File name: Pandora39s1_DearbornMI_20240430_L2Fit_fout2c1d20210608p1-8.txt File generation date: 20240501T053857.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v1d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20240430_L1_smca1c1d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20240430 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240430T115903.9Z 8886.499351 188 1 49.03 2 74.61 83.52 70.02 193.73 0.00 1 0.00 1 0 17 9.224e-02 5.277e-03 1.355e-01 3.889e-03 5.249147e-01 2.069456e-03 6.008873e-03 -6.000000e+00 5.390151e-02 229.71 -2.00 3.54 -2.00 320.48 0.00e+00 2.419356e-03 7.689977e-04 4.966837e-04 -6.000000e+00 2.335652e-03 280.22 -2.00 20.00 -2.00 319.89 0.00e+00 3.699 0.001 302.00 328.00 3 3.5939e+00 6.3051e-03 4.5874e-02 -6.0000e+00 1.3461e-01 2.4721e-02 7.9016e-03 2.8153e-02 -6.0000e+00 1.4580e-01 -1.9442e-02 7.3249e-03 1.4737e-02 -6.0000e+00 8.6573e-02 -5.1578e-03 3.6829e-03 5.5020e-03 -6.0000e+00 3.6641e-02 2.0884e-04 -1.7571e-05 1.1760e-04 6.1275e-05 -6.0000e+00 2.6047e-03 9.9279e-03 -4.0060e-06 11 1 0 11 8 0 98.23 22.15 0.27 0.00993 0.00980 38 8 1 5 0 1289.980 26.21 20.00 22.15 21.69 20.5 1031.79 19156 -61967 -17758 1437 -12273 -721 -20219 -11074 -54256 -11502 -28715 6509 14615 -9455 -16476 -12001 12137 -20911 11162 10257 -7836 -8620 1577 -3080 -9714 -9505 -11283 -13840 -3232 -5734 -1263 -235 -2867 -3819 -1398 4237 691 -6971 3441 -2429 -1048 -659 -2167 14 2800 2097 68 -1607 328 1552 -95 1555 1316 632 -502 2184 1157 -106 1608 -92 798 1872 2367 442 -643 918 -115 789 1582 458 734 1330 573 183 -219 -1118 -1318 -1234 54 -677 -1390 -891 -1566 -2308 -394 -612 -190 295 781 1076 402 690 337 -387 -66 -256 964 1217 147 -244 -361 -642 -689 31 -623 -819 -628 -664 -113 299 43 377 372 387 -696 -261 583 41 191 -37 -354 338 174 76 412 283 -306 870 451 -312 -118 -382 -413 -24 15 107 -335 554 19 146 21 -117 -333 106 -828 -165 10 -95 -5 -192 -109 -877 -135 -402 77 190 -195 -424 -341 312 -783 325 316 -295 -331 58 -128 -462 -473 -574 -695 -145 -287 -70 -15 -202 -281 -96 294 54 -697 377 -332 -156 -104 -364 2 463 356 12 -293 60 300 -21 351 323 168 -142 622 340 -31 458 -27 239 608 858 179 -269 364 -45 314 685 229 400 749 322 98 -108 -500 -550 -516 24 -360 -858 -617 -1185 -1793 -321 -534 -173 276 726 959 335 554 258 -302 -56 -239 1016 1446 183 -303 -439 -715 -711 32 -694 -967 -780 -847 -155 446 70 619 628 625 -1066 -379 837 61 303 -62 -598 554 277 116 601 397 -432 1236 679 -523 -206 -712 -803 -49 31 236 -763 1277 45 328 46 -247 -685 SS 20240430T121046.5Z 8886.507483 191 1 48.98 2 72.46 85.43 70.54 196.39 0.00 1 0.00 1 0 17 5.641e-02 5.198e-03 3.015e-02 1.495e-03 4.664347e-01 7.826314e-04 5.404077e-03 -6.000000e+00 3.296482e-02 229.72 -2.00 3.54 -2.00 319.95 0.00e+00 1.515224e-03 2.466080e-04 5.234230e-04 -6.000000e+00 1.428484e-03 280.22 -2.00 20.00 -2.00 319.34 0.00e+00 3.271 0.001 302.00 328.00 3 2.5268e+00 2.2761e-03 4.0559e-02 -6.0000e+00 8.2327e-02 -5.3414e-03 2.7337e-03 2.4732e-02 -6.0000e+00 8.9170e-02 -8.8953e-04 2.3322e-03 1.2618e-02 -6.0000e+00 5.2947e-02 -1.0544e-02 1.2050e-03 4.1262e-03 -6.0000e+00 2.2408e-02 9.8479e-04 1.3911e-04 4.5256e-05 4.6634e-05 -6.0000e+00 1.5930e-03 1.0069e-02 -7.0110e-06 10 0 0 10 0 0 98.78 22.15 0.28 0.01007 0.01111 138 31 1 5 0 354.890 26.21 20.00 22.15 22.06 20.6 1034.94 4855 -30436 3453 -26298 -18951 153 -18056 6263 -20318 -11277 -27965 -1900 -16327 1322 -4834 -3527 -575 1934 1643 -7724 3825 -2733 -1369 -3217 -389 -2942 -1724 -2717 -4697 1547 -5161 4355 -1563 62 -4626 -3836 -2914 -3507 -717 -2176 -227 -2145 607 -1980 702 -395 -287 315 -1839 1078 75 1298 325 2208 442 1605 1131 -309 422 -173 1281 639 2292 1584 864 253 643 -124 858 1049 71 1195 -29 922 -204 -453 -841 -1099 -638 -1495 -684 -1106 -1842 -1760 -470 -517 280 622 752 782 499 587 -665 224 38 -71 456 896 156 -396 -29 -1142 -445 215 -476 -1366 -676 -639 -357 471 302 313 129 114 -274 45 379 76 419 43 -181 30 475 1 414 280 -479 857 451 49 0 -376 -358 -140 -73 15 -207 545 31 -83 98 -151 -331 56 -533 46 -425 -276 2 -294 91 -411 -221 -673 -40 -482 40 -178 -146 -25 89 81 -438 197 -152 -79 -205 -26 -209 -121 -184 -318 105 -428 373 -159 6 -475 -399 -338 -468 -113 -408 -46 -469 135 -458 160 -92 -67 74 -452 271 21 389 106 731 156 578 418 -115 153 -63 479 264 1033 782 435 122 300 -59 444 616 44 769 -18 581 -119 -240 -414 -539 -340 -927 -464 -846 -1534 -1549 -422 -496 281 638 771 771 475 517 -560 188 35 -71 512 1088 204 -517 -36 -1343 -484 235 -563 -1670 -863 -866 -518 714 495 516 210 183 -412 66 554 112 653 71 -302 49 751 1 622 404 -670 1199 666 79 0 -677 -669 -265 -146 32 -439 1171 67 -177 204 -302 -641 SS 20240430T121647.5Z 8886.511661 195 1 48.98 2 71.35 86.42 70.85 197.74 0.00 1 0.00 1 0 17 4.457e-02 5.460e-03 2.176e-02 1.358e-03 4.453140e-01 7.088902e-04 5.156021e-03 -6.000000e+00 2.605120e-02 229.72 -2.00 3.54 -2.00 319.75 0.00e+00 1.437493e-03 2.076294e-04 3.183795e-04 -6.000000e+00 1.128640e-03 280.22 -2.00 20.00 -2.00 319.11 0.00e+00 3.088 0.001 302.00 328.00 3 2.5651e+00 2.0357e-03 3.8412e-02 -6.0000e+00 6.5061e-02 1.1416e-03 2.4120e-03 2.3519e-02 -6.0000e+00 7.0466e-02 -5.1932e-03 1.9724e-03 1.1877e-02 -6.0000e+00 4.1841e-02 -9.4429e-03 1.0248e-03 3.9090e-03 -6.0000e+00 1.7710e-02 1.1517e-03 2.2372e-04 4.1206e-05 4.2886e-05 -6.0000e+00 1.2586e-03 9.7696e-03 2.2557e-05 11 1 0 11 8 0 90.06 22.15 0.22 0.00977 0.01145 151 34 1 5 0 324.350 26.21 20.00 22.15 22.32 20.7 1036.68 -10932 -14735 2723 -20524 -9328 -29656 4056 -17521 -4146 -15224 -8741 -7207 -7047 -664 -2702 488 -3923 456 -2549 -696 243 983 -1227 -2772 1335 -3231 -241 -5628 -2245 -3087 408 92 -1394 -2611 -3119 -729 -4795 -1927 -2369 -1366 -1930 -1153 -992 -1438 978 -309 924 -1186 45 277 1183 602 1438 1673 989 1224 221 514 -192 780 702 1670 2197 1738 869 29 485 -708 1288 623 628 880 257 775 43 -127 -1278 -1206 -1134 -1089 -1148 -1047 -2104 -1692 -799 -684 427 391 919 549 472 605 -148 31 -188 -90 302 942 12 -141 -301 -939 -1026 -96 1415 -1407 -651 -702 -337 316 329 110 207 221 -195 31 282 170 181 83 -367 162 231 108 412 281 -253 594 505 -191 116 -401 -248 -181 73 70 -205 640 72 24 -61 -150 -523 -185 -286 46 -404 -159 -604 68 -394 -91 -393 -219 -200 -236 -24 -120 24 -216 26 -158 -44 16 63 -85 -210 103 -273 -20 -464 -175 -257 37 9 -156 -303 -348 -81 -622 -288 -432 -288 -450 -282 -252 -373 250 -81 239 -316 12 78 358 193 491 610 379 483 90 207 -76 306 288 740 1074 925 471 15 243 -363 705 376 414 602 175 501 26 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