File name: Pandora120s1_Davos_20250601_L2Fit_fout2c5d20240814p1-8.txt File generation date: 20250601T232608.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v5d20240814.txt Level 1 file used: Pandora120s1_Davos_20250601_L1_smca1c5d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20250601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1159 305.2573 305.3987 305.5401 305.6814 305.8228 305.9641 306.1054 306.2467 306.3880 306.5293 306.6706 306.8118 306.9531 307.0943 307.2356 307.3768 307.5180 307.6592 307.8004 307.9415 308.0827 308.2239 308.3650 308.5061 308.6473 308.7884 308.9295 309.0706 309.2116 309.3527 309.4938 309.6348 309.7758 309.9169 310.0579 310.1989 310.3399 310.4808 310.6218 310.7627 310.9037 311.0446 311.1855 311.3265 311.4674 311.6082 311.7491 311.8900 312.0308 312.1717 312.3125 312.4533 312.5941 312.7349 312.8757 313.0165 313.1573 313.2980 313.4388 313.5795 313.7202 313.8609 314.0016 314.1423 314.2830 314.4237 314.5643 314.7050 314.8456 314.9862 315.1268 315.2674 315.4080 315.5486 315.6891 315.8297 315.9702 316.1108 316.2513 316.3918 316.5323 316.6728 316.8133 316.9537 317.0942 317.2346 317.3750 317.5155 317.6559 317.7963 317.9366 318.0770 318.2174 318.3577 318.4981 318.6384 318.7787 318.9190 319.0593 319.1996 319.3399 319.4801 319.6204 319.7606 319.9008 320.0410 320.1813 320.3214 320.4616 320.6018 320.7420 320.8821 321.0222 321.1624 321.3025 321.4426 321.5827 321.7227 321.8628 322.0029 322.1429 322.2829 322.4230 322.5630 322.7030 322.8430 322.9829 323.1229 323.2629 323.4028 323.5427 323.6827 323.8226 323.9625 324.1023 324.2422 324.3821 324.5219 324.6618 324.8016 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250601T064506.8Z 9283.281328 143 1 49.52 2 59.46 89.45 107.54 38.31 0.00 1 0.00 1 0 17 1.407e-02 6.538e-03 1.800e-02 4.311e-03 2.836526e-01 2.151615e-03 3.486992e-03 -6.000000e+00 7.941210e-03 231.23 -2.00 3.62 -2.00 317.90 0.00e+00 2.474794e-04 3.230116e-04 7.216361e-05 -6.000000e+00 3.158227e-04 273.49 -2.00 20.00 -2.00 317.55 0.00e+00 1.960 0.000 302.00 328.00 3 6.3283e+00 5.7543e-03 2.2461e-02 -6.0000e+00 2.0057e-02 6.2001e-02 6.4529e-03 1.5190e-02 -6.0000e+00 2.1835e-02 -8.0832e-03 4.1380e-03 7.5098e-03 -6.0000e+00 1.2794e-02 -2.7050e-03 2.1210e-03 2.1347e-03 -6.0000e+00 5.3443e-03 1.2654e-04 1.1794e-04 1.1905e-04 2.1171e-05 -6.0000e+00 3.5594e-04 3.8902e-03 0.0000e+00 11 8 0 10 0 0 99.93 15.33 0.12 0.00389 0.00478 14 3 1 8 0 3536.420 15.01 15.33 21.61 20.77 21.17 32.3 879.45 86 2202 -1100 -1422 2010 2467 5704 2730 -1236 -346 2702 1219 -4930 2616 -3477 664 -729 2465 -103 1575 -2854 3632 2989 -909 -1914 783 1137 1363 -1538 1688 146 -2777 1616 -1796 -1573 -2668 -876 -1214 -1081 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-556 46 136 164 874 280 1106 1404 430 437 94 -538 -521 -17 180 -35 372 369 -4 -234 -122 -1074 -409 SU 20250601T071314.6Z 9283.300864 162 1 18.48 2 54.65 94.70 104.57 44.27 0.00 1 0.00 1 0 17 7.847e-03 5.540e-03 4.815e-03 1.998e-03 2.445196e-01 1.000555e-03 3.036339e-03 -6.000000e+00 4.429507e-03 231.23 -2.00 3.62 -2.00 316.58 0.00e+00 2.687395e-04 1.088396e-04 4.233624e-05 -6.000000e+00 1.761110e-04 273.49 -2.00 20.00 -2.00 316.26 0.00e+00 1.724 0.000 302.00 328.00 3 4.8714e+00 2.6336e-03 1.9536e-02 -6.0000e+00 1.1188e-02 3.0927e-02 2.9392e-03 1.3065e-02 -6.0000e+00 1.2178e-02 -3.8785e-03 1.7304e-03 6.4194e-03 -6.0000e+00 7.1356e-03 -2.2870e-03 8.2978e-04 1.7966e-03 -6.0000e+00 2.9817e-03 7.1378e-04 -1.1594e-05 5.3635e-05 1.8666e-05 -6.0000e+00 1.9844e-04 1.3809e-03 0.0000e+00 12 1 1 12 1 1 99.59 15.56 0.24 0.00138 0.00129 12 7 1 8 0 1402.200 15.01 15.56 23.40 20.96 21.38 32.0 886.74 -998 134 75 -1365 -175 -1588 2089 1021 -744 -1398 -2075 -805 -1508 -1932 -337 -557 197 494 -286 1859 893 1195 -86 482 1073 516 -94 -77 -477 792 504 966 931 -2036 -1398 -1208 -596 -514 -621 -1059 -815 -924 -768 -767 -392 -559 -146 -1053 -452 427 836 918 862 404 847 777 720 785 894 1269 1171 1389 1620 798 -798 123 -608 364 680 126 -23 -201 35 -312 -115 232 -594 279 -397 -1048 -827 -1626 -1050 -846 -776 -497 -347 352 96 334 471 406 812 722 372 296 572 -59 -207 -302 -596 15 30 -671 -922 -677 -671 -119 37 45 4 208 274 9 436 95 544 646 -226 -557 -234 253 -7 956 193 611 1019 304 476 129 -5 169 191 -14 -172 -145 48 -193 -309 -208 -524 -90 -157 22 12 -201 -23 -228 318 163 -132 -252 -366 -149 -322 -476 -92 -162 58 152 -91 603 292 385 -29 173 402 199 -35 -26 -154 257 177 367 379 -822 -516 -460 -257 -245 -354 -683 -554 -598 -505 -502 -255 -391 -99 -697 -292 282 590 636 629 308 653 613 572 610 680 974 953 1230 1434 733 -695 103 -485 295 625 121 -24 -208 35 -295 -105 189 -448 210 -336 -1014 -823 -1757 -1174 -936 -925 -628 -428 434 124 399 510 424 795 734 419 345 739 -77 -273 -400 -721 17 34 -842 -1157 -882 -913 -168 52 67 7 307 400 13 571 123 731 872 -332 -797 -351 366 -9 1251 259 765 1256 404 638 183 -7 247 289 -21 -277 -240 76 -310 -515 -334 -807 -135 SU 20250601T071833.4Z 9283.304553 165 1 49.82 2 53.74 95.72 103.97 45.36 0.00 1 0.00 1 0 17 7.761e-03 5.446e-03 1.116e-03 4.206e-04 2.399244e-01 2.101668e-04 2.980793e-03 -6.000000e+00 4.381305e-03 231.23 -2.00 3.62 -2.00 316.94 0.00e+00 1.426418e-04 2.476406e-05 4.392811e-05 -6.000000e+00 1.741892e-04 273.49 -2.00 20.00 -2.00 316.61 0.00e+00 1.687 0.000 302.00 328.00 3 2.6328e+00 5.5589e-04 1.9155e-02 -6.0000e+00 1.1066e-02 2.1631e-02 6.2079e-04 1.2837e-02 -6.0000e+00 1.2045e-02 -6.1153e-03 3.6884e-04 6.3114e-03 -6.0000e+00 7.0578e-03 -1.9287e-03 1.7865e-04 1.7702e-03 -6.0000e+00 2.9493e-03 6.9985e-03 1.2772e-05 1.1401e-05 1.8442e-05 -6.0000e+00 1.9627e-04 1.0517e-03 0.0000e+00 10 0 0 10 0 0 99.93 15.60 0.23 0.00105 0.00115 420 85 1 8 0 118.600 15.01 15.60 23.89 21.06 21.38 32.8 891.91 -946 -460 -1821 -2878 -2181 -627 450 1219 343 -909 -1315 -544 -266 352 16 -703 310 252 797 717 61 693 741 254 172 188 -107 -195 266 1006 1211 1494 1020 -1779 -1422 -1398 -1072 -548 -565 -1030 -1201 -970 -985 -625 -649 -847 -544 -652 -521 570 635 687 1022 672 986 1049 744 898 812 1075 1484 1133 1334 276 -370 249 -311 824 564 -78 23 -333 182 33 -39 60 -365 214 -381 -955 -854 -1902 -1448 -955 -789 -440 -302 145 175 189 454 382 940 775 361 551 661 68 -200 -137 -343 -65 129 -661 -1005 -695 -660 -100 94 172 -156 132 -68 41 304 490 236 323 -148 -457 -178 227 56 577 369 611 1286 529 339 220 -26 45 146 -31 -105 -80 61 -203 -413 -167 -428 -96 -136 -70 -276 -393 -263 -74 58 178 55 -150 -210 -92 -51 77 4 -186 83 70 228 213 18 203 225 83 59 66 -36 -60 77 293 380 506 372 -642 -471 -478 -417 -255 -286 -589 -728 -604 -624 -392 -407 -526 -326 -380 -297 332 397 456 712 488 726 790 565 667 592 790 1152 961 1219 262 -330 199 -236 633 495 -71 22 -324 171 32 -35 46 -262 154 -308 -879 -871 -1936 -1527 -1065 -948 -560 -400 177 227 228 495 376 942 809 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