File name: Pandora39s1_DearbornMI_20231007_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T012443.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20231007_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20231007 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231007T133549.6Z 8680.566547 296 1 49.27 2 69.83 118.26 22.47 229.63 0.00 1 0.00 1 0 17 3.051e-02 5.399e-03 4.163e-03 3.641e-04 4.142147e-01 1.864380e-04 4.923241e-03 -6.000000e+00 1.763017e-02 226.58 -2.00 3.54 -2.00 319.31 0.00e+00 1.059000e-03 4.898837e-05 2.141431e-04 -6.000000e+00 7.822390e-04 283.25 -2.00 20.00 -2.00 318.61 0.00e+00 2.869 0.000 302.00 328.00 3 3.7205e-01 5.2271e-04 3.5439e-02 -6.0000e+00 4.3659e-02 3.3935e-03 6.1204e-04 2.1605e-02 -6.0000e+00 4.7364e-02 -1.6915e-03 4.6728e-04 1.0796e-02 -6.0000e+00 2.8246e-02 -8.7607e-03 2.4567e-04 3.2873e-03 -6.0000e+00 1.2075e-02 1.3254e-02 -1.7328e-04 1.0911e-05 3.7809e-05 -6.0000e+00 8.6076e-04 6.2108e-03 -3.8826e-05 10 0 0 10 0 0 99.76 22.30 0.24 0.00621 0.00491 1468 327 1 5 0 33.440 26.32 20.00 22.30 16.64 17.7 930.21 -11380 -3719 -10019 -8939 -12178 -11076 -9802 -9310 -6532 -11154 -7194 -9117 -3568 -5558 -1227 -3121 -1514 -1309 -1383 499 -1835 66 -1300 -682 -2104 -1383 -2705 -2564 -1597 -1418 141 -308 1457 -2956 -2714 -2717 -3235 -2140 -1338 -997 -1679 -682 -995 -589 91 37 -310 -139 -294 452 1253 449 1485 1135 928 1144 838 296 407 701 1017 1612 1819 1908 403 553 462 -462 1068 465 327 482 207 441 152 -143 -395 -929 -310 -895 -1177 -1049 -2193 -1407 -925 -562 -129 207 538 467 643 694 158 507 478 -25 380 756 -2 -422 -333 -802 -499 347 -832 -1311 -719 -695 -258 370 311 94 161 82 22 264 464 177 284 -65 -600 68 251 153 375 475 -124 1219 747 70 232 -294 -46 -57 142 -182 -248 490 -96 -250 -70 -213 -342 -286 -95 -280 -230 -298 -271 -260 -278 -211 -397 -253 -363 -160 -306 -76 -222 -114 -106 -108 40 -153 5 -114 -64 -212 -144 -285 -256 -167 -142 16 -38 198 -429 -374 -379 -507 -393 -294 -256 -476 -202 -307 -183 28 12 -97 -44 -94 149 444 174 613 502 428 543 407 144 193 330 496 851 977 1107 240 311 250 -253 625 310 239 366 156 318 101 -86 -219 -551 -182 -604 -908 -903 -2060 -1285 -900 -583 -140 230 597 500 637 684 146 465 471 -26 441 979 -2 -548 -436 -970 -561 391 -1021 -1712 -980 -936 -369 569 515 151 272 131 32 371 645 256 437 -107 -999 111 397 233 542 657 -178 1732 1072 110 392 -492 -79 -102 269 -367 -485 971 -192 -491 -138 -407 -634 SS 20231007T135243.7Z 8680.578283 306 1 49.35 2 67.12 121.72 24.94 236.54 0.00 1 0.00 1 0 17 1.785e-02 5.266e-03 4.142e-03 4.846e-04 3.704292e-01 2.468614e-04 4.391833e-03 -6.000000e+00 1.031411e-02 226.57 -2.00 3.54 -2.00 319.08 0.00e+00 7.541693e-04 5.932223e-05 1.883253e-04 -6.000000e+00 4.575863e-04 283.25 -2.00 20.00 -2.00 318.36 0.00e+00 2.552 0.000 302.00 328.00 3 1.0703e+00 6.8304e-04 3.1526e-02 -6.0000e+00 2.5542e-02 -1.7470e-03 7.9192e-04 1.9188e-02 -6.0000e+00 2.7708e-02 7.7273e-03 5.7265e-04 9.5539e-03 -6.0000e+00 1.6525e-02 -1.2070e-02 3.0055e-04 2.8368e-03 -6.0000e+00 7.0646e-03 9.4276e-03 -4.1621e-05 1.4747e-05 3.2002e-05 -6.0000e+00 5.0351e-04 5.9621e-03 -3.0079e-05 10 0 0 10 0 0 99.99 22.30 0.22 0.00596 0.00565 1488 331 1 5 0 32.980 26.32 20.00 22.30 17.90 17.9 938.28 -4069 -2705 -4812 -5882 -5383 -6686 -5503 -5855 -3342 -6851 -5754 -3780 -2877 -2575 -926 -1239 -953 295 -155 757 25 365 972 -313 -860 -896 -1431 -1558 -1376 71 -49 754 534 -2471 -2863 -2017 -2809 -1803 -1047 -1098 -1527 -680 -556 -669 303 -140 -265 -131 -289 270 983 458 1082 1061 764 1068 639 297 448 700 1201 1648 1898 1798 288 264 377 -442 1106 478 211 540 140 616 119 -147 -342 -804 -221 -898 -1150 -1158 -2092 -1520 -789 -611 -50 142 563 430 557 686 154 598 514 78 440 831 -43 -455 -273 -894 -475 299 -796 -1278 -674 -599 -253 432 288 179 167 115 -42 241 362 120 306 -51 -580 25 241 106 381 421 -179 1086 685 109 198 -285 -100 -47 178 -120 -191 489 -104 -216 -66 -232 -371 -141 -101 -186 -214 -179 -226 -201 -243 -150 -306 -282 -182 -162 -171 -71 -105 -86 28 -16 78 3 39 107 -37 -109 -119 -189 -195 -165 9 -7 113 88 -426 -470 -333 -520 -390 -271 -331 -506 -235 -199 -242 109 -51 -96 -47 -104 100 390 183 458 477 358 513 314 145 215 334 592 876 1106 1127 183 159 216 -254 677 333 161 428 111 463 83 -93 -198 -456 -133 -620 -903 -1012 -1985 -1512 -774 -640 -55 160 633 465 558 681 144 545 501 79 500 1049 -58 -614 -347 -1053 -521 331 -958 -1637 -900 -844 -377 642 459 294 269 174 -64 343 509 176 475 -79 -917 39 389 165 562 594 -244 1462 991 172 312 -471 -171 -83 332 -237 -388 1011 -205 -442 -130 -438 -682 SS 20231007T135726.3Z 8680.581554 309 1 49.35 2 66.39 122.71 25.67 238.27 0.00 1 0.00 1 0 17 1.647e-02 5.199e-03 4.373e-03 5.157e-04 3.602893e-01 2.634653e-04 4.294736e-03 -6.000000e+00 9.518808e-03 226.57 -2.00 3.54 -2.00 319.07 0.00e+00 6.601322e-04 6.295202e-05 1.844494e-04 -6.000000e+00 4.222572e-04 283.25 -2.00 20.00 -2.00 318.35 0.00e+00 2.478 0.000 302.00 328.00 3 1.1482e+00 7.2802e-04 3.0667e-02 -6.0000e+00 2.3572e-02 -4.7078e-03 8.4252e-04 1.8719e-02 -6.0000e+00 2.5572e-02 1.2056e-02 6.0344e-04 9.2935e-03 -6.0000e+00 1.5250e-02 -1.3878e-02 3.1578e-04 2.7265e-03 -6.0000e+00 6.5202e-03 9.4874e-03 2.6693e-05 1.5712e-05 3.2037e-05 -6.0000e+00 4.6464e-04 5.8037e-03 -1.7174e-05 10 0 0 10 0 0 99.99 22.30 0.22 0.00580 0.00600 1854 413 1 5 0 26.470 26.32 19.99 22.30 18.02 17.8 938.33 -2550 -2095 -3604 -6427 -7981 -3386 -5303 -4270 -5635 -4571 -4984 -2798 -2369 -1867 -826 -1910 352 111 627 732 -19 290 414 -149 -452 -306 -1702 -1508 -1767 480 281 1073 1186 -2393 -2380 -1862 -2346 -1589 -958 -1296 -1449 -842 -744 -734 -135 -296 -474 96 -493 521 769 397 1018 952 633 986 744 283 503 490 1125 1392 1836 1696 213 369 329 -313 973 583 183 368 19 564 152 -160 -167 -855 23 -912 -1196 -1117 -2163 -1488 -845 -573 -28 213 547 465 628 732 151 621 532 -91 458 796 -24 -507 -276 -885 -487 315 -735 -1285 -677 -586 -276 447 331 162 142 127 -24 234 412 138 329 -40 -508 -51 259 17 324 425 -235 1144 632 84 215 -260 -147 -31 163 -142 -160 482 -102 -226 -48 -254 -301 -87 -77 -137 -233 -270 -110 -192 -173 -256 -215 -240 -144 -142 -131 -67 -174 33 11 66 80 -2 32 49 -19 -61 -42 -238 -199 -224 61 40 166 201 -429 -404 -319 -450 -356 -238 -375 -459 -279 -255 -254 -47 -103 -164 33 -169 183 289 162 441 438 304 484 373 142 246 239 567 757 1092 1083 138 225 191 -182 603 410 141 295 15 430 107 -102 -98 -490 14 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