File name: Pandora289s1_DeBilt_20250604_L2Fit_fout2c2d20250401p1-8.txt File generation date: 20250729T071936.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v2d20250401.txt Level 1 file used: Pandora289s1_DeBilt_20250604_L1_smca1c2d20250401p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0110 305.1514 305.2918 305.4321 305.5725 305.7128 305.8531 305.9934 306.1337 306.2740 306.4143 306.5545 306.6948 306.8350 306.9752 307.1155 307.2557 307.3959 307.5360 307.6762 307.8164 307.9565 308.0967 308.2368 308.3769 308.5170 308.6571 308.7972 308.9372 309.0773 309.2173 309.3574 309.4974 309.6374 309.7774 309.9174 310.0574 310.1973 310.3373 310.4772 310.6171 310.7571 310.8970 311.0369 311.1767 311.3166 311.4565 311.5963 311.7362 311.8760 312.0158 312.1556 312.2954 312.4352 312.5749 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5530 313.6927 313.8323 313.9720 314.1116 314.2513 314.3909 314.5305 314.6701 314.8097 314.9492 315.0888 315.2284 315.3679 315.5074 315.6469 315.7864 315.9259 316.0654 316.2049 316.3443 316.4838 316.6232 316.7626 316.9020 317.0414 317.1808 317.3202 317.4596 317.5989 317.7383 317.8776 318.0169 318.1562 318.2955 318.4348 318.5741 318.7133 318.8526 318.9918 319.1310 319.2702 319.4094 319.5486 319.6878 319.8270 319.9661 320.1053 320.2444 320.3835 320.5226 320.6617 320.8008 320.9399 321.0789 321.2180 321.3570 321.4960 321.6351 321.7741 321.9131 322.0520 322.1910 322.3300 322.4689 322.6078 322.7467 322.8857 323.0246 323.1634 323.3023 323.4412 323.5800 323.7189 323.8577 323.9965 324.1353 324.2741 324.4129 324.5516 324.6904 324.8291 324.9679 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250604T072308.0Z 9286.307731 3570 1 29.33 2 56.38 96.14 126.71 14.82 0.00 1 0.00 1 0 17 3.332e-02 1.019e-02 2.401e-02 5.868e-03 2.998644e-01 3.043494e-03 3.847665e-03 -6.000000e+00 1.974041e-02 232.65 -2.00 3.84 -2.00 317.77 0.00e+00 1.176134e-03 4.841517e-04 2.652215e-04 -6.000000e+00 8.494749e-04 279.14 -2.00 20.00 -2.00 317.09 0.00e+00 1.800 0.000 302.00 328.00 3 6.5175e+00 8.1729e-03 2.5110e-02 -6.0000e+00 4.9666e-02 1.1569e-01 9.1890e-03 1.7085e-02 -6.0000e+00 5.3749e-02 -1.9732e-02 5.6401e-03 8.3434e-03 -6.0000e+00 3.1852e-02 -2.9489e-03 2.7933e-03 2.4339e-03 -6.0000e+00 1.3172e-02 8.3347e-05 3.6890e-05 1.7632e-04 2.5515e-05 -6.0000e+00 9.5134e-04 -6.4064e-03 0.0000e+00 12 8 8 10 0 0 99.92 24.40 0.60 -0.00641 -0.00613 8 8 1 5 0 3663.500 33.75 20.01 24.40 20.77 0.0 974.85 16872 14593 -4170 4716 -4859 -11366 6410 -16034 2206 -5213 -9481 -2420 -979 -2563 3335 7400 -571 -3111 -3754 1779 3254 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1135 1218 897 1944 263 -543 -1387 -1266 -589 309 1551 905 -495 711 -2520 -1122 -614 -1450 -2915 -2490 661 -903 814 1088 2523 1938 767 -964 -559 -1198 -778 -224 90 1163 310 293 -247 1138 1966 275 -438 -711 -165 93 685 -708 63 505 67 -261 1031 -154 701 120 -246 -127 -2230 SU 20250604T072424.8Z 9286.308621 3572 1 2.69 2 56.19 96.40 126.66 15.20 0.00 1 0.00 1 0 17 1.498e-02 8.252e-03 1.272e-02 5.863e-03 2.829105e-01 3.057767e-03 3.670691e-03 -6.000000e+00 8.872430e-03 232.65 -2.00 3.84 -2.00 316.31 0.00e+00 1.740724e-04 3.403365e-04 1.303035e-04 -6.000000e+00 3.818526e-04 279.14 -2.00 20.00 -2.00 315.67 0.00e+00 1.791 0.000 302.00 328.00 3 4.3119e+00 8.0305e-03 2.4304e-02 -6.0000e+00 2.2323e-02 4.4305e-02 8.9493e-03 1.6061e-02 -6.0000e+00 2.4159e-02 -1.0870e-02 5.1511e-03 7.7973e-03 -6.0000e+00 1.4317e-02 1.1819e-04 2.3530e-03 2.1245e-03 -6.0000e+00 5.9193e-03 8.1472e-04 -1.1541e-04 1.7170e-04 2.5906e-05 -6.0000e+00 4.2767e-04 -5.2691e-03 0.0000e+00 12 9 1 12 1 1 999.00 24.40 0.35 -0.00527 -0.00614 1 22 1 5 0 1339.970 33.75 20.00 24.40 20.81 0.0 975.20 1258 248 -2123 -4408 -3203 -3545 3549 -3657 1762 3406 -4941 -3656 -2139 -4476 433 -228 1098 293 1470 1435 4501 -1775 1449 2491 561 -315 608 -512 471 -2051 2464 4129 804 -2084 -1614 -1554 -2928 -152 -1300 922 -920 512 -1645 -1514 22 212 10 -716 177 777 -202 -390 909 -201 630 284 2569 615 993 483 -533 1607 1067 1092 1325 576 58 -405 -459 531 57 -286 553 1758 -616 -1024 -347 -1479 -569 460 -670 -1320 -2133 -2746 -924 -970 593 288 17 423 -223 79 -40 568 891 9 718 -2 402 -163 -92 -1213 -1036 869 535 -479 -2133 -1278 -412 198 274 1186 649 -74 61 441 381 509 194 378 -101 -35 614 692 110 697 592 -652 184 956 -102 173 -270 -692 252 325 -240 -110 -553 -249 -194 163 -121 -271 208 43 -392 -811 -585 -601 563 -690 326 664 -1064 -789 -490 -1201 118 -70 355 100 514 484 1517 -642 509 896 219 -131 253 -207 179 -767 891 1587 350 -915 -696 -689 -1252 -71 -696 535 -578 340 -1102 -1030 15 150 7 -497 119 517 -139 -272 671 -151 487 227 2050 504 802 386 -433 1338 920 967 1217 520 51 -336 -385 486 53 -288 566 1752 -599 -962 -305 -1267 -475 389 -617 -1310 -2227 -2942 -1027 -1105 711 350 21 516 -272 89 -45 582 948 10 835 -3 506 -215 -119 -1523 -1241 995 642 -599 -2768 -1716 -552 280 399 1726 954 -108 86 592 487 651 261 524 -144 -51 866 974 149 933 779 -832 236 1254 -140 249 -386 -1016 371 505 -380 -174 -890 -401 -305 253 -187 -412 SU 20250604T072544.5Z 9286.309542 3574 1 29.92 2 55.98 96.68 126.61 15.59 0.00 1 0.00 1 0 17 1.059e-02 6.271e-03 3.385e-03 1.209e-03 2.807661e-01 6.275371e-04 3.618057e-03 -6.000000e+00 6.273091e-03 232.65 -2.00 3.84 -2.00 316.96 0.00e+00 4.638755e-04 8.186835e-05 9.961980e-05 -6.000000e+00 2.699768e-04 279.14 -2.00 20.00 -2.00 316.29 0.00e+00 1.782 0.000 302.00 328.00 3 4.0869e+00 1.6614e-03 2.4168e-02 -6.0000e+00 1.5783e-02 3.7731e-02 1.8570e-03 1.5973e-02 -6.0000e+00 1.7081e-02 -5.6469e-03 1.0918e-03 7.7500e-03 -6.0000e+00 1.0122e-02 -2.6640e-03 5.1717e-04 2.1350e-03 -6.0000e+00 4.1852e-03 1.0340e-03 4.0445e-05 3.5669e-05 2.4349e-05 -6.0000e+00 3.0237e-04 -5.4324e-03 0.0000e+00 10 0 0 10 0 0 99.99 24.41 0.25 -0.00543 -0.00513 117 117 1 5 0 255.670 33.75 20.00 24.41 20.86 0.0 975.53 1166 -1663 -3655 -2038 -2682 -3829 -1386 -1494 1678 -1449 -1976 -2863 -437 685 572 727 568 -2 523 808 1683 188 480 550 1087 767 -404 -516 -166 -240 793 1576 1198 924 -2517 -3498 -2741 -1130 -196 -217 -830 -1179 -641 -478 -391 -67 -486 -229 -426 -101 334 989 738 751 892 706 956 761 282 428 661 1062 1675 1603 1459 102 -668 -639 -368 1491 598 50 259 148 450 -117 -755 -907 -1257 -852 -943 -1287 -1304 -2149 -1502 -701 -595 151 132 601 533 681 69 129 519 348 287 210 723 392 -321 -815 -895 -170 -130 -561 -1285 -540 -581 228 607 587 366 288 11 -10 -26 410 89 268 92 -72 -183 358 303 730 337 -196 521 408 186 -39 -525 -195 96 138 -235 -4 249 217 121 -88 -631 -515 134 -222 -521 -278 -339 -453 -161 -192 235 -224 -312 -464 -75 132 128 165 138 0 139 222 471 54 138 163 341 254 -136 -168 -51 -71 236 503 420 341 -949 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