File name: Pandora289s1_DeBilt_20250627_L2Fit_fout2c2d20250401p1-8.txt File generation date: 20250729T072650.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v2d20250401.txt Level 1 file used: Pandora289s1_DeBilt_20250627_L1_smca1c2d20250401p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0110 305.1514 305.2918 305.4321 305.5725 305.7128 305.8531 305.9934 306.1337 306.2740 306.4143 306.5545 306.6948 306.8350 306.9752 307.1155 307.2557 307.3959 307.5360 307.6762 307.8164 307.9565 308.0967 308.2368 308.3769 308.5170 308.6571 308.7972 308.9372 309.0773 309.2173 309.3574 309.4974 309.6374 309.7774 309.9174 310.0574 310.1973 310.3373 310.4772 310.6171 310.7571 310.8970 311.0369 311.1767 311.3166 311.4565 311.5963 311.7362 311.8760 312.0158 312.1556 312.2954 312.4352 312.5749 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5530 313.6927 313.8323 313.9720 314.1116 314.2513 314.3909 314.5305 314.6701 314.8097 314.9492 315.0888 315.2284 315.3679 315.5074 315.6469 315.7864 315.9259 316.0654 316.2049 316.3443 316.4838 316.6232 316.7626 316.9020 317.0414 317.1808 317.3202 317.4596 317.5989 317.7383 317.8776 318.0169 318.1562 318.2955 318.4348 318.5741 318.7133 318.8526 318.9918 319.1310 319.2702 319.4094 319.5486 319.6878 319.8270 319.9661 320.1053 320.2444 320.3835 320.5226 320.6617 320.8008 320.9399 321.0789 321.2180 321.3570 321.4960 321.6351 321.7741 321.9131 322.0520 322.1910 322.3300 322.4689 322.6078 322.7467 322.8857 323.0246 323.1634 323.3023 323.4412 323.5800 323.7189 323.8577 323.9965 324.1353 324.2741 324.4129 324.5516 324.6904 324.8291 324.9679 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250627T070308.3Z 9309.293846 3011 1 30.93 2 59.55 90.46 76.47 69.62 0.00 1 0.00 1 0 17 1.871e-02 7.796e-03 1.347e-02 3.643e-03 2.886428e-01 1.891869e-03 3.695635e-03 -6.000000e+00 1.112740e-02 233.71 -2.00 3.84 -2.00 317.59 0.00e+00 8.304623e-04 2.905763e-04 1.771498e-04 -6.000000e+00 4.818386e-04 281.55 -2.00 20.00 -2.00 316.86 0.00e+00 1.965 0.000 302.00 328.00 3 5.7910e+00 5.0728e-03 2.5911e-02 -6.0000e+00 2.8049e-02 6.9894e-02 5.6947e-03 1.6553e-02 -6.0000e+00 3.0320e-02 -5.5427e-03 3.4468e-03 8.0000e-03 -6.0000e+00 1.7976e-02 -5.1385e-03 1.6842e-03 2.2337e-03 -6.0000e+00 7.4326e-03 1.5325e-04 -2.5007e-04 1.0887e-04 2.4290e-05 -6.0000e+00 5.3451e-04 -4.5522e-03 0.0000e+00 11 8 0 10 0 0 97.37 24.31 0.51 -0.00455 -0.00643 10 10 1 5 0 3091.930 33.75 20.02 24.31 21.14 0.0 975.41 -3679 -7795 -768 1864 -10734 -4400 -688 -984 -1916 -4000 -4224 -6450 -1133 -1198 1889 -2927 1363 -789 3575 -466 -1043 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1570 891 205 -45 -586 408 -282 -604 642 587 1127 -262 -888 -1827 -444 -354 -1029 -1482 -274 -728 -156 1152 1664 1269 497 -208 -54 -513 -91 -160 462 145 220 -374 1231 859 1123 -284 -419 51 1210 780 -32 -1241 -637 -178 261 214 353 794 711 179 -629 -1603 -1037 SU 20250627T072701.1Z 9309.310430 3102 1 14.06 2 55.89 95.29 73.16 73.88 0.00 1 0.00 1 0 17 1.300e-02 7.134e-03 6.594e-03 2.847e-03 2.582787e-01 1.491901e-03 3.332689e-03 -6.000000e+00 7.729431e-03 233.71 -2.00 3.84 -2.00 316.44 0.00e+00 6.125359e-04 1.726870e-04 9.538545e-05 -6.000000e+00 3.346416e-04 281.55 -2.00 20.00 -2.00 315.75 0.00e+00 1.778 0.000 302.00 328.00 3 4.9818e+00 3.9383e-03 2.3308e-02 -6.0000e+00 1.9484e-02 3.7814e-02 4.3858e-03 1.4782e-02 -6.0000e+00 2.1059e-02 -3.2781e-03 2.5321e-03 7.1301e-03 -6.0000e+00 1.2486e-02 -2.2510e-03 1.1642e-03 1.9594e-03 -6.0000e+00 5.1640e-03 4.4137e-04 5.6127e-05 8.4083e-05 2.3124e-05 -6.0000e+00 3.7119e-04 -6.1085e-03 0.0000e+00 12 9 1 12 1 1 98.28 24.47 0.22 -0.00611 -0.00569 5 13 1 5 0 2342.190 33.75 20.00 24.47 21.52 0.0 976.97 -6596 194 -1714 -2516 -4837 -2232 -1068 2848 589 1854 -3123 -4671 -1237 -707 26 483 -901 1466 686 1898 914 1902 -103 2582 1472 -53 1136 -1085 -379 -1075 -890 1427 653 461 -1578 -3193 -2225 795 -1086 420 -1180 -977 -396 -473 -11 787 -600 224 -581 -387 359 105 521 501 679 604 545 414 533 89 1157 1352 1542 1894 1076 77 -789 -472 576 1471 705 222 617 -146 778 5 -963 -1211 -1514 -1137 -1282 -2162 -1123 -1845 -1485 -1232 -133 -256 73 451 645 695 92 -540 635 316 -106 232 1002 592 -251 -1090 -952 -160 -94 -542 -944 -441 -421 -57 407 800 543 512 -16 -161 705 133 387 384 -263 165 -280 207 367 895 118 -134 619 752 467 -272 -625 -619 67 19 65 -77 69 427 69 -29 -833 -517 -1019 31 -296 -424 -767 -350 -166 469 101 336 -603 -926 -254 -164 7 142 -286 473 213 602 301 626 -35 871 533 -20 436 -411 -135 -368 -307 517 260 192 -662 -1306 -918 359 -553 248 -736 -653 -273 -332 -8 547 -419 152 -387 -255 241 75 369 374 525 480 443 339 432 72 925 1130 1302 1714 1017 71 -683 -405 493 1286 651 221 628 -147 744 5 -825 -1015 -1248 -1000 -1192 -2131 -1191 -1975 -1672 -1398 -160 -324 89 569 777 817 99 -571 661 333 -124 283 1256 778 -325 -1389 -1117 -192 -111 -694 -1220 -591 -560 -79 603 1174 800 757 -22 -215 888 170 516 521 -379 242 -405 288 514 1192 150 -172 796 980 656 -382 -899 -910 98 29 105 -122 112 688 109 -46 -1285 -786 SU 20250627T072823.7Z 9309.311386 3104 1 30.07 2 55.68 95.58 72.96 74.13 0.00 1 0.00 1 0 17 9.040e-03 6.351e-03 1.406e-03 6.737e-04 2.559487e-01 3.532306e-04 3.301243e-03 -6.000000e+00 5.376512e-03 233.71 -2.00 3.84 -2.00 316.22 0.00e+00 3.906998e-04 3.845862e-05 6.554153e-05 -6.000000e+00 2.327867e-04 281.55 -2.00 20.00 -2.00 315.53 0.00e+00 1.768 0.000 302.00 328.00 3 3.1328e+00 9.2794e-04 2.3118e-02 -6.0000e+00 1.3553e-02 2.1871e-02 1.0323e-03 1.4596e-02 -6.0000e+00 1.4649e-02 -3.2215e-03 5.9313e-04 7.0464e-03 -6.0000e+00 8.6854e-03 -2.8843e-03 2.6894e-04 1.9217e-03 -6.0000e+00 3.5918e-03 2.8680e-03 5.9337e-10 1.9829e-05 2.3163e-05 -6.0000e+00 2.5822e-04 -5.6255e-03 0.0000e+00 10 0 0 10 0 0 99.96 24.47 0.27 -0.00563 -0.00563 151 151 1 5 0 199.060 33.75 20.00 24.47 21.53 0.0 977.07 598 794 -1222 -2354 -3266 -1860 -1275 970 135 -203 -2272 -2127 -685 -228 482 137 -168 192 884 699 1652 755 752 681 1170 667 43 -853 -321 -88 -9 1526 1003 652 -2138 -2856 -2257 -1123 -224 -432 -744 -704 -524 -453 -400 22 -227 -359 -579 -403 248 1045 899 869 844 743 834 733 351 347 616 1247 1567 1483 1150 87 -640 -532 3 1457 499 117 166 22 319 -107 -592 -663 -1015 -610 -792 -1538 -1666 -2111 -1595 -690 -468 111 -3 414 696 565 121 93 720 352 359 290 511 260 -206 -752 -967 -125 15 -635 -1144 -531 -774 271 444 500 231 218 126 187 208 529 165 319 -105 -109 -167 324 527 778 392 -120 613 564 291 -213 -573 -243 147 175 -6 -23 161 162 -69 -147 -627 -552 102 152 -250 -472 -607 -315 -215 177 28 -45 -521 -492 -167 -58 139 44 -58 63 300 246 594 276 275 257 467 281 18 -355 -126 -33 -4 607 437 298 -990 -1278 -1023 -528 -117 -265 -482 -489 -355 -312 -276 15 -155 -255 -402 -277 173 723 666 679 646 586 671 595 283 276 493 1037 1329 1353 1090 81 -555 -453 3 1280 469 119 172 23 311 -102 -509 -551 -829 -531 -737 -1529 -1717 -2321 -1758 -804 -557 138 -3 516 829 653 134 95 762 381 410 350 643 343 -267 -945 -1175 -147 18 -807 -1483 -714 -1043 383 639 749 334 314 175 249 264 671 221 438 -148 -155 -235 457 712 1043 500 -154 787 740 395 -303 -834 -347 219 265 -9 -36 257 261 -108 -233 -954 -829 SU 20250627T072938.5Z 9309.312251 3106 1 3.18 2 55.49 95.84 72.79 74.35 0.00 1 0.00 1 0 17 8.941e-03 6.523e-03 1.932e-03 1.116e-03 2.545452e-01 5.875383e-04 3.298797e-03 -6.000000e+00 5.317190e-03 233.71 -2.00 3.84 -2.00 315.70 0.00e+00 3.549515e-04 5.719314e-05 5.137154e-05 -6.000000e+00 2.302336e-04 281.55 -2.00 20.00 -2.00 315.04 0.00e+00 1.760 0.000 302.00 328.00 3 1.9796e+00 1.5352e-03 2.2993e-02 -6.0000e+00 1.3403e-02 1.6010e-02 1.7050e-03 1.4499e-02 -6.0000e+00 1.4488e-02 -4.2185e-03 9.7181e-04 6.9993e-03 -6.0000e+00 8.5898e-03 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