File name: Pandora39s1_DearbornMI_20220605_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T222129.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220605_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220605T124812.2Z 8191.533474 132 1 47.99 2 61.07 84.83 110.06 37.50 0.00 1 0.00 1 0 17 2.522e-02 6.944e-03 2.615e-02 4.652e-03 3.136805e-01 2.409904e-03 3.735040e-03 -6.000000e+00 1.488776e-02 232.24 -2.00 3.54 -2.00 318.48 0.00e+00 2.045214e-03 4.710400e-04 9.997964e-05 -6.000000e+00 6.484997e-04 283.96 -2.00 20.00 -2.00 317.72 0.00e+00 2.058 0.000 302.00 328.00 3 5.8096e+00 6.5695e-03 2.6374e-02 -6.0000e+00 3.7366e-02 3.3204e-02 7.4583e-03 1.6871e-02 -6.0000e+00 4.0358e-02 -1.1035e-03 4.8817e-03 8.1916e-03 -6.0000e+00 2.3966e-02 -7.2316e-03 2.5062e-03 2.9721e-03 -6.0000e+00 1.0133e-02 1.3831e-04 3.1424e-04 1.4100e-04 3.0738e-05 -6.0000e+00 7.1247e-04 5.0923e-03 1.7897e-05 11 8 0 10 0 0 99.92 22.19 0.31 0.00509 0.00745 12 3 1 5 0 3998.830 26.21 20.00 22.19 27.49 12.1 1051.91 3391 -1615 2905 -7123 -3610 -13231 4769 9191 4511 -9805 -6477 404 -6356 -5675 1307 1955 2178 -3140 -2249 1572 4058 -1986 -976 2287 -2534 -3685 -2909 -1911 309 5619 2984 4201 3127 -2166 -3268 -2727 -3621 -1211 878 -1761 -258 -611 -1495 303 92 2280 182 -266 -871 510 767 -892 -1120 790 599 2338 -393 70 -63 592 1552 1970 1751 2054 -220 -27 -1433 -42 -158 816 349 597 595 1259 -180 -145 -902 -836 1024 -1585 -1089 -1272 -1140 -1497 -1363 -1136 712 334 588 858 119 465 -334 652 1182 -224 838 527 -104 -491 -242 -1132 -623 610 -741 -1524 -811 -239 -659 679 424 -173 258 354 -16 682 45 -658 323 -267 -258 -182 122 -6 834 960 -66 798 691 301 119 -287 92 -16 58 305 -17 549 86 -138 -492 -631 -411 183 -99 172 -430 -191 -769 250 513 289 -749 -480 30 -589 -611 151 247 290 -464 -345 240 611 -317 -160 382 -464 -705 -546 -335 51 894 530 808 660 -487 -701 -587 -872 -333 273 -648 -102 -253 -644 130 39 961 77 -112 -366 216 345 -439 -586 428 335 1313 -230 40 -36 335 904 1233 1199 1492 -163 -18 -942 -27 -108 627 283 503 499 1005 -140 -102 -580 -518 659 -1182 -911 -1137 -1089 -1510 -1469 -1306 816 396 697 1012 131 468 -312 611 1123 -239 989 669 -141 -662 -307 -1384 -712 702 -931 -1973 -1092 -336 -983 1031 685 -287 415 554 -23 921 61 -924 478 -423 -405 -292 190 -9 1180 1293 -88 1062 944 444 186 -470 148 -27 102 567 -32 1039 166 -260 -925 -1143 -722 SS 20220605T134400.6Z 8191.572229 169 1 48.77 2 50.77 94.18 103.38 48.79 0.00 1 0.00 1 0 17 9.355e-03 6.019e-03 7.335e-03 2.245e-03 2.414408e-01 1.160951e-03 2.908364e-03 -6.000000e+00 5.521696e-03 232.24 -2.00 3.54 -2.00 317.54 0.00e+00 3.845252e-04 1.743328e-04 1.322766e-04 -6.000000e+00 2.405635e-04 283.96 -2.00 20.00 -2.00 316.76 0.00e+00 1.578 0.000 302.00 328.00 3 2.9056e+00 3.1005e-03 2.0216e-02 -6.0000e+00 1.3859e-02 -3.0763e-03 3.4765e-03 1.2773e-02 -6.0000e+00 1.4969e-02 6.8467e-03 2.1022e-03 6.2142e-03 -6.0000e+00 8.8889e-03 -8.2724e-03 1.0332e-03 1.7254e-03 -6.0000e+00 3.7581e-03 4.5989e-03 2.8727e-04 6.7832e-05 2.0143e-05 -6.0000e+00 2.6429e-04 4.8706e-03 -1.8272e-05 10 0 0 10 0 0 99.99 22.20 0.21 0.00487 0.00703 57 13 3 5 0 855.480 26.21 19.99 22.20 29.33 12.2 1063.14 -436 911 -1152 -1875 -1265 -3554 1635 -730 -1094 -2691 -1801 -859 -1190 -2193 -1002 -460 -343 -357 -933 1154 -1346 402 374 1093 113 520 -1155 -1948 -29 631 2162 756 1453 -1838 -1405 -344 -1899 -725 -351 -636 -1161 -273 -856 -72 -340 -437 -210 279 -868 207 1657 74 1386 641 688 806 610 298 743 1003 1143 1518 1538 1483 -628 46 45 -457 681 694 376 341 -80 334 -23 -98 46 -143 53 -327 -1177 -964 -2345 -1449 -1146 -405 -153 -21 266 111 513 389 280 614 405 196 435 550 -308 -524 -651 -800 -393 559 -1122 -1416 -514 -883 -334 610 301 91 117 250 11 342 671 259 524 146 -437 224 96 168 442 856 134 1116 806 193 298 -75 -144 112 208 -52 -230 258 -302 -249 -215 -294 -585 -47 102 -131 -196 -125 -356 168 -86 -141 -363 -238 -118 -178 -376 -191 -94 -73 -78 -214 268 -322 94 91 278 30 143 -317 -503 -7 156 559 204 416 -545 -407 -99 -590 -260 -150 -313 -620 -150 -486 -41 -193 -247 -116 149 -459 109 911 44 859 420 464 553 425 207 505 680 802 1138 1194 1213 -517 34 33 -330 518 568 337 318 -75 299 -19 -77 33 -97 38 -260 -1011 -909 -2389 -1537 -1297 -468 -186 -26 333 134 594 412 272 574 397 211 518 695 -415 -697 -818 -973 -450 650 -1434 -1846 -695 -1256 -494 949 475 145 182 376 15 441 888 343 739 222 -686 347 147 246 610 1166 175 1431 1092 270 436 -115 -224 179 337 -89 -407 465 -555 -449 -374 -495 -964 SS 20220605T134912.4Z 8191.575838 172 1 48.57 2 49.81 95.12 102.69 49.77 0.00 1 0.00 1 0 17 9.894e-03 6.014e-03 4.396e-03 1.565e-03 2.397447e-01 8.102252e-04 2.887095e-03 -6.000000e+00 5.839949e-03 232.24 -2.00 3.54 -2.00 317.15 0.00e+00 5.201645e-04 1.106627e-04 8.409204e-05 -6.000000e+00 2.544518e-04 283.96 -2.00 20.00 -2.00 316.40 0.00e+00 1.546 0.000 302.00 328.00 3 4.7172e+00 2.1503e-03 1.9914e-02 -6.0000e+00 1.4657e-02 1.4246e-02 2.4049e-03 1.2660e-02 -6.0000e+00 1.5832e-02 -1.3775e-03 1.4223e-03 6.1495e-03 -6.0000e+00 9.4013e-03 -4.3112e-03 6.8591e-04 1.7221e-03 -6.0000e+00 3.9746e-03 7.7158e-04 1.7062e-04 4.6735e-05 2.0439e-05 -6.0000e+00 2.7955e-04 5.0494e-03 -2.6530e-05 10 0 0 10 0 0 99.83 22.20 0.24 0.00505 0.00633 42 9 1 5 0 1156.140 26.21 20.00 22.20 29.48 12.2 1064.19 -4079 -369 -2172 -3852 -1047 -3335 1300 -503 466 -1479 -965 -1492 316 -480 -580 251 -730 670 741 1277 -282 1862 1264 78 504 247 -471 -1169 995 -316 1638 967 1263 -1076 -1944 -1201 -2604 -403 -340 -985 -1179 -922 -846 -479 238 -700 -389 -673 -232 186 874 478 1067 1293 560 1591 622 429 492 890 578 1484 1561 1251 -45 -98 111 -553 1143 276 55 387 -152 484 56 109 -95 -489 -164 -968 -1088 -1149 -2179 -1376 -776 -849 -192 -22 162 188 200 590 264 724 636 109 324 902 -119 -485 -595 -882 -438 418 -325 -1327 -557 -757 -289 451 334 154 220 209 -160 324 401 286 366 221 -554 163 191 282 486 668 -40 995 1036 -20 297 -388 -86 50 174 26 -250 430 -79 -141 -210 -421 -665 -555 -51 -306 -503 -120 -388 156 -68 69 -228 -146 -239 56 -97 -133 61 -186 175 189 334 -75 514 363 23 151 76 -144 -355 278 -89 482 307 428 -373 -638 -394 -904 -160 -161 -539 -697 -535 -504 -285 148 -438 -237 -400 -134 108 533 311 690 876 392 1123 449 309 347 625 423 1153 1308 1107 -39 -80 84 -412 893 244 50 368 -145 442 50 88 -70 -361 -120 -794 -999 -1103 -2253 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