File name: Pandora39s1_DearbornMI_20240508_L2Fit_fout2c1d20210608p1-8.txt File generation date: 20240516T065244.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v1d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20240508_L1_smca1c1d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T110438.1Z 8894.461552 64 1 49.15 2 82.83 73.11 83.46 67.69 0.00 1 0.00 1 0 17 6.245e-01 2.070e-02 4.744e-01 1.459e-02 1.026125e+00 9.098982e-03 1.097000e-02 -6.000000e+00 3.781276e-01 230.41 -2.00 3.54 -2.00 322.49 0.00e+00 1.032917e-02 5.888493e-03 7.909904e-03 -6.000000e+00 1.766996e-02 281.12 -2.00 20.00 -2.00 322.10 0.00e+00 7.380 0.007 302.00 328.00 3 1.1831e+00 3.9183e-02 1.1297e-01 -6.0000e+00 9.5425e-01 8.8719e-01 5.9719e-02 1.1349e-01 -6.0000e+00 1.0408e+00 -1.2243e+00 6.0071e-02 4.2255e-02 -6.0000e+00 6.0559e-01 4.9082e-01 2.6425e-02 1.6257e-02 -6.0000e+00 2.5537e-01 4.1095e-05 -8.5965e-04 4.1434e-04 1.8781e-04 -6.0000e+00 1.8814e-02 5.1709e-03 5.9039e-05 12 8 8 10 0 0 41.40 22.12 0.53 0.00517 -0.00129 53 12 1 5 0 927.190 26.21 20.00 22.12 21.57 20.9 1025.44 900000 -196548 900000 -160868 900000 -229903 900000 -74655 900000 900000 -64622 -159903 -244751 900000 -66384 900000 -73227 -76793 -83779 -106056 -11222 -117778 900000 -32750 66412 -25018 -12802 -64320 -111782 -84866 -76171 89179 900000 900000 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2792 2079 1058 1433 1074 -1481 658 1531 19 1187 1624 1497 373 -25 2738 541 2507 2755 -75 -1045 998 -2316 -1003 -1327 -1101 1025 -2351 -1717 -845 -135 -1797 -1874 -2605 -1400 -3873 -3216 -2918 -1671 -1053 -1834 -776 -1358 1675 -872 -2511 479 -491 3628 1387 3492 464 3103 2277 240 3379 2959 1606 -796 633 -845 1428 1000 413 172 2263 -496 -1752 -1618 -960 -2943 SS 20240508T111543.3Z 8894.469251 67 1 49.19 2 80.86 74.89 81.59 69.35 0.00 1 0.00 1 0 17 8.021e-01 1.079e-02 3.366e-01 5.651e-03 8.788118e-01 3.318088e-03 9.915148e-03 -6.000000e+00 4.764498e-01 230.41 -2.00 3.54 -2.00 322.02 0.00e+00 9.684612e-03 1.971621e-03 3.296965e-03 -6.000000e+00 2.216182e-02 281.12 -2.00 20.00 -2.00 321.57 0.00e+00 5.975 0.004 302.00 328.00 3 1.2869e+00 1.3126e-02 7.7358e-02 -6.0000e+00 1.1897e+00 2.2250e-01 2.1141e-02 5.2789e-02 -6.0000e+00 1.2889e+00 -2.9488e-01 2.3633e-02 3.2932e-02 -6.0000e+00 7.6122e-01 1.0905e-01 1.0521e-02 1.6302e-02 -6.0000e+00 3.2305e-01 1.6995e-04 1.2528e-04 1.6004e-04 2.5522e-04 -6.0000e+00 2.3017e-02 4.7893e-03 5.0555e-05 12 8 8 10 0 0 90.63 22.12 0.35 0.00479 0.00573 125 28 1 5 0 393.480 26.21 20.00 22.12 22.24 20.7 1029.20 -336119 900000 -231769 -292935 900000 -240098 900000 -233365 -241879 -285478 -252769 900000 -234786 -44845 -210632 167083 -125646 -102675 -57842 -118092 212833 -133061 900000 -56846 900000 -26989 -17459 -107267 37951 -39284 -48758 -15662 -15765 15160 -32309 18331 -10575 35966 -28566 12059 -6763 2931 27365 -1667 35033 -691 29091 2445 19088 6428 4130 20209 8643 24195 7957 30640 -4065 9974 -655 -373 2339 -663 16415 7259 7129 4976 10074 1682 9078 5493 2227 4001 609 5041 -1559 4750 -4603 -351 -1833 -4040 1244 -131 -1441 -1762 2115 -1648 654 818 1926 120 -504 1104 -2441 -514 -3097 176 -1235 957 -204 69 -177 -1818 262 -1397 -70 -2065 -1390 -1850 -692 95 -300 296 -441 297 -49 161 223 716 -4 133 -138 450 687 170 996 464 -162 1167 1165 -85 248 -414 -396 -135 -112 -76 -191 854 -41 -413 -43 -106 -329 -3364 900000 -1276 -2345 900000 -1322 900000 -1285 -1452 -2857 -2024 900000 -2820 -247 -3689 920 -1383 -1028 -405 -1595 1172 -2131 900000 -484 900000 -189 -125 -1718 209 -413 -732 -212 -252 190 -631 220 -191 486 -901 302 -230 98 767 -65 982 -29 961 114 821 351 265 1254 614 1620 668 2136 -410 865 -61 -35 222 -73 1792 1002 1060 765 1516 294 1657 1199 553 1011 156 1147 -342 880 -900 -70 -432 -1188 382 -47 -585 -766 945 -812 329 421 979 60 -237 484 -1096 -241 -1719 113 -948 839 -200 68 -165 -1547 196 -1041 -54 -1735 -1231 -1790 -739 115 -416 443 -685 451 -72 229 320 1065 -6 215 -221 680 992 237 1330 604 -208 1551 1771 -151 496 -848 -868 -316 -281 -200 -518 2330 -111 -1092 -106 -243 -718 SS 20240508T112645.9Z 8894.476921 72 1 49.08 2 78.88 76.66 79.71 70.99 0.00 1 0.00 1 0 17 5.118e-01 6.001e-03 1.660e-01 2.270e-03 7.546813e-01 1.264812e-03 8.496653e-03 -6.000000e+00 3.002262e-01 230.41 -2.00 3.54 -2.00 321.54 0.00e+00 3.848098e-03 6.667976e-04 2.583548e-03 -6.000000e+00 1.309112e-02 281.12 -2.00 20.00 -2.00 321.05 0.00e+00 5.003 0.002 302.00 328.00 3 9.7824e-01 4.5409e-03 6.4960e-02 -6.0000e+00 7.5084e-01 5.4320e-02 6.7759e-03 4.3978e-02 -6.0000e+00 8.1255e-01 -6.4084e-02 7.4028e-03 2.6178e-02 -6.0000e+00 4.8252e-01 1.3275e-02 3.4197e-03 1.0256e-02 -6.0000e+00 2.0570e-01 6.6030e-04 3.4915e-04 6.4789e-05 1.4158e-04 -6.0000e+00 1.4513e-02 3.7592e-03 7.5327e-05 10 0 0 10 0 0 30.19 22.12 0.29 0.00376 0.00638 253 56 1 5 0 193.980 26.11 20.00 22.12 22.73 21.0 1032.85 900000 -204386 -149542 -227457 -157607 -182553 -136993 -179970 -173667 -66455 -182072 -51301 -127374 -79533 -89377 -69556 -25502 -33681 -1064 -62691 13896 -53132 -35467 -53966 -40575 -30177 -30795 -49858 -43035 -9914 -26116 -4255 -10261 -9729 -19773 -699 -5094 -3775 5199 -9829 6992 -3048 844 4 4176 -1533 3361 5959 -1089 8299 1073 5129 2749 4884 2346 3572 2670 169 2000 -370 2609 1127 4334 3255 1229 1131 1082 349 2314 2722 142 1633 445 1380 -324 -35 -283 -1844 -1184 -1497 18 -866 -1629 -1475 -593 -606 375 309 303 1147 75 709 -1142 -384 -664 -166 185 897 243 -355 -271 -848 -119 37 -1080 -1585 -753 -892 -348 436 263 370 -126 322 -342 225 421 209 440 -197 -85 47 728 -27 350 207 -492 887 585 -308 74 -240 -407 -220 85 -158 -292 505 170 -145 117 -96 -117 900000 -1192 -596 -1739 -628 -970 -515 -1195 -1230 -176 -1692 -159 -1127 -581 -930 -723 -198 -320 -8 -845 98 -684 -455 -836 -596 -425 -446 -863 -719 -151 -531 -85 -254 -254 -557 -17 -144 -128 199 -524 356 -186 52 0 266 -107 233 427 -82 629 99 515 314 600 316 498 387 25 283 -53 381 186 799 688 281 258 250 86 622 839 50 584 159 458 -99 -10 -74 -509 -370 -563 8 -439 -847 -816 -348 -379 243 206 201 728 45 398 -637 -222 -435 -126 164 909 271 -401 -288 -820 -104 31 -998 -1557 -776 -992 -425 595 401 563 -196 524 -534 336 630 326 722 -312 -143 76 1128 -41 503 289 -671 1237 919 -517 138 -483 -871 -501 206 -407 -770 1255 424 -375 283 -219 -256 SS 20240508T113257.2Z 8894.481217 75 1 49.11 2 77.76 77.65 78.65 71.90 0.00 1 0.00 1 0 17 4.219e-01 5.928e-03 8.391e-02 1.652e-03 6.955194e-01 9.022307e-04 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