File name: Pandora39s1_DearbornMI_20230725_L2Fit_fout2c1d20210608p1-8.txt File generation date: 20230728T065304.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v1d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20230725_L1_smca1c1d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20230725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230725T114952.4Z 8606.492968 87 1 48.03 2 75.01 76.90 146.94 21.33 0.00 1 0.00 1 0 17 2.318e-01 9.219e-03 1.974e-01 6.812e-03 5.632782e-01 3.735298e-03 6.470669e-03 -6.000000e+00 1.377280e-01 232.57 -2.00 3.54 -2.00 320.69 0.00e+00 4.004001e-03 1.535860e-03 1.213359e-03 -6.000000e+00 6.713008e-03 288.01 -2.00 20.00 -2.00 320.01 0.00e+00 3.789 0.001 302.00 328.00 3 4.3630e+00 1.1985e-02 4.8181e-02 -6.0000e+00 3.4605e-01 7.2549e-02 1.5382e-02 3.0524e-02 -6.0000e+00 3.7394e-01 -5.8017e-02 1.3884e-02 1.6832e-02 -6.0000e+00 2.2125e-01 7.4263e-03 6.8523e-03 6.9086e-03 -6.0000e+00 9.4135e-02 8.2561e-05 6.2400e-04 2.0589e-04 8.1041e-05 -6.0000e+00 6.7507e-03 9.7283e-03 8.9580e-05 11 8 0 10 0 0 32.29 22.31 0.48 0.00973 0.01442 16 4 1 5 0 3001.300 26.32 20.00 22.31 29.37 17.5 1021.76 -102613 -12249 -88283 900000 900000 -88144 104910 -116162 900000 -1588 900000 -95148 -6179 -10654 -17120 -576 -33641 23359 -40327 35298 -8966 3249 -4805 -12 -5021 -23091 -12567 -28216 -12178 -38891 36806 -8851 2611 -15864 -1783 -5948 -8850 9716 -9707 3528 -219 1242 -2084 -633 12231 -10093 3204 -6573 3994 3858 15038 -1779 6283 8112 335 -270 486 3054 -3951 3657 669 4077 3007 2370 228 -42 3209 -1927 2876 -1217 1512 2119 2557 2138 -1370 2592 -1081 -416 -2240 -61 -1800 580 -2288 -2684 -508 -210 -411 -941 1706 -634 611 -494 334 63 305 74 -1509 1195 -443 856 -1522 -282 -281 563 -1475 -305 201 -910 -326 242 817 -212 523 -267 -296 128 -459 -96 -138 108 -621 994 89 678 635 886 -337 109 732 -609 167 -590 345 63 46 441 -62 418 188 -126 -460 -335 -463 -1362 -81 -1197 900000 900000 -1073 696 -2313 900000 -12 900000 -2237 -78 -171 -360 -12 -1036 465 -1563 703 -283 92 -156 0 -179 -1030 -507 -1289 -475 -2189 1191 -505 150 -1137 -107 -379 -653 709 -1006 376 -27 160 -291 -89 1540 -1623 459 -1066 605 625 2407 -372 1317 1800 84 -71 129 784 -1064 911 180 1168 980 856 86 -15 1120 -728 1139 -573 757 1095 1298 1031 -626 1026 -415 -160 -973 -30 -1051 360 -1586 -1978 -392 -172 -354 -838 1478 -541 478 -364 242 45 238 66 -1572 1374 -537 1019 -1811 -302 -278 556 -1592 -344 238 -1162 -431 351 1287 -354 862 -426 -444 182 -657 -142 -218 178 -1032 1582 138 1009 903 1252 -465 153 1084 -1015 301 -1098 665 128 100 1004 -141 965 436 -285 -1022 -707 -945 SS 20230725T120110.2Z 8606.500813 90 1 49.01 2 72.97 78.67 146.18 25.96 0.00 1 0.00 1 0 17 9.799e-02 5.735e-03 8.547e-02 3.194e-03 5.083498e-01 1.694569e-03 5.831362e-03 -6.000000e+00 5.790056e-02 232.57 -2.00 3.54 -2.00 320.28 0.00e+00 1.148486e-03 6.142503e-04 7.411017e-04 -6.000000e+00 2.563442e-03 288.01 -2.00 20.00 -2.00 319.56 0.00e+00 3.362 0.001 302.00 328.00 3 3.6520e+00 5.1794e-03 4.3002e-02 -6.0000e+00 1.4524e-01 1.2845e-02 6.4435e-03 2.7376e-02 -6.0000e+00 1.5673e-01 -5.2954e-03 5.5611e-03 1.3766e-02 -6.0000e+00 9.3280e-02 -1.0309e-02 2.8085e-03 4.1457e-03 -6.0000e+00 3.9545e-02 2.7341e-04 4.6680e-04 9.6090e-05 4.8500e-05 -6.0000e+00 2.7694e-03 9.9947e-03 6.9838e-05 11 1 0 11 8 0 65.13 22.31 0.28 0.00999 0.01350 41 9 1 5 0 1195.100 26.32 20.00 22.31 30.55 17.6 1029.23 -63015 -41547 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566 -15 594 -101 -301 -782 -426 -580 -508 -817 -124 -1418 -969 -532 -1006 858 181 684 922 895 772 -382 185 250 -247 347 701 -191 -562 -357 -1023 -779 112 -678 -1794 -275 -1104 -145 607 425 419 225 835 -483 146 871 82 602 126 -998 -309 943 -284 264 564 341 470 883 296 261 -226 -739 -687 -480 -114 -586 2138 -204 4 -40 -431 -572 SS 20230725T120821.5Z 8606.505805 94 1 49.46 2 71.66 79.80 145.62 28.81 0.00 1 0.00 1 0 17 7.362e-02 5.538e-03 4.597e-02 2.304e-03 4.750884e-01 1.220412e-03 5.499497e-03 -6.000000e+00 4.350346e-02 232.57 -2.00 3.54 -2.00 319.96 0.00e+00 1.449260e-03 3.948714e-04 4.179367e-04 -6.000000e+00 1.925891e-03 288.01 -2.00 20.00 -2.00 319.21 0.00e+00 3.137 0.001 302.00 328.00 3 3.4080e+00 3.5906e-03 4.0125e-02 -6.0000e+00 1.0912e-01 1.0570e-02 4.3601e-03 2.5468e-02 -6.0000e+00 1.1776e-01 -7.2772e-03 3.6043e-03 1.2754e-02 -6.0000e+00 7.0084e-02 -8.2873e-03 1.8497e-03 4.0451e-03 -6.0000e+00 2.9714e-02 4.4875e-04 3.3922e-04 6.9445e-05 4.5019e-05 -6.0000e+00 2.0806e-03 9.4558e-03 6.6330e-05 10 0 0 10 0 0 64.76 22.31 0.40 0.00946 0.01200 58 13 1 5 0 852.590 26.32 20.00 22.31 31.33 17.9 1034.26 -3279 -37688 -26421 -21064 -13344 -19085 -48206 -7589 -23351 -13365 -25091 2021 -2647 1271 1237 -3418 -5921 1094 8696 3721 4731 -257 65 -2981 -1866 -2317 -5668 -7108 -8805 221 -4374 756 -3973 -2350 -2918 -4761 -3469 -3796 -851 -1591 -1390 -1198 -324 -1340 6 -871 -1392 1130 -1129 906 265 1568 915 2057 723 1512 672 -729 26 461 1257 1329 1738 1874 861 479 441 273 646 1260 -24 668 734 820 438 120 -989 -1231 -375 -1336 -1329 -888 -2227 -1531 -1016 -438 127 847 647 714 505 1051 112 450 183 -148 88 833 34 -576 -177 -997 -402 405 -913 -1233 -773 -748 -282 629 284 269 -105 119 -59 339 555 212 148 -308 -272 -151 492 -31 329 248 -41 1097 632 -55 272 -230 -281 -50 231 -83 -235 509 -160 -184 109 -206 -332 -38 -678 -437 -310 -169 -261 -975 -116 -468 -257 -564 39 -65 37 43 -142 -275 51 401 189 243 -14 4 -191 -126 -165 -417 -507 -626 15 -363 68 -382 -229 -298 -464 -375 -490 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