File name: Pandora39s1_DearbornMI_20230720_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T004551.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20230720_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20230720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230720T112822.7Z 8601.478040 79 1 48.56 2 78.15 72.76 102.69 54.23 0.00 1 0.00 1 0 17 4.767e-01 1.505e-02 3.729e-01 1.477e-02 6.492792e-01 8.427091e-03 7.951420e-03 -6.000000e+00 2.870925e-01 232.75 -2.00 3.54 -2.00 321.37 0.00e+00 8.798095e-03 4.268156e-03 4.476959e-03 -6.000000e+00 1.393416e-02 287.91 -2.00 20.00 -2.00 320.77 0.00e+00 4.717 0.002 302.00 328.00 3 4.1806e+00 3.0184e-02 6.0494e-02 -6.0000e+00 7.2531e-01 8.7674e-02 4.1190e-02 4.0539e-02 -6.0000e+00 7.8613e-01 -8.6642e-02 3.9140e-02 2.4816e-02 -6.0000e+00 4.6201e-01 1.6759e-02 1.8423e-02 1.0147e-02 -6.0000e+00 1.9463e-01 3.8080e-05 2.3125e-04 4.4824e-04 1.7086e-04 -6.0000e+00 1.3940e-02 1.0718e-02 9.6892e-06 12 8 8 10 0 0 99.95 22.27 0.49 0.01072 0.01246 23 5 1 5 0 2110.840 26.32 20.00 22.27 28.96 17.5 1021.77 -60295 -193867 900000 -172836 -189656 1418 900000 900000 -125286 -205101 900000 900000 -150050 -133871 -85416 5465 -110815 900000 -44915 900000 -52376 -77562 -54353 -66458 117798 8281 -29522 -38482 70276 -22980 -14298 122604 7363 -14254 -1518 32197 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1055 -445 -350 -3048 -1615 -382 27 -906 492 -1160 -3472 -1121 601 -1544 1182 -1582 -1627 77 1281 -578 -1250 364 15 510 991 1164 -1237 2915 -1360 -1087 1851 1546 885 91 3112 -205 -333 446 -1378 881 1101 -346 -1361 140 1434 138 2990 -1616 -1354 -872 -484 -1047 SS 20230720T113802.0Z 8601.484746 85 1 13.66 2 76.44 74.27 101.29 56.02 0.00 1 0.00 1 0 17 4.160e-01 1.575e-02 3.370e-01 1.177e-02 5.702669e-01 6.387220e-03 6.889141e-03 -6.000000e+00 2.475130e-01 232.75 -2.00 3.54 -2.00 320.61 0.00e+00 3.264864e-03 2.575847e-03 3.136997e-03 -6.000000e+00 1.133734e-02 287.91 -2.00 20.00 -2.00 319.93 0.00e+00 4.162 0.001 302.00 328.00 3 4.1468e+00 2.0299e-02 5.2788e-02 -6.0000e+00 6.2349e-01 6.5485e-02 2.5879e-02 3.5028e-02 -6.0000e+00 6.7365e-01 -1.0058e-01 2.3186e-02 1.7764e-02 -6.0000e+00 3.9804e-01 3.8716e-02 1.1502e-02 5.0626e-03 -6.0000e+00 1.6836e-01 7.3437e-05 5.4921e-04 3.4854e-04 8.4712e-05 -6.0000e+00 1.1920e-02 7.0974e-03 9.5966e-05 12 9 9 12 1 1 99.80 22.28 0.34 0.00710 0.01122 4 4 1 5 0 2698.610 26.32 20.00 22.28 29.25 17.4 1023.69 -120262 -96743 -119358 -82388 -65436 -11138 75403 900000 -86520 900000 -24980 108975 8363 -48120 91945 10511 18523 -48442 231436 -43080 186786 -28566 159837 12348 -28826 41361 -9627 77916 -41578 108114 18864 -20265 10641 25419 12556 -18453 5973 -9300 6995 -20446 4972 865 1067 3934 4580 8200 -12365 18842 3644 8574 4884 -1094 6328 -357 3190 4577 4263 -4865 11682 -16405 12564 1658 -289 4051 713 6014 1955 3046 487 6022 746 -243 1917 -686 570 -2515 -2736 -7307 4471 -7341 989 -752 -1269 -1277 -1122 -917 -1148 3692 -1150 4608 -1835 -325 1135 294 -1548 -1455 1584 -1496 1446 -1434 -182 -2151 -968 -675 -1348 449 -886 58 -444 775 -545 491 26 777 72 275 928 963 2506 -382 261 -827 -980 -671 -53 2435 715 2050 -757 975 -710 -794 -1278 -547 -22 -95 454 226 714 -943 364 -620 404 -2127 -1526 -2453 -1151 -751 -128 865 900000 -1572 900000 -287 1250 100 -1219 1055 211 381 -2045 2655 -1937 2143 -1141 1834 390 -1402 1087 -423 1438 -2328 1618 776 -1376 601 1283 691 -1414 403 -871 677 -2950 616 119 153 562 661 1165 -2193 2511 587 1404 918 -232 1358 -88 802 1177 1125 -1397 2780 -5151 3086 500 -100 1482 278 2149 716 1135 205 2738 378 -129 987 -344 268 -1099 -1120 -3155 1902 -3964 569 -499 -920 -948 -892 -776 -1023 3225 -1055 3843 -1521 -256 842 223 -1275 -1369 1605 -1776 1799 -1774 -216 -2383 -1012 -707 -1473 511 -1077 74 -602 1144 -863 809 43 1226 112 405 1355 1463 3852 -634 432 -1347 -1548 -1051 -78 3397 980 2834 -1183 1612 -1261 -1503 -2543 -1103 -47 -209 1019 519 1638 -2131 793 -1295 830 SS 20230720T114759.9Z 8601.491666 88 1 49.06 2 74.66 75.83 99.82 57.83 0.00 1 0.00 1 0 17 9.039e-02 4.858e-03 4.040e-02 1.408e-03 5.180185e-01 7.591738e-04 5.980102e-03 -6.000000e+00 5.345331e-02 232.75 -2.00 3.54 -2.00 320.38 0.00e+00 2.014757e-03 2.799208e-04 6.215811e-04 -6.000000e+00 2.363743e-03 287.91 -2.00 20.00 -2.00 319.67 0.00e+00 3.709 0.001 302.00 328.00 3 1.8146e+00 2.3458e-03 4.6038e-02 -6.0000e+00 1.3415e-01 1.9642e-03 2.9269e-03 2.8068e-02 -6.0000e+00 1.4474e-01 -4.0612e-03 2.5606e-03 1.4331e-02 -6.0000e+00 8.6125e-02 -1.2194e-02 1.2876e-03 4.8502e-03 -6.0000e+00 3.6501e-02 1.2436e-03 1.8318e-04 4.2318e-05 5.6378e-05 -6.0000e+00 2.5548e-03 8.0104e-03 2.6414e-05 10 0 0 10 0 0 93.61 22.28 0.26 0.00801 0.00939 229 51 1 5 0 214.220 26.32 20.00 22.28 29.93 17.4 1027.81 -28271 -35130 -32477 -25334 -26351 -22415 -27162 -36605 -29193 -31112 -29583 -8453 -19405 -13985 -15222 1468 -10856 -2050 -4582 1606 -2400 -3500 -2007 -6556 -3009 -8266 -2387 -8205 -1816 -4418 -3621 34 -68 -2221 -4403 -3009 -6141 -325 -1719 -673 -1589 -945 -595 -1649 485 -750 1739 509 -642 -101 771 1005 1226 1770 -111 972 75 1151 -518 396 1376 1596 2266 1555 685 212 1087 -529 1407 647 431 684 258 599 120 -129 -1108 -1126 -714 -1280 -899 -1013 -2129 -1548 -681 -561 439 271 973 758 902 776 180 475 -67 -174 264 851 -8 -302 -405 -765 -373 198 -838 -1260 -686 -695 -154 338 258 119 116 226 -83 280 281 267 329 -4 -534 15 339 2 283 164 -248 950 562 -112 215 -394 -155 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