File name: Pandora39s1_DearbornMI_20230516_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T001254.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20230516_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20230516 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230516T113428.0Z 8536.482269 117 1 19.06 2 76.29 76.50 59.48 115.12 0.00 1 0.00 1 0 17 2.510e-01 9.160e-03 2.555e-01 7.974e-03 5.716208e-01 4.289959e-03 6.559139e-03 -6.000000e+00 1.474590e-01 231.01 -2.00 3.54 -2.00 320.52 0.00e+00 1.823042e-03 1.648288e-03 9.623421e-04 -6.000000e+00 6.780154e-03 281.91 -2.00 20.00 -2.00 319.92 0.00e+00 4.122 0.001 302.00 328.00 3 3.8659e+00 1.3225e-02 5.0893e-02 -6.0000e+00 3.6918e-01 6.0931e-02 1.6735e-02 3.0994e-02 -6.0000e+00 3.9938e-01 -4.9940e-02 1.5717e-02 1.6133e-02 -6.0000e+00 2.3715e-01 1.1305e-02 7.8588e-03 5.3409e-03 -6.0000e+00 1.0066e-01 1.0038e-04 1.1705e-04 2.3658e-04 6.4401e-05 -6.0000e+00 7.1421e-03 6.5376e-03 -4.5439e-05 12 9 1 12 1 1 87.62 22.29 0.27 0.00654 0.00742 6 4 1 5 0 2698.180 26.32 20.00 22.29 18.76 16.0 1011.38 -78883 29410 -56708 104991 -123059 -88464 -52525 47591 -50774 -58288 900000 3391 900000 -36373 -13279 -43552 75828 96853 3868 66302 -35317 -37328 -14049 -1313 -27733 -5209 8697 -11251 -3417 8231 23392 -19543 -10088 11792 -14975 -1784 345 8504 12441 -4082 -8227 1413 8183 10044 3294 1497 -3181 -900 1075 -1257 865 11156 7757 1128 2233 2322 -1402 692 2205 469 2137 -1217 -2225 3700 1590 -1296 -2095 843 591 -262 2175 -737 -1078 -1491 4596 -2293 -2599 -3101 900 -2027 1066 -435 -2719 -415 816 850 -1604 -367 1690 -535 1086 748 -175 -687 -570 -282 -66 1734 -82 360 -657 279 -778 -952 -982 -1301 -1244 470 149 -23 313 695 121 -31 13 518 -542 -42 1024 202 -664 -283 540 -833 1406 560 -645 1435 623 353 -622 -683 -430 69 -429 6 135 255 218 -381 27 294 -255 -869 229 -588 816 -2104 -1146 -527 370 -641 -850 900000 33 900000 -792 -281 -1393 884 1004 105 1052 -1457 -1596 -508 -47 -1343 -212 322 -471 -137 322 924 -1326 -706 687 -1097 -117 25 681 1128 -516 -1203 200 1133 1394 496 234 -529 -150 183 -234 175 2251 1701 286 590 637 -409 197 602 130 606 -393 -817 1411 637 -517 -831 334 259 -128 1133 -412 -596 -784 2157 -1038 -1103 -1334 412 -1078 636 -298 -2007 -317 660 734 -1489 -335 1559 -485 902 581 -131 -526 -481 -271 -70 1990 -103 450 -782 310 -805 -991 -1095 -1541 -1504 596 205 -34 503 1135 198 -50 20 752 -793 -63 1625 329 -1093 -465 853 -1283 2023 806 -906 2021 942 577 -1120 -1272 -835 140 -908 14 300 576 496 -845 58 598 -519 SS 20230516T114438.2Z 8536.489331 120 1 48.75 2 74.46 78.10 57.79 117.25 0.00 1 0.00 1 0 17 1.449e-01 5.666e-03 9.263e-02 3.136e-03 5.155507e-01 1.671460e-03 5.911751e-03 -6.000000e+00 8.511922e-02 231.01 -2.00 3.54 -2.00 320.38 0.00e+00 2.038124e-03 6.057211e-04 5.353033e-04 -6.000000e+00 3.694259e-03 281.91 -2.00 20.00 -2.00 319.76 0.00e+00 3.665 0.001 302.00 328.00 3 3.3155e+00 5.0841e-03 4.5388e-02 -6.0000e+00 2.1313e-01 4.0031e-02 6.3071e-03 2.7658e-02 -6.0000e+00 2.3052e-01 -1.8105e-02 5.6316e-03 1.4201e-02 -6.0000e+00 1.3686e-01 -4.4362e-03 2.8344e-03 4.9716e-03 -6.0000e+00 5.7891e-02 2.8460e-04 2.1307e-04 9.4583e-05 5.5633e-05 -6.0000e+00 4.0921e-03 6.1229e-03 -1.3698e-05 10 0 0 10 0 0 86.71 22.29 0.29 0.00612 0.00772 46 10 1 5 0 1059.720 26.32 19.99 22.29 19.31 16.0 1014.81 -51030 -28688 -57779 -68561 -44632 65290 -58607 -31723 -31349 -19929 6748 -56269 -13414 -21813 4241 -4354 -10543 -6057 -5828 -5219 -9159 964 -6345 4277 -15855 -3136 -8587 -11277 -5571 -5786 -4322 -3187 821 -1052 -1995 -7205 -3608 -400 -2583 3170 -3456 -728 -839 -498 2177 959 -1675 989 954 1187 3339 1533 2736 1795 1283 2444 -748 1412 -504 1308 335 1441 151 3003 218 328 788 -571 1802 849 2053 395 704 518 -455 -1577 -266 -632 -403 -374 -664 -853 -2284 -1506 -1302 -638 -219 73 888 706 710 839 336 346 708 -332 473 357 -135 -311 -312 -655 -129 282 -872 -732 -1011 -898 -405 46 440 40 259 -49 -5 58 390 534 256 132 -366 19 283 188 116 493 -91 845 797 45 205 -638 -33 -143 -70 -183 -237 591 -47 -25 -173 -199 -116 -637 -322 -898 -1118 -535 290 -911 -429 -471 -284 77 -1284 -267 -539 106 -126 -357 -214 -219 -205 -381 37 -276 181 -877 -160 -465 -602 -278 -313 -266 -223 62 -84 -154 -598 -325 -42 -334 456 -545 -119 -143 -86 372 169 -306 179 178 234 709 365 697 497 375 730 -236 434 -154 392 106 493 59 1239 94 137 319 -239 806 437 1144 233 409 287 -233 -737 -114 -271 -190 -204 -418 -606 -1786 -1237 -1143 -594 -199 68 821 673 630 690 264 274 608 -327 493 420 -172 -394 -372 -718 -131 285 -958 -850 -1239 -1170 -566 70 724 65 415 -80 -8 84 565 804 410 223 -625 32 455 291 171 697 -125 1165 1198 76 348 -1157 -61 -282 -147 -406 -540 1364 -110 -56 -373 -409 -231 SS 20230516T115516.9Z 8536.496723 123 1 48.96 2 72.53 79.78 56.06 119.56 0.00 1 0.00 1 0 25 6.013e-02 5.162e-03 4.975e-02 2.742e-03 4.631850e-01 1.440347e-03 5.384117e-03 -6.000000e+00 3.531798e-02 231.01 -2.00 3.54 -2.00 319.87 0.00e+00 2.033732e-03 4.436096e-04 4.076485e-04 -6.000000e+00 1.533129e-03 281.91 -2.00 20.00 -2.00 319.22 0.00e+00 3.283 0.001 302.00 328.00 3 3.6516e+00 4.1815e-03 4.0670e-02 -6.0000e+00 8.8434e-02 3.6019e-02 5.0041e-03 2.4729e-02 -6.0000e+00 9.5650e-02 -1.0322e-02 4.1710e-03 1.2552e-02 -6.0000e+00 5.6790e-02 -7.6105e-03 2.1555e-03 4.3141e-03 -6.0000e+00 2.4018e-02 3.0926e-04 5.2678e-05 8.2535e-05 4.7379e-05 -6.0000e+00 1.6983e-03 6.6583e-03 -2.9440e-05 11 1 0 11 8 0 92.47 22.29 0.25 0.00666 0.00705 34 8 1 5 0 1439.570 26.32 20.00 22.29 19.68 16.1 1017.47 -35462 -7238 -18336 -14188 -6966 -16046 -5820 -6171 -34633 -6589 -26984 2012 -14636 5684 -8224 -3568 -1450 -6783 1894 -7598 3821 382 1772 -2948 1278 -4216 -8483 -4566 -5552 823 -901 2621 1902 538 -2363 -1221 -3287 869 -3783 -2039 -1715 -2360 511 -389 703 -847 347 25 -632 1090 -495 247 482 1544 732 1 1026 -591 1437 116 1534 1667 1560 2138 1371 313 1029 -272 386 997 212 1201 -254 1179 -36 -484 -691 -627 520 -1450 -778 -1083 -1601 -1629 -950 -752 -78 348 108 559 401 1243 700 431 230 78 365 663 -97 -412 -538 -960 -242 142 -788 -812 -851 -729 -293 425 513 441 -43 285 -96 282 327 33 178 -96 -435 108 174 -161 404 533 -4 829 374 6 5 -397 -74 19 73 225 -265 454 -108 -202 -77 -242 -150 -646 -111 -322 -224 -100 -243 -92 -105 -873 -133 -691 44 -455 176 -334 -157 -68 -364 99 -457 209 22 105 -197 87 -317 -665 -329 -396 59 -75 238 194 57 -247 -128 -396 119 -658 -390 -360 -528 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