File name: Pandora39s1_DearbornMI_20230713_L2Fit_fout2c1d20210608p1-8.txt File generation date: 20230714T211922.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v1d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20230713_L1_smca1c1d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20230713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230713T143852.6Z 8594.610331 309 1 48.84 2 42.56 104.40 19.78 198.27 0.00 1 0.00 1 0 17 1.848e-02 9.607e-03 1.151e-02 4.580e-03 2.065508e-01 2.379892e-03 2.514468e-03 -6.000000e+00 1.093343e-02 232.91 -2.00 3.54 -2.00 316.95 0.00e+00 7.452372e-05 3.094364e-04 1.849660e-04 -6.000000e+00 4.826471e-04 287.59 -2.00 20.00 -2.00 316.13 0.00e+00 1.356 0.000 302.00 328.00 3 6.0919e+00 6.3050e-03 1.7394e-02 -6.0000e+00 2.7453e-02 3.9549e-02 7.0464e-03 1.0980e-02 -6.0000e+00 2.9620e-02 2.3358e-03 4.1078e-03 5.3074e-03 -6.0000e+00 1.7618e-02 -6.7985e-03 1.9481e-03 1.4591e-03 -6.0000e+00 7.4622e-03 2.4650e-04 -8.5189e-07 1.3742e-04 1.8018e-05 -6.0000e+00 5.2237e-04 6.4294e-03 -4.6852e-05 12 9 8 11 8 0 99.95 22.28 0.39 0.00643 0.00642 63 14 1 5 0 775.100 26.32 20.00 22.28 25.92 17.2 1007.90 4847 -3802 3726 -1236 -1046 2404 -4029 1736 -4113 3565 -689 4739 -4721 2091 1173 -1798 1688 -2827 6113 -2014 2924 -2257 3654 -1826 853 148 -1537 1308 -2174 4583 -3371 2800 -344 -2386 -5136 -2306 -2874 -2807 936 -2067 840 -3013 387 -1221 384 -1135 -675 707 -2400 1983 -651 2052 591 1228 324 2707 1229 253 1644 -540 2333 -550 2545 959 220 -37 81 587 886 1176 -1256 1671 -490 885 -136 484 387 -1500 941 -2041 -79 -2092 -927 -1834 -441 -619 382 319 -418 976 -849 1278 -1422 867 -641 -10 310 229 673 -1265 288 -1309 -159 -156 -887 -1752 -816 -444 -879 1229 698 719 -185 690 -1068 104 -478 -281 1041 -141 588 -131 1211 -197 290 570 386 1377 308 611 -195 331 -734 270 23 281 37 429 -78 -666 487 -915 -794 729 -658 590 -186 -142 311 -599 272 -744 611 -121 820 -997 464 293 -493 459 -828 1689 -621 863 -697 1097 -607 288 52 -533 409 -656 1281 -1069 886 -120 -843 -1744 -764 -1058 -1204 460 -1155 490 -1894 240 -773 238 -734 -423 422 -1437 1141 -403 1313 403 870 238 1965 916 189 1191 -400 1736 -451 2092 839 189 -30 62 433 692 1027 -1177 1582 -473 843 -122 387 280 -1047 665 -1650 -69 -2066 -962 -1938 -492 -740 476 410 -543 1203 -985 1373 -1432 817 -638 -10 369 289 891 -1681 355 -1582 -180 -181 -1124 -2282 -1101 -624 -1293 1867 1115 1159 -290 997 -1494 135 -612 -372 1454 -206 878 -196 1754 -289 400 745 481 1675 397 832 -281 487 -1109 401 35 462 63 745 -139 -1163 814 -1505 -1271 SS 20230713T154919.3Z 8594.659251 352 1 7.61 2 30.65 123.44 27.33 233.92 0.00 1 0.00 1 0 17 8.212e-03 6.448e-03 2.326e-03 1.602e-03 1.722717e-01 8.481538e-04 2.094581e-03 -6.000000e+00 4.859995e-03 232.91 -2.00 3.54 -2.00 314.92 0.00e+00 3.282404e-04 7.129642e-05 2.844757e-05 -6.000000e+00 2.144472e-04 287.60 -2.00 20.00 -2.00 314.25 0.00e+00 1.162 0.000 302.00 328.00 3 3.9355e+00 2.1942e-03 1.4689e-02 -6.0000e+00 1.2203e-02 1.9171e-02 2.4238e-03 9.0727e-03 -6.0000e+00 1.3165e-02 -6.7624e-04 1.3856e-03 4.3887e-03 -6.0000e+00 7.8308e-03 -3.5169e-03 6.0691e-04 1.2075e-03 -6.0000e+00 3.3177e-03 2.7772e-03 2.9847e-04 4.6729e-05 1.6613e-05 -6.0000e+00 2.3209e-04 5.3114e-03 -6.8842e-06 12 9 1 12 1 1 99.93 22.27 0.27 0.00531 0.00755 15 23 1 5 0 464.580 26.32 19.99 22.27 28.67 17.3 1024.86 -379 -967 -521 -3733 -652 -739 -42 915 428 -1077 -909 -300 -903 -61 421 -510 -162 620 1353 1264 1068 586 1480 11 119 778 63 55 187 1585 1601 1494 1034 -1491 -1963 -1737 -1645 -829 -240 -955 -803 -539 -454 -1065 -38 -537 -606 -203 -641 364 598 500 893 810 245 1172 972 280 464 581 1082 1108 1666 1265 -358 -262 246 -609 1030 603 -187 183 -173 619 74 -279 -114 -653 -108 -929 -1306 -1169 -2172 -1395 -613 -786 -243 -226 192 43 230 451 -209 688 444 -44 495 751 68 -638 -340 -1009 -125 465 -500 -1202 -563 -433 -316 438 289 237 217 325 24 437 551 321 547 209 -452 175 396 102 602 553 208 865 662 -2 313 -224 -82 -22 280 -46 -406 326 -126 -332 -142 -574 -594 -132 -331 -188 -1255 -190 -213 -13 307 157 -408 -335 -113 -351 -26 199 -240 -78 302 671 644 548 299 768 6 68 449 36 29 91 804 788 775 569 -836 -1031 -911 -951 -518 -167 -719 -647 -448 -384 -909 -32 -448 -491 -158 -512 287 464 410 764 722 213 1022 858 247 402 503 965 1055 1606 1277 -358 -252 217 -553 921 576 -196 189 -179 646 73 -259 -100 -546 -93 -842 -1318 -1224 -2321 -1550 -690 -949 -294 -283 240 54 267 498 -222 689 462 -48 587 932 85 -794 -417 -1158 -142 539 -604 -1483 -722 -579 -421 608 402 332 303 440 30 526 654 396 688 284 -613 235 544 134 783 684 245 1045 798 -2 400 -295 -109 -31 385 -67 -588 480 -190 -492 -203 -836 -845 SS 20230713T155415.4Z 8594.662679 356 1 3.26 2 29.90 125.15 28.05 235.73 0.00 1 0.00 1 0 17 9.172e-03 7.264e-03 4.475e-03 3.184e-03 1.722326e-01 1.689987e-03 2.071395e-03 -6.000000e+00 5.431001e-03 232.91 -2.00 3.54 -2.00 314.76 0.00e+00 1.810050e-04 1.385325e-04 3.523761e-05 -6.000000e+00 2.395049e-04 287.60 -2.00 20.00 -2.00 314.12 0.00e+00 1.153 0.000 302.00 328.00 3 2.9197e+00 4.3655e-03 1.4582e-02 -6.0000e+00 1.3637e-02 2.3250e-02 4.8210e-03 8.9950e-03 -6.0000e+00 1.4710e-02 -9.9724e-04 2.7547e-03 4.3510e-03 -6.0000e+00 8.7498e-03 -4.4477e-03 1.2006e-03 1.1876e-03 -6.0000e+00 3.7086e-03 7.7314e-03 6.5531e-04 9.2652e-05 1.6631e-05 -6.0000e+00 2.5919e-04 4.5266e-03 8.7010e-05 12 9 1 12 1 1 99.10 22.27 0.25 0.00453 0.00945 3 14 2 5 0 771.150 26.32 20.00 22.27 28.93 17.5 1027.22 -1262 -841 -2027 -1862 -1098 -1287 -979 1143 2177 -891 -1159 -1337 -372 -621 -331 -1676 1088 739 1502 1989 1308 765 604 954 751 -543 303 783 342 902 1808 1005 2118 -1475 -2028 -1475 -1458 -1254 -38 -787 -905 -664 -301 -1142 -270 -457 -763 79 -834 802 492 1018 681 1251 765 909 641 -85 896 1233 569 1509 1688 887 -94 -295 -491 -749 945 532 125 -306 -460 281 34 329 -468 -1066 181 -1247 -1587 -1287 -2515 -1217 -789 -567 -341 -324 159 215 843 -223 114 817 948 334 254 663 -363 -589 -405 -631 -167 375 -317 -1253 -577 -545 -808 816 736 185 52 37 150 309 1151 560 462 267 -100 474 -12 250 321 799 -17 1014 573 75 -97 -415 351 -229 340 -69 -256 226 -442 23 -451 -374 -714 -456 -318 -762 -655 -343 -411 -321 408 805 -346 -440 -524 -153 -276 -157 -854 550 384 795 1040 692 403 327 538 427 -319 173 424 178 459 946 541 1191 -854 -1102 -822 -867 -814 -27 -617 -743 -547 -252 -968 -225 -378 -629 64 -657 620 398 843 577 1099 673 810 579 -77 788 1108 519 1422 1661 897 -94 -281 -443 -673 859 518 131 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