-05 1.4314e-05 -6.0000e+00 2.4745e-04 -1.5301e-02 -4.9466e-05 10 0 0 10 0 0 12.09 13.76 0.33 -0.01530 -0.01444 545 130 5 2 0 23.360 14.99 13.76 5.19 19.54 19.75 29.4 779.10 -577 -405 -27 150 208 538 516 431 414 176 163 -4 -160 -157 -289 -236 -69 136 221 37 162 155 103 221 217 205 201 144 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310 172 40 63 280 132 249 342 186 210 421 197 65 -21 -237 -292 -56 -40 -71 138 192 116 147 166 140 175 114 -49 -293 -477 -475 SQ 20241117T081453.2Z 9087.343671 281 2 13.32 2 76.34 138.75 87.54 307.53 0.00 1 0.00 1 0 8 2.630e-03 2.607e-03 1.437e-04 1.434e-04 8.060356e+02 7.488595e+00 7.084689e+01 -6.000000e+00 1.344150e+02 266.22 -2.00 20.00 -2.00 505.25 0.00e+00 4.843147e-04 3.762804e-06 2.768558e-05 -6.000000e+00 7.048145e-05 266.22 -2.00 20.00 -2.00 500.44 0.00e+00 3.375749e-01 2.811976e-03 7.004677e-03 -6.000000e+00 5.187512e-02 221.28 -2.00 3.62 -2.00 502.03 0.00e+00 4.139 0.001 489.00 513.00 1 7.2293e-03 2.1428e-04 4.9434e-03 -6.0000e+00 3.9525e-03 9.5620e-05 5.6118e-05 3.0961e-04 -6.0000e+00 1.0362e-03 1.1625e+00 1.1485e-04 1.3220e-05 1.4373e-05 -6.0000e+00 2.4735e-04 -1.5112e-02 -5.1066e-05 10 0 0 10 0 0 6.42 13.76 0.33 -0.01511 -0.01432 545 130 5 2 0 23.360 14.99 13.76 5.38 19.54 19.75 29.4 779.10 -581 -362 -1 158 199 496 492 409 442 164 166 12 -164 -186 -249 -201 -61 157 189 60 150 139 60 225 192 203 208 138 -281 -410 -432 -501 -99 284 103 72 84 -53 -159 -91 -60 3 122 227 259 242 214 95 26 -313 -406 -645 -700 -377 -121 -20 111 122 92 82 240 201 233 249 94 31 -109 -150 -348 -424 -342 -393 -125 96 -63 -210 -298 -265 -352 -300 -177 -270 -137 66 -31 -25 79 -68 -13 -23 167 243 257 214 265 51 -145 -165 -469 -623 -579 -417 -17 -45 -149 -64 -290 -296 -183 -141 -25 149 271 287 358 447 421 340 309 193 33 51 279 147 245 329 169 204 402 183 54 -27 -264 -262 -47 -43 -47 147 214 147 144 160 137 177 111 -34 -293 -492 -525 -567 -361 -1 162 203 515 519 435 468 172 171 12 -165 -191 -254 -207 -62 163 201 62 156 145 62 236 201 213 217 146 -289 -409 -427 -501 -102 292 109 76 88 -55 -162 -92 -60 3 126 237 272 254 222 97 26 -315 -397 -620 -673 -369 -122 -21 113 124 93 83 245 207 239 255 95 31 -107 -150 -345 -416 -335 -388 -122 94 -62 -203 -291 -257 -340 -290 -173 -257 -132 64 -30 -24 78 -67 -13 -23 168 242 257 213 259 50 -141 -156 -450 -594 -543 -404 -17 -45 -148 -63 -280 -292 -177 -138 -24 150 276 294 357 447 421 348 311 191 32 50 273 145 241 324 166 201 393 178 52 -26 -254 -245 -45 -42 -47 143 210 145 143 160 138 177 110 -33 -286 -472 -504 SQ 20241117T081506.6Z 9087.343827 281 3 13.25 2 76.31 138.80 87.56 307.57 0.00 1 0.00 1 0 8 2.678e-03 2.657e-03 1.437e-04 1.435e-04 8.027536e+02 7.487897e+00 7.054004e+01 -6.000000e+00 1.368893e+02 266.22 -2.00 20.00 -2.00 505.25 0.00e+00 4.914104e-04 3.764272e-06 2.831758e-05 -6.000000e+00 7.177889e-05 266.22 -2.00 20.00 -2.00 500.44 0.00e+00 3.340146e-01 2.813679e-03 7.035087e-03 -6.000000e+00 5.283024e-02 221.28 -2.00 3.62 -2.00 502.03 0.00e+00 4.132 0.001 489.00 513.00 1 8.0306e-03 2.1441e-04 4.9372e-03 -6.0000e+00 4.0253e-03 1.5214e-04 5.6146e-05 3.0892e-04 -6.0000e+00 1.0553e-03 1.1627e+00 8.4195e-05 1.3214e-05 1.4510e-05 -6.0000e+00 2.5190e-04 -1.4932e-02 -5.2458e-05 10 0 0 10 0 0 4.19 13.76 0.33 -0.01493 -0.01435 545 130 5 2 0 23.360 14.99 13.76 5.38 19.54 19.75 29.4 779.10 -576 -396 -27 147 210 514 505 433 441 178 163 -5 -150 -167 -271 -208 -86 145 221 47 126 115 72 234 218 246 199 124 -307 -434 -440 -519 -107 314 100 90 93 -57 -155 -90 -54 26 169 257 258 276 230 93 4 -326 -442 -636 -692 -376 -149 -50 68 100 127 92 242 194 227 241 121 35 -97 -184 -338 -407 -332 -354 -132 41 -81 -242 -276 -250 -340 -309 -174 -236 -134 54 -78 -42 73 -94 -2 -23 146 242 235 217 280 38 -124 -184 -488 -611 -607 -426 -54 -61 -109 -41 -277 -295 -150 -109 -27 172 241 287 400 450 443 314 302 169 32 77 297 166 246 307 164 202 446 222 76 -23 -268 -297 -35 -46 -64 160 215 128 116 180 146 192 137 -56 -304 -512 -560 -563 -395 -27 151 214 533 533 461 467 186 168 -5 -150 -171 -277 -214 -87 151 235 49 131 120 75 245 229 258 207 131 -316 -433 -435 -520 -110 323 105 95 97 -59 -157 -91 -55 27 175 269 272 290 239 95 4 -329 -433 -612 -665 -369 -151 -51 70 102 129 94 247 199 234 247 123 35 -95 -178 -335 -400 -325 -350 -128 40 -80 -234 -271 -242 -328 -299 -169 -225 -128 52 -77 -41 72 -93 -2 -23 148 240 235 216 274 38 -121 -174 -468 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