File name: Pandora39s1_DearbornMI_20240108_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T015326.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20240108_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20240108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240108T140935.9Z 8773.589999 145 1 3.26 2 80.63 132.01 69.50 170.00 0.00 1 0.00 1 0 17 6.022e-01 3.886e-02 4.323e-01 2.912e-02 8.592225e-01 1.649686e-02 9.650389e-03 -6.000000e+00 3.467040e-01 223.30 -2.00 3.54 -2.00 321.54 0.00e+00 9.101105e-03 7.476658e-03 9.363179e-04 -6.000000e+00 1.933876e-02 273.51 -2.00 20.00 -2.00 321.11 0.00e+00 5.849 0.004 302.00 328.00 3 2.4367e+00 5.3417e-02 7.3043e-02 -6.0000e+00 8.5453e-01 7.7154e-01 6.8179e-02 4.7522e-02 -6.0000e+00 9.3220e-01 -1.1304e+00 6.1640e-02 2.4706e-02 -6.0000e+00 5.5321e-01 4.8440e-01 3.0363e-02 1.2304e-02 -6.0000e+00 2.4052e-01 5.8324e-05 -1.7776e-03 7.9073e-04 1.6274e-04 -6.0000e+00 1.8179e-02 5.2243e-03 6.1622e-05 12 9 9 12 1 1 999.00 22.08 0.23 0.00522 -0.00813 1 7 1 5 0 1623.870 26.11 20.00 22.08 8.94 18.2 934.64 42823 900000 -83965 900000 -20944 -78280 30138 -176019 900000 -207431 900000 900000 900000 74785 85238 50029 -56517 337482 -9239 -548 -85590 190494 -45288 900000 900000 -28438 900000 -24627 900000 -18045 900000 84377 25229 -26494 10938 84445 -15481 900000 165860 164594 -19158 105360 48174 25541 43466 50390 35519 -11209 211353 4098 53366 4920 92473 47570 34634 77017 -13879 35406 54324 78269 58134 33891 23810 38263 17181 -19447 49819 -3674 25023 9224 22010 6669 9857 13118 -7094 -8458 9961 17288 8984 8398 -803 5174 -9645 -1228 31 1379 306 -6864 2116 -4973 7665 -1456 180 -3647 5689 -8211 -1459 -2901 -6628 -1281 2111 -800 -6703 2067 -5916 1044 4309 -2556 571 -3748 1859 -4605 -1819 -2708 1999 2615 1394 -181 -1738 4230 1833 2766 409 1295 1167 1600 3061 1561 1888 409 -461 -727 1160 582 227 1026 -509 886 -760 346 -523 -1978 -2144 1213 900000 -2569 900000 -593 -2218 854 -9206 900000 -15143 900000 900000 900000 2119 2415 1417 -3074 9561 -345 -19 -6248 5397 -2155 900000 900000 -1160 900000 -930 900000 -724 900000 2390 1102 -1921 508 2392 -965 900000 4699 4663 -2004 3607 2893 1939 2758 3026 2536 -1282 5987 460 4233 675 5973 4976 4302 6633 -2752 4321 5417 5942 5534 4357 3891 6170 3515 -5529 7708 -944 5514 2613 5990 2179 3032 3610 -2139 -2387 2205 3700 2404 2634 -328 2224 -5323 -662 18 812 184 -4524 1271 -3090 4058 -797 95 -2112 3429 -6513 -1240 -2831 -7447 -1388 2095 -761 -6039 1706 -5395 940 3981 -2661 642 -4884 2534 -7116 -2826 -4206 2941 3693 1995 -274 -2731 6665 2831 4160 602 1823 1631 2160 3978 2139 2845 702 -876 -1476 2405 1292 528 2430 -1253 2171 -1886 833 -1181 -4311 -4535 SS 20240108T142024.7Z 8773.597508 151 1 49.43 2 79.17 134.07 69.23 172.51 0.00 1 0.00 1 0 17 6.193e-01 1.039e-02 3.051e-01 5.638e-03 7.911361e-01 3.109967e-03 8.737888e-03 -6.000000e+00 3.542516e-01 223.30 -2.00 3.54 -2.00 321.59 0.00e+00 4.832564e-03 1.538187e-03 1.028053e-03 -6.000000e+00 1.552425e-02 273.51 -2.00 20.00 -2.00 321.16 0.00e+00 5.128 0.002 302.00 328.00 3 2.4894e+00 1.0576e-02 6.5861e-02 -6.0000e+00 8.7293e-01 2.0606e-01 1.5806e-02 4.5065e-02 -6.0000e+00 9.5110e-01 -2.3559e-01 1.7925e-02 2.5050e-02 -6.0000e+00 5.6447e-01 8.4824e-02 8.4134e-03 1.0475e-02 -6.0000e+00 2.4072e-01 1.2393e-04 -9.2322e-04 1.5958e-04 1.2219e-04 -6.0000e+00 1.7510e-02 7.1414e-03 -6.4071e-05 12 9 8 11 8 0 99.90 22.09 0.26 0.00714 0.00020 49 11 1 5 0 1008.640 26.11 20.00 22.09 9.43 18.6 938.78 -160486 -248175 16022 -216416 900000 -226124 -230862 -90596 -245038 -191389 -215695 35640 -148943 -90552 -67594 4797 -7692 -65431 -59150 -47641 68760 -57256 87916 -45218 -18332 -67554 -13647 29800 -15701 224500 -35467 590 -17286 10565 -28448 14161 -2970 8377 40243 493 20322 7250 21700 -7662 10870 4199 8222 6708 2958 9240 10405 20345 8297 9082 4299 5260 9083 -2918 -1695 3479 3601 -3580 6412 4169 2787 2722 3824 5012 300 4302 1402 3237 924 2835 -1194 2020 142 -4 1080 -2096 2109 -3410 -962 -2342 -1236 -1765 233 397 749 2278 -1359 939 -1484 487 -1443 -853 -655 608 -71 -603 669 -932 -379 -837 -755 -1411 -1821 -517 -58 656 -308 -158 -202 314 -439 497 337 -244 833 -132 37 405 1209 -60 734 552 -523 1085 403 176 -365 29 -433 74 102 -1 -38 715 -272 -507 96 -625 154 -882 -3287 88 -2109 900000 -2317 -2711 -498 -4163 -2154 -3234 196 -1898 -901 -690 29 -60 -981 -902 -711 378 -916 483 -746 -259 -1570 -196 273 -234 1234 -895 13 -518 253 -974 322 -90 270 1156 24 913 400 1094 -533 642 274 536 471 232 749 906 1808 920 1094 578 730 1242 -444 -247 473 510 -608 1138 862 596 582 857 1124 79 1244 458 1076 308 864 -342 525 36 -1 309 -744 849 -1672 -507 -1333 -742 -1128 152 265 497 1430 -826 526 -835 283 -969 -667 -577 611 -79 -675 697 -888 -337 -733 -672 -1336 -1831 -554 -69 872 -466 -247 -323 490 -660 739 501 -380 1299 -215 59 640 1818 -89 1027 748 -698 1481 625 303 -703 61 -963 167 247 -3 -99 1886 -724 -1297 229 -1398 339 SS 20240108T145035.1Z 8773.618461 168 1 49.52 2 75.37 140.07 68.91 179.54 0.00 1 0.00 1 0 17 4.201e-01 1.597e-02 3.072e-01 1.114e-02 6.073632e-01 5.963054e-03 7.019101e-03 -6.000000e+00 2.424671e-01 223.30 -2.00 3.54 -2.00 320.82 0.00e+00 4.751173e-03 2.408313e-03 9.851774e-04 -6.000000e+00 1.066838e-02 273.51 -2.00 20.00 -2.00 320.36 0.00e+00 3.879 0.001 302.00 328.00 3 4.8417e+00 1.8285e-02 4.9282e-02 -6.0000e+00 6.0007e-01 1.0932e-01 2.3839e-02 3.2051e-02 -6.0000e+00 6.5488e-01 -6.7728e-02 2.4230e-02 1.8492e-02 -6.0000e+00 3.8751e-01 2.2402e-02 1.2062e-02 8.2518e-03 -6.0000e+00 1.6449e-01 4.4498e-05 -3.4302e-04 3.3137e-04 9.5121e-05 -6.0000e+00 1.2221e-02 4.9994e-03 2.2638e-05 12 8 8 10 0 0 99.54 22.10 0.22 0.00500 0.00242 14 3 1 5 0 3536.500 26.11 20.00 22.10 11.32 18.5 950.66 -225150 -139863 -65618 900000 21782 -146430 64665 900000 -126349 -71985 -10983 -23256 900000 -116902 238532 -47611 -27666 900000 -22248 17730 -12849 44898 76111 72798 -14172 76994 -30818 -17560 -21598 14344 -3399 42537 -14880 86287 26812 46797 4351 24339 -3991 -894 -2874 -1929 -4374 9212 -6527 19904 20289 -4267 6027 -5352 6277 -792 9977 2287 4392 3233 4368 8060 -5622 7564 10405 2384 576 1201 410 3205 6213 -493 4664 216 1401 3134 -1127 2173 109 -2693 -2376 1682 1507 -2648 -428 1624 -5615 -3568 136 -2582 -352 690 2206 363 -6 313 19 -160 -340 -908 -632 1366 257 -463 940 -3331 2051 -702 -1594 -2243 -576 -3159 -759 -195 1673 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