File name: Pandora120s1_Davos_20250817_L2Fit_fout2c5d20240814p1-8.txt File generation date: 20250817T233535.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v5d20240814.txt Level 1 file used: Pandora120s1_Davos_20250817_L1_smca1c5d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20250817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1159 305.2573 305.3987 305.5401 305.6814 305.8228 305.9641 306.1054 306.2467 306.3880 306.5293 306.6706 306.8118 306.9531 307.0943 307.2356 307.3768 307.5180 307.6592 307.8004 307.9415 308.0827 308.2239 308.3650 308.5061 308.6473 308.7884 308.9295 309.0706 309.2116 309.3527 309.4938 309.6348 309.7758 309.9169 310.0579 310.1989 310.3399 310.4808 310.6218 310.7627 310.9037 311.0446 311.1855 311.3265 311.4674 311.6082 311.7491 311.8900 312.0308 312.1717 312.3125 312.4533 312.5941 312.7349 312.8757 313.0165 313.1573 313.2980 313.4388 313.5795 313.7202 313.8609 314.0016 314.1423 314.2830 314.4237 314.5643 314.7050 314.8456 314.9862 315.1268 315.2674 315.4080 315.5486 315.6891 315.8297 315.9702 316.1108 316.2513 316.3918 316.5323 316.6728 316.8133 316.9537 317.0942 317.2346 317.3750 317.5155 317.6559 317.7963 317.9366 318.0770 318.2174 318.3577 318.4981 318.6384 318.7787 318.9190 319.0593 319.1996 319.3399 319.4801 319.6204 319.7606 319.9008 320.0410 320.1813 320.3214 320.4616 320.6018 320.7420 320.8821 321.0222 321.1624 321.3025 321.4426 321.5827 321.7227 321.8628 322.0029 322.1429 322.2829 322.4230 322.5630 322.7030 322.8430 322.9829 323.1229 323.2629 323.4028 323.5427 323.6827 323.8226 323.9625 324.1023 324.2422 324.3821 324.5219 324.6618 324.8016 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250817T062334.2Z 9360.266368 235 1 44.57 2 70.31 91.37 20.89 194.89 0.00 1 0.00 1 0 17 7.886e-02 1.560e-02 1.137e-01 1.052e-02 3.853291e-01 5.253604e-03 4.632750e-03 -6.000000e+00 4.442355e-02 231.07 -2.00 3.62 -2.00 319.29 0.00e+00 -2.192372e-04 1.172940e-03 1.570514e-04 -6.000000e+00 1.769649e-03 278.26 -2.00 20.00 -2.00 318.96 0.00e+00 2.936 0.000 302.00 328.00 3 6.3196e+00 1.4365e-02 3.2183e-02 -6.0000e+00 1.1215e-01 9.0143e-02 1.6435e-02 2.0712e-02 -6.0000e+00 1.2216e-01 -2.2977e-02 1.3097e-02 1.0353e-02 -6.0000e+00 7.1594e-02 -3.3233e-05 7.0608e-03 3.0032e-03 -6.0000e+00 2.9873e-02 4.9480e-05 3.4351e-04 2.9493e-04 3.0309e-05 -6.0000e+00 1.9955e-03 1.3540e-02 0.0000e+00 12 9 8 11 8 0 99.95 15.42 0.23 0.01354 0.01612 15 3 1 8 0 2970.370 15.01 15.42 22.53 20.87 21.27 32.6 869.91 -19107 3102 -21016 3339 -20750 35173 3033 45727 -24516 23908 -7412 -5930 -1683 17657 -7095 3633 -7732 14896 15201 -10582 -555 -3034 9194 -10662 16091 -13467 8725 4089 13354 1708 8742 594 3266 -5394 -1667 436 8047 -2192 -874 2657 -216 1115 -1685 1125 4327 3158 -1679 1404 -3744 -910 -2417 -487 -2929 836 -391 1896 -734 974 1329 1815 2159 -210 1525 865 308 -3116 -176 -1313 1830 -1919 -1483 -1703 784 -672 1207 -2619 2351 -864 -430 -2089 -1072 -1561 -2393 -1222 -278 649 -1598 2149 -913 15080 1006 30 785 -481 -1097 2300 980 1015 -802 -1436 -296 109 147 -2448 -396 -1048 -661 -202 56 1094 68 -360 383 -336 317 188 584 577 -689 -1029 -1630 112 -513 775 -2094 1383 440 569 874 924 -575 120 974 223 -48 185 -171 12 22 -531 216 -449 -671 94 -806 90 -650 682 87 1043 -1178 723 -308 -272 -88 906 -540 271 -681 1110 1182 -1109 -52 -295 844 -1295 1590 -1833 914 417 1271 195 1046 86 503 -870 -242 65 1298 -479 -215 715 -64 337 -534 365 1366 1004 -553 447 -1265 -317 -937 -199 -1310 378 -184 899 -359 456 606 834 1058 -116 912 541 183 -1771 -95 -752 1171 -1421 -1151 -1330 575 -465 733 -1484 1201 -476 -271 -1534 -874 -1386 -2241 -1205 -292 715 -1863 2419 -1026 13392 940 26 654 -435 -1119 2550 1237 1386 -1111 -1870 -344 117 160 -2992 -502 -1395 -920 -296 90 1755 114 -588 614 -500 439 260 839 889 -1143 -1734 -2694 177 -779 1105 -2932 1765 574 812 1360 1530 -997 211 1782 417 -94 372 -351 24 44 -1010 408 -833 SU 20250817T063725.7Z 9360.275992 239 1 50.22 2 67.94 93.95 21.62 202.97 0.00 1 0.00 1 0 25 1.117e-02 5.409e-03 2.454e-03 3.732e-04 3.446910e-01 1.848760e-04 4.187206e-03 -6.000000e+00 6.293549e-03 231.07 -2.00 3.62 -2.00 318.58 0.00e+00 2.567373e-04 3.391267e-05 1.100426e-04 -6.000000e+00 2.506372e-04 278.26 -2.00 20.00 -2.00 318.25 0.00e+00 2.640 0.000 302.00 328.00 3 1.3627e+00 4.9951e-04 2.8841e-02 -6.0000e+00 1.5889e-02 4.5326e-03 5.6420e-04 1.8459e-02 -6.0000e+00 1.7306e-02 -6.6302e-03 3.9990e-04 9.1710e-03 -6.0000e+00 1.0142e-02 -3.1269e-03 2.1369e-04 2.6276e-03 -6.0000e+00 4.2332e-03 9.8470e-03 -3.1168e-05 1.0319e-05 2.5349e-05 -6.0000e+00 2.8260e-04 1.1277e-02 0.0000e+00 10 0 0 10 0 0 31.59 15.48 0.23 0.01128 0.01104 890 181 2 8 0 55.970 15.01 15.48 23.25 20.96 21.27 32.8 873.95 -2787 -2408 -3189 -5314 -2980 -3866 329 -1709 -646 -3348 -1075 -2426 -37 -593 237 -965 -60 -225 764 623 -247 877 172 442 -531 -51 -1208 -354 -810 1527 236 1545 -16 -2097 -1779 -1575 -1317 -782 -1023 -1221 -1212 -1152 -904 -566 -427 -895 -295 -733 -61 493 702 649 1186 699 1143 866 845 861 858 1210 1529 1425 1373 489 -137 682 -22 1256 389 27 -45 -387 150 71 123 390 -4 514 -253 -812 -644 -1897 -1210 -1040 -709 -549 -270 44 219 298 671 659 1327 874 468 567 579 -181 -393 -199 -307 213 203 -788 -1107 -703 -765 -22 -74 105 -252 192 -22 205 560 640 289 139 -409 -670 -193 65 -34 495 310 823 1458 472 381 133 94 46 217 -97 -195 -1 -4 -297 -449 -167 -341 197 -133 -123 -163 -250 -124 -165 15 -92 -38 -206 -64 -163 -3 -55 25 -112 -7 -29 101 86 -34 121 25 70 -90 -9 -203 -55 -121 236 41 296 -3 -436 -344 -318 -307 -221 -349 -472 -498 -492 -393 -245 -186 -390 -126 -310 -26 218 338 305 590 366 612 479 470 468 457 651 877 902 951 355 -94 428 -13 793 285 22 -39 -339 126 56 87 247 -3 316 -179 -662 -586 -1896 -1256 -1052 -771 -633 -322 52 254 321 718 643 1238 870 479 651 745 -254 -553 -262 -366 234 228 -977 -1462 -965 -1103 -30 -111 170 -421 310 -33 285 786 893 422 202 -637 -1067 -300 98 -49 734 439 1095 1938 691 562 209 152 76 375 -180 -354 -2 -8 -567 -834 -295 -620 347 SU 20250817T064510.1Z 9360.281366 243 1 50.31 2 66.62 95.40 22.15 207.26 0.00 1 0.00 1 0 17 9.686e-03 5.408e-03 1.826e-03 3.281e-04 3.257239e-01 1.629939e-04 3.984048e-03 -6.000000e+00 5.457676e-03 231.07 -2.00 3.62 -2.00 318.37 0.00e+00 2.970338e-04 2.802279e-05 9.766247e-05 -6.000000e+00 2.173449e-04 278.26 -2.00 20.00 -2.00 318.03 0.00e+00 2.502 0.000 302.00 328.00 3 1.2828e+00 4.3981e-04 2.7320e-02 -6.0000e+00 1.3779e-02 4.0440e-03 4.9462e-04 1.7475e-02 -6.0000e+00 1.5007e-02 -6.2454e-03 3.3611e-04 8.6644e-03 -6.0000e+00 8.7946e-03 -3.0314e-03 1.7714e-04 2.4744e-03 -6.0000e+00 3.6710e-03 1.2264e-02 -6.1493e-05 9.0411e-06 2.4004e-05 -6.0000e+00 2.4506e-04 1.1031e-02 0.0000e+00 10 0 0 10 0 0 87.35 15.53 0.24 0.01103 0.01057 1009 205 2 8 0 49.360 15.01 15.53 23.92 20.96 21.38 33.1 878.17 -1279 -967 -2898 -4231 -3675 -1851 -271 25 -200 -2968 -2033 -1727 -748 61 -244 -804 -201 -158 319 636 -459 539 442 -132 -117 -265 -865 -726 -94 684 547 1444 308 -1952 -1528 -1476 -1218 -705 -836 -1288 -1292 -1111 -985 -513 -506 -760 -365 -608 -256 746 689 832 1028 651 1058 959 773 864 888 1277 1583 1344 1408 363 -122 570 26 1069 480 -63 -73 -461 148 -25 101 281 -25 519 -264 -776 -844 -1929 -1275 -1017 -809 -520 -374 63 115 367 616 687 1263 922 466 552 575 -181 -400 -261 -317 179 218 -834 -1055 -742 -714 -54 -41 110 -236 147 -52 231 533 631 337 163 -340 -607 -203 111 -32 575 290 863 1419 504 296 165 51 42 210 -100 -187 -10 -7 -294 -412 -178 -324 120 -73 -59 -180 -239 -186 -93 -15 2 -14 -218 -146 -136 -69 7 -30 -108 -28 -23 49 101 -73 85 74 -24 -22 -52 -164 -128 -16 119 106 307 72 -448 -325 -329 -312 -219 -312 -545 -529 -471 -426 -220 -219 -360 -169 -278 -117 353 323 418 547 364 603 563 457 499 503 730 964 902 1030 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