File name: Pandora39s1_DearbornMI_20220604_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T222300.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220604_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220604T105242.2Z 8190.453266 75 1 48.94 2 81.75 67.05 112.58 20.74 0.00 1 0.00 1 0 17 7.551e-01 1.621e-02 3.750e-01 8.778e-03 8.868918e-01 5.374520e-03 9.832355e-03 -6.000000e+00 4.561626e-01 232.17 -2.00 3.54 -2.00 322.15 0.00e+00 1.019733e-02 3.341837e-03 1.458649e-03 -6.000000e+00 2.279381e-02 283.85 -2.00 20.00 -2.00 321.70 0.00e+00 6.536 0.005 302.00 328.00 3 1.4992e+00 2.1892e-02 8.2386e-02 -6.0000e+00 1.1457e+00 3.6134e-01 3.4898e-02 5.6648e-02 -6.0000e+00 1.2428e+00 -4.9686e-01 3.7474e-02 3.0126e-02 -6.0000e+00 7.3373e-01 1.9675e-01 1.6501e-02 1.5859e-02 -6.0000e+00 3.1186e-01 8.0391e-05 -5.0499e-04 2.5853e-04 2.2322e-04 -6.0000e+00 2.2359e-02 7.4367e-03 1.9505e-05 12 9 8 11 8 0 99.22 22.20 0.52 0.00744 0.00364 63 14 1 5 0 776.730 26.21 20.00 22.20 18.79 11.7 996.82 900000 -269419 900000 -220422 900000 -329791 900000 -328961 -160075 900000 -232994 38741 -136526 900000 -198663 900000 -141995 900000 -149324 53036 53187 -79545 900000 -97927 900000 -116150 900000 -78927 900000 -91389 900000 120871 -31662 164751 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419 -2812 750 -1241 2571 -586 1807 602 -80 208 -881 449 -1287 545 -1580 981 -1789 -390 366 -1030 453 -1687 -916 -3923 514 -1915 -1211 -469 971 -360 -1613 -529 -1195 985 -578 885 -1013 1128 -49 1159 2523 523 2341 104 2157 -166 1173 296 522 -701 -81 1146 -1269 2044 -1519 2060 -64 -778 -431 -1097 -1608 SS 20220604T110902.8Z 8190.464616 80 1 48.83 2 78.94 69.61 111.49 24.46 0.00 1 0.00 1 0 17 6.462e-01 1.988e-02 3.884e-01 1.285e-02 7.100958e-01 7.332735e-03 8.307586e-03 -6.000000e+00 3.856695e-01 232.17 -2.00 3.54 -2.00 321.57 0.00e+00 -4.481632e-04 3.879780e-03 6.038267e-03 -6.000000e+00 1.803100e-02 283.85 -2.00 20.00 -2.00 321.03 0.00e+00 5.026 0.002 302.00 328.00 3 3.6911e+00 2.6761e-02 7.0697e-02 -6.0000e+00 9.6691e-01 1.4990e-01 3.7712e-02 5.9230e-02 -6.0000e+00 1.0465e+00 -2.8774e-01 3.6493e-02 2.6034e-02 -6.0000e+00 6.1977e-01 1.2238e-01 1.6792e-02 6.1577e-03 -6.0000e+00 2.6169e-01 4.6055e-05 5.5798e-04 3.8749e-04 1.0412e-04 -6.0000e+00 1.8724e-02 9.2390e-03 3.8709e-05 12 8 8 10 0 0 99.45 22.20 0.45 0.00924 0.01343 28 6 1 5 0 1743.630 26.21 20.00 22.20 19.09 11.8 999.09 -211554 -86436 900000 900000 -198746 900000 -217825 -188720 -31322 -212144 178006 -212688 -130935 -126795 263033 -70874 -95124 16119 900000 27119 -34958 49327 -77910 122969 900000 182767 -8935 56107 119839 17603 -57230 -13113 59010 13707 18352 88100 40358 110952 -32263 25577 -6357 79032 12993 63548 -724 82425 9183 7366 34924 -5507 39811 43806 24926 7878 16544 -3491 4622 13077 -3493 17989 -2020 5774 12266 11319 7760 11748 6808 7637 12957 179 1439 -2496 5683 5066 4849 4397 -1775 2944 -4705 5106 -1137 -3160 -8402 -2315 -1786 1434 1243 611 45 -979 4410 -4439 -1580 -4549 2714 -2251 -1696 1081 -645 169 -1665 -2412 -2356 -232 -1940 -4437 450 -1407 848 868 -786 -282 1546 418 518 -1160 407 1217 -148 392 -131 733 411 1755 -201 2015 -128 2316 540 -1142 936 -612 -259 -320 -313 128 358 970 11 -99 -1421 298 -788 -3532 -1082 900000 900000 -2962 900000 -4545 -3375 -392 -5554 2229 -7142 -2576 -3024 3293 -1394 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3.4075e+00 1.1327e-02 5.6111e-02 -6.0000e+00 5.4703e-01 7.3103e-02 1.5474e-02 3.6691e-02 -6.0000e+00 5.9195e-01 -6.1130e-02 1.5546e-02 2.2390e-02 -6.0000e+00 3.4802e-01 1.1042e-02 7.4346e-03 9.4948e-03 -6.0000e+00 1.4625e-01 1.1280e-04 -1.7011e-04 1.8123e-04 1.2566e-04 -6.0000e+00 1.0454e-02 7.4170e-03 6.4246e-06 11 8 0 10 0 0 99.34 22.20 0.32 0.00742 0.00614 29 6 1 5 0 1671.080 26.21 20.00 22.20 19.30 11.8 1001.14 -24269 -197035 -78301 -115050 -98136 900000 -95887 900000 -128045 900000 -142511 -3303 -99472 102743 12969 -13083 36994 -34244 24917 -60745 63480 -13382 136631 -21644 23800 2447 -7057 20273 -44403 375 -35166 60187 30445 -2751 -13351 -17680 6458 -10984 -3110 -9069 5418 -5292 6911 -4283 4452 8668 -33 17810 -7051 11816 209 8975 -4020 5235 4167 1632 4507 -5057 3333 -3194 2606 -2901 5232 3515 1420 4840 4382 -127 -1664 2347 1437 2444 -91 87 -2091 -977 831 -1339 994 -1813 1074 -1974 -107 -2239 562 -114 78 55 -776 -173 -1646 2000 -935 795 -836 -298 -83 17 805 -1702 632 -1267 -744 192 55 -162 -1643 366 -1086 878 -2 1079 -119 106 -140 607 429 -174 575 -413 -93 -19 826 496 777 100 -880 258 59 296 -316 234 -811 57 -439 120 -194 472 169 -102 309 -607 38 -143 -3289 -463 -896 -606 900000 -644 900000 -1478 900000 -2086 -20 -1549 607 108 -169 328 -660 301 -1747 562 -259 807 -495 383 51 -158 354 -1448 9 -1436 1180 884 -117 -607 -822 277 -641 -204 -748 431 -503 614 -440 430 828 -3 1666 -855 1335 28 1247 -696 897 761 317 870 -1067 632 -646 522 -682 1291 985 423 1364 1234 -39 -570 885 600 1051 -40 36 -799 -333 262 -439 357 -792 532 -1103 -64 -1455 380 -83 59 43 -611 -130 -1174 1286 -619 531 -606 -248 -80 19 952 -2063 706 -1310 -701 179 55 -171 -1856 434 -1425 1210 -3 1734 -194 166 -210 862 610 -259 899 -680 -152 -30 1256 728 1131 142 -1214 362 88 496 -586 463 -1642 121 -997 286 -476 1173 423 -249 707 -1326 79 SS 20220604T112404.4Z 8190.475050 89 1 8.11 2 76.32 71.94 110.34 27.80 0.00 1 0.00 1 0 17 2.959e-01 8.229e-03 1.631e-01 4.219e-03 6.047421e-01 2.259285e-03 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