File name: Pandora39s1_DearbornMI_20231021_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T012753.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20231021_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20231021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231021T133222.0Z 8694.564144 89 1 45.48 2 73.82 121.74 147.04 74.94 0.00 1 0.00 1 0 17 4.316e-02 4.892e-03 1.382e-02 7.600e-04 4.557978e-01 3.902575e-04 5.325662e-03 -6.000000e+00 2.481087e-02 225.11 -2.00 3.54 -2.00 319.93 0.00e+00 1.767869e-03 1.242375e-04 2.394426e-04 -6.000000e+00 1.098368e-03 281.51 -2.00 20.00 -2.00 319.29 0.00e+00 3.529 0.001 302.00 328.00 3 7.7905e-01 1.1296e-03 4.1743e-02 -6.0000e+00 6.1274e-02 2.0086e-02 1.3654e-03 2.3798e-02 -6.0000e+00 6.6554e-02 1.7450e-03 1.1576e-03 1.2105e-02 -6.0000e+00 3.9694e-02 -1.3474e-02 6.0012e-04 4.1644e-03 -6.0000e+00 1.7001e-02 4.5169e-03 -1.8772e-04 2.3040e-05 4.5317e-05 -6.0000e+00 1.2169e-03 3.7273e-03 -2.8455e-05 12 1 1 12 1 1 99.99 22.16 0.23 0.00373 0.00232 903 217 1 5 0 50.300 26.21 20.00 22.16 15.35 17.9 929.06 -12228 -11071 -15357 -9136 -16861 -19566 -14075 -13881 -13369 -11959 -15236 -8800 -7450 -5108 -3851 -2522 -2616 387 1194 59 -81 -1771 -615 170 -2716 -1047 -2698 -4528 -3756 -1224 -785 266 829 -2149 -2578 -2233 -3091 -1960 -1333 -1774 -1689 -820 -950 -696 -41 228 -220 191 -476 746 1233 350 1124 1111 728 938 381 15 87 436 1103 1452 1805 1919 452 280 603 -261 1206 769 380 601 186 562 133 -386 -421 -1134 -416 -975 -1236 -1052 -2076 -1438 -836 -475 57 327 804 731 718 709 121 564 381 -109 488 861 73 -412 -222 -784 -413 369 -395 -1338 -833 -706 -260 479 199 116 121 98 -42 273 427 159 246 -143 -555 -18 296 42 251 353 -243 1046 598 -7 57 -314 -144 -117 79 -148 -202 517 -22 -143 15 -134 -230 -178 -178 -266 -139 -257 -311 -232 -259 -277 -259 -353 -215 -218 -178 -159 -108 -122 19 62 3 -5 -101 -37 11 -190 -75 -197 -323 -260 -88 -64 24 84 -231 -266 -233 -364 -270 -221 -347 -365 -186 -225 -168 -10 56 -54 47 -121 196 327 103 352 373 257 341 142 6 32 158 413 591 814 942 229 136 281 -124 614 448 243 400 123 354 77 -203 -205 -550 -217 -590 -858 -818 -1767 -1285 -742 -449 56 332 813 713 651 638 103 478 349 -106 533 1055 97 -547 -277 -904 -440 393 -455 -1650 -1074 -965 -379 707 319 193 200 154 -62 404 626 242 374 -229 -908 -29 457 67 380 514 -342 1464 911 -10 97 -566 -268 -229 162 -305 -428 1111 -47 -304 30 -276 -458 SS 20231021T134053.0Z 8694.570058 95 1 0.75 2 72.50 123.44 145.59 76.84 0.00 1 0.00 1 0 17 9.525e-02 1.090e-02 8.912e-02 9.735e-03 4.288281e-01 4.947161e-03 5.079699e-03 -6.000000e+00 5.481419e-02 225.11 -2.00 3.54 -2.00 318.58 0.00e+00 8.455201e-04 1.057511e-03 5.781819e-04 -6.000000e+00 2.424028e-03 281.51 -2.00 20.00 -2.00 317.91 0.00e+00 3.278 0.001 302.00 328.00 3 2.2527e+00 1.3427e-02 3.8818e-02 -6.0000e+00 1.3537e-01 2.3661e-02 1.5381e-02 2.1988e-02 -6.0000e+00 1.4700e-01 -1.2968e-02 1.0840e-02 1.1042e-02 -6.0000e+00 8.7674e-02 -1.6910e-03 5.7381e-03 3.3572e-03 -6.0000e+00 3.7582e-02 1.3559e-03 1.5199e-03 2.8272e-04 3.7128e-05 -6.0000e+00 2.6851e-03 1.3270e-03 1.2046e-04 12 9 9 12 1 1 999.00 22.16 0.18 0.00133 0.01275 1 29 1 5 0 372.000 26.21 20.00 22.16 15.45 17.8 929.47 62514 -47902 -5206 -30222 5221 7810 -17102 -2706 -21480 24046 -14546 44314 -22316 -4278 -1927 1153 5474 -7432 10361 -10664 10775 -9239 -746 4561 3942 4658 -1568 6228 -2912 8380 269 8831 913 3788 -1939 -4241 -5585 -1892 305 172 -288 -5991 -1418 -898 13 2400 992 332 -2973 4168 -3797 -538 -716 4802 -1556 1296 1267 -1362 1820 -1688 3010 1105 3291 1596 843 -697 -297 544 2214 2478 882 2296 -495 2795 -2019 224 -470 454 -971 -4109 -1425 -2449 -434 -2519 -133 -789 -86 -76 994 558 -158 333 -669 1169 -797 455 137 -312 75 660 410 -1945 -1328 -1333 -572 -1250 -135 -171 -74 1089 487 524 -170 -79 -272 132 -314 71 958 382 -105 -44 498 639 587 132 -79 -212 1085 414 -514 1550 -556 -320 -243 160 -458 257 166 137 336 -760 -917 1138 -2676 -202 -1346 157 241 -714 -111 -1137 886 -781 1531 -1727 -333 -167 109 535 -854 1093 -1396 1197 -1219 -95 595 551 674 -241 840 -418 1131 44 1500 180 742 -383 -871 -1257 -486 90 58 -106 -2397 -563 -359 5 943 395 134 -1255 1711 -1780 -258 -370 2513 -881 735 714 -782 1018 -974 1724 683 2147 1117 600 -478 -201 368 1559 1879 725 1937 -415 2270 -1585 163 -326 307 -702 -3349 -1230 -2284 -418 -2566 -142 -867 -97 -88 1137 628 -170 344 -656 1147 -823 500 164 -406 101 884 529 -2399 -1579 -1606 -707 -1617 -179 -234 -105 1624 759 833 -268 -121 -399 189 -449 103 1440 590 -165 -68 755 948 845 185 -109 -296 1560 633 -824 2518 -938 -554 -433 296 -860 482 313 256 608 -1351 -1608 SS 20231021T134534.6Z 8694.573317 98 1 49.12 2 71.78 124.38 144.78 77.85 0.00 1 0.00 1 0 25 7.862e-02 6.567e-03 9.703e-02 6.125e-03 4.129499e-01 3.151110e-03 4.889587e-03 -6.000000e+00 4.520255e-02 225.11 -2.00 3.54 -2.00 319.80 0.00e+00 -2.031433e-04 9.356470e-04 2.068056e-04 -6.000000e+00 2.000892e-03 281.51 -2.00 20.00 -2.00 319.13 0.00e+00 3.156 0.001 302.00 328.00 3 4.4350e+00 9.0458e-03 3.7528e-02 -6.0000e+00 1.1163e-01 1.1218e-02 1.0782e-02 2.1543e-02 -6.0000e+00 1.2125e-01 2.6634e-02 8.6679e-03 1.0822e-02 -6.0000e+00 7.2317e-02 -2.0332e-02 4.5066e-03 3.1507e-03 -6.0000e+00 3.0975e-02 1.7419e-04 3.5862e-05 1.8932e-04 3.8375e-05 -6.0000e+00 2.2168e-03 3.8001e-03 -7.4099e-06 11 8 0 10 0 0 99.97 22.16 0.30 0.00380 0.00407 99 22 1 5 0 496.100 26.21 20.00 22.16 15.58 17.9 931.38 29611 -45345 44127 6116 20120 -8690 9921 25009 1445 -11386 -2993 9489 -11196 -15802 -24367 13006 -6585 13081 4411 -2040 8645 5992 6424 -8125 -7431 6627 -3273 -588 4057 -3006 1784 4446 11480 -1699 3580 1150 -2531 -1071 -3092 1858 -2439 -4338 2193 -934 1583 -131 -3739 -4739 -2019 709 1351 1894 1183 -419 -104 1207 -201 570 -259 2320 1426 1451 508 2284 -338 -249 -977 -292 916 670 172 751 265 1458 438 -887 835 -734 -760 -257 -1240 -1007 -2020 -785 -317 -863 -269 416 723 1229 978 1148 -412 272 -272 -591 855 1025 490 -752 -224 -735 -136 -423 -627 -1574 -451 -821 -131 29 336 658 -99 -27 -87 -187 444 -118 262 298 -847 204 -107 -145 292 384 247 1053 1252 -375 49 19 75 -68 -154 -206 100 523 -439 136 -57 -222 -232 437 -1397 636 114 318 -176 184 456 37 -355 -88 274 -447 -790 -1485 646 -407 748 277 -143 553 397 449 -711 -690 560 -305 -51 321 -267 168 458 1221 -212 403 135 -344 -162 -580 389 -587 -1124 552 -246 408 -35 -1020 -1307 -549 195 401 609 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