File name: Pandora39s1_DearbornMI_20220824_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T230333.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220824_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220824T113334.8Z 8271.481653 153 1 48.41 2 82.88 81.58 52.03 89.83 0.00 1 0.00 1 0 17 5.589e-01 4.098e-02 5.371e-01 3.787e-02 8.269975e-01 2.355029e-02 9.756923e-03 -6.000000e+00 3.461028e-01 231.04 -2.00 3.54 -2.00 322.23 0.00e+00 -2.232890e-02 1.341601e-02 1.368206e-03 -6.000000e+00 1.670429e-02 287.76 -2.00 20.00 -2.00 321.74 0.00e+00 7.410 0.008 302.00 328.00 3 2.9030e+00 9.5184e-02 8.9712e-02 -6.0000e+00 8.7247e-01 5.8930e-01 1.2355e-01 6.4406e-02 -6.0000e+00 9.5269e-01 -1.1581e+00 9.2612e-02 2.3577e-02 -6.0000e+00 5.5109e-01 5.0729e-01 4.3323e-02 1.9256e-02 -6.0000e+00 2.3076e-01 1.1261e-05 -1.1373e-03 1.2022e-03 2.8023e-04 -6.0000e+00 1.7387e-02 6.5325e-03 8.0552e-05 12 8 8 10 0 0 96.63 22.24 0.91 0.00653 -0.00201 18 4 1 5 0 2688.800 26.21 20.00 22.24 27.36 13.3 993.20 900000 -28353 6536 131122 900000 900000 900000 900000 -175904 900000 -130527 -127855 900000 900000 900000 -36454 900000 -43120 165855 40022 122412 -38404 133230 -23757 900000 47233 93994 -73252 17899 -69459 -58899 -6678 900000 900000 -32300 -22887 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-600 3653 493 4409 3965 -445 4794 5945 882 1326 4558 -1282 166 8618 -2489 1583 -2218 1242 8437 4013 4155 1743 -4351 1826 827 -7409 1257 -2398 3680 -2614 -8761 -2326 2818 -7261 487 -301 -3017 -9060 140 -1913 -1190 -3077 -7065 -747 -222 4966 3853 979 -864 9978 481 1029 -1635 2908 -1479 1909 4947 604 2799 3271 3454 -578 2364 -3462 -5368 2078 7810 2052 -7911 250 -4431 3812 -3570 1356 SS 20220824T114551.8Z 8271.490183 156 1 48.88 2 80.63 83.61 49.83 91.88 0.00 1 0.00 1 0 17 5.116e-01 1.105e-02 3.394e-01 6.737e-03 7.171170e-01 3.865106e-03 7.962271e-03 -6.000000e+00 3.070636e-01 231.04 -2.00 3.54 -2.00 321.67 0.00e+00 5.819281e-04 2.167434e-03 1.361585e-03 -6.000000e+00 1.372999e-02 287.76 -2.00 20.00 -2.00 321.11 0.00e+00 5.837 0.004 302.00 328.00 3 1.9968e+00 1.4668e-02 6.9456e-02 -6.0000e+00 7.6976e-01 9.7521e-02 2.1386e-02 4.0770e-02 -6.0000e+00 8.3357e-01 -1.7150e-01 2.1365e-02 2.1954e-02 -6.0000e+00 4.9109e-01 5.9655e-02 9.7640e-03 6.9526e-03 -6.0000e+00 2.0641e-01 1.2087e-04 1.6757e-04 2.0196e-04 8.6249e-05 -6.0000e+00 1.4734e-02 6.0128e-03 7.4103e-05 12 8 8 10 0 0 71.36 22.24 0.46 0.00601 0.00727 71 16 1 5 0 688.300 26.21 20.00 22.24 27.68 13.2 994.76 -195789 -153259 -136232 -112161 -77340 900000 900000 -128304 900000 -250686 11525 -186171 4166 -98601 -17017 900000 -5013 34623 -70863 -15506 -88313 272193 -69293 -3580 -218 -41223 -11193 -91497 15590 -92752 41715 -36976 35506 -32094 -26176 4684 -31243 882 -18860 28815 -3978 4423 4477 2082 6502 20065 14910 -583 12998 2581 14137 1877 14133 8324 -3064 7260 4261 7933 3535 8298 449 5172 3114 7189 2796 1746 4158 1981 9592 -263 5277 1494 4951 1525 2715 -627 -3354 -1265 -2200 -675 -1596 1606 -2547 -1709 -555 -770 1592 55 2443 -861 294 459 400 -1535 -152 -2156 -1161 357 -1159 354 -885 -486 -1164 -30 -912 -1336 -298 -910 97 -183 553 -278 551 -48 -86 230 -337 -400 40 230 -599 1274 20 232 296 859 21 1122 819 -201 317 -469 394 -111 -124 -175 -151 1222 -202 -99 -201 -309 -697 -1402 -1006 -894 -736 -508 900000 900000 -842 900000 -5685 76 -2889 27 -1059 -112 900000 -39 227 -1184 -157 -1897 1787 -1365 -41 -3 -787 -160 -2840 184 -3321 520 -1103 593 -1111 -828 112 -1212 30 -968 1101 -237 261 278 135 411 1138 917 -44 908 219 1207 204 1501 943 -416 933 583 1042 472 1044 64 775 545 1361 581 363 851 436 2183 -76 1594 489 1544 464 744 -160 -833 -317 -631 -227 -637 713 -1300 -924 -318 -472 1001 36 1566 -550 174 255 216 -883 -97 -1632 -1014 353 -1173 384 -919 -457 -1008 -25 -836 -1306 -305 -1010 118 -231 772 -419 836 -71 -122 314 -463 -574 61 361 -944 1903 30 326 399 1209 29 1588 1202 -339 588 -947 837 -253 -301 -450 -400 3256 -549 -260 -495 -721 -1566 SS 20220824T115530.4Z 8271.496880 161 1 48.58 2 78.85 85.20 48.10 93.54 0.00 1 0.00 1 0 17 3.028e-01 5.983e-03 2.067e-01 3.249e-03 6.186445e-01 1.780288e-03 7.136518e-03 -6.000000e+00 1.780371e-01 231.04 -2.00 3.54 -2.00 321.22 0.00e+00 3.759589e-03 8.777823e-04 2.189759e-03 -6.000000e+00 7.912287e-03 287.76 -2.00 20.00 -2.00 320.61 0.00e+00 4.989 0.002 302.00 328.00 3 1.8156e+00 6.2667e-03 5.9724e-02 -6.0000e+00 4.4493e-01 1.1587e-02 8.6051e-03 3.5334e-02 -6.0000e+00 4.8064e-01 -3.4497e-02 8.4487e-03 1.9702e-02 -6.0000e+00 2.8638e-01 9.0911e-04 4.0100e-03 7.0627e-03 -6.0000e+00 1.2186e-01 3.4806e-04 3.7560e-04 9.7741e-05 1.0218e-04 -6.0000e+00 8.5529e-03 5.4469e-03 6.7901e-05 10 0 0 10 0 0 87.18 22.24 0.35 0.00545 0.00827 118 26 1 5 0 411.630 26.21 20.01 22.24 28.32 13.4 999.59 -132151 9125 -79765 -124727 -141139 -156526 -18173 -121405 75944 -60086 -12473 -71397 -58810 -27637 -27508 -12918 -20597 14854 -31185 -3885 -15271 -3309 -28457 -17240 -20252 -8560 -22517 -2843 -11944 -29364 3779 -1362 -2753 -11812 -7790 -7936 -18544 706 -6687 6118 -2968 -176 -1953 714 6452 3865 2924 4855 6439 42 2651 1110 4367 1391 1538 1841 -953 279 -1831 1344 179 3353 1535 3526 -107 704 1570 -155 1413 1043 1839 361 338 -877 869 -12 248 -2430 -1006 -609 -1273 -96 -2792 -1590 -1499 -256 339 600 1157 1386 964 877 540 -85 -327 -524 332 569 158 -549 -581 -658 -688 250 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