File name: Pandora39s1_DearbornMI_20240513_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T023634.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20240513_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20240513 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240513T115423.9Z 8899.496110 100 1 49.00 2 73.02 80.07 110.39 22.19 0.00 1 0.00 1 0 17 1.384e-01 5.038e-03 5.563e-02 1.619e-03 5.578831e-01 8.698827e-04 6.393211e-03 -6.000000e+00 8.129539e-02 230.85 -2.00 3.54 -2.00 320.57 0.00e+00 2.713264e-03 3.371535e-04 5.007557e-04 -6.000000e+00 3.526077e-03 281.69 -2.00 20.00 -2.00 319.97 0.00e+00 3.373 0.001 302.00 328.00 3 2.2642e+00 2.6799e-03 4.4842e-02 -6.0000e+00 2.0350e-01 -1.4317e-02 3.4072e-03 3.0134e-02 -6.0000e+00 2.2011e-01 -5.2281e-03 3.2136e-03 1.5790e-02 -6.0000e+00 1.3068e-01 -1.1015e-02 1.6037e-03 5.9280e-03 -6.0000e+00 5.5302e-02 1.0325e-03 -2.3456e-04 4.8322e-05 6.5410e-05 -6.0000e+00 3.9092e-03 3.5239e-03 -4.1437e-05 10 0 0 10 0 0 99.97 22.21 0.25 0.00352 0.00176 232 52 1 5 0 211.180 26.21 20.00 22.21 24.25 20.7 1039.50 -61283 -33557 -42887 -31974 -53705 -48130 -55432 -4405 -53399 -31637 -38481 -40744 -34054 -20738 -13335 -13880 -5679 -18168 2304 -8599 2221 -10456 -6740 -4788 -8157 -3519 -9877 -4778 -9624 3071 -3933 732 -1634 -4463 -2722 -1048 -2775 -4542 -2115 -1187 -909 -1242 -1070 -379 250 1082 91 1520 488 1652 437 1575 1808 1307 1245 817 601 -653 128 39 717 1590 1863 2535 276 684 785 -5 921 686 71 1068 394 495 218 -698 32 -1866 -602 -1102 -870 -1307 -2094 -1151 -728 -208 122 374 643 828 452 655 240 350 547 -398 586 951 234 -524 -255 -806 -226 252 -976 -1280 -987 -603 -443 318 137 137 80 100 37 170 662 334 459 -152 -606 118 363 44 104 464 -269 1175 587 -1 45 -297 -205 -134 35 -291 -219 421 -64 -154 100 -20 -107 -541 -255 -376 -250 -466 -404 -553 -31 -667 -341 -470 -591 -579 -389 -273 -334 -140 -558 62 -272 65 -350 -231 -175 -329 -143 -413 -192 -404 124 -192 40 -103 -302 -174 -67 -204 -405 -216 -142 -121 -177 -159 -57 38 168 14 245 82 294 87 343 428 323 324 222 168 -184 35 11 202 488 641 957 110 263 295 -2 389 331 38 588 216 258 104 -304 13 -768 -270 -579 -527 -867 -1525 -880 -593 -180 110 347 597 739 377 507 178 262 447 -375 604 1107 296 -668 -306 -888 -237 263 -1063 -1481 -1199 -778 -615 467 221 230 134 162 56 246 949 499 726 -253 -1022 192 573 67 152 668 -377 1650 876 -2 80 -558 -401 -275 75 -652 -504 983 -151 -354 218 -42 -222 SS 20240513T120356.5Z 8899.502737 107 1 49.14 2 71.28 81.58 109.74 24.29 0.00 1 0.00 1 0 17 9.274e-02 5.008e-03 1.011e-01 3.410e-03 5.117328e-01 1.825579e-03 5.897721e-03 -6.000000e+00 5.446699e-02 230.85 -2.00 3.54 -2.00 320.50 0.00e+00 2.146889e-03 6.791435e-04 5.314584e-04 -6.000000e+00 2.362249e-03 281.69 -2.00 20.00 -2.00 319.89 0.00e+00 3.077 0.000 302.00 328.00 3 3.2641e+00 5.5817e-03 4.1036e-02 -6.0000e+00 1.3634e-01 -5.0783e-02 6.9876e-03 2.7599e-02 -6.0000e+00 1.4747e-01 3.5627e-02 6.3975e-03 1.4330e-02 -6.0000e+00 8.7556e-02 -2.4188e-02 3.2159e-03 5.0264e-03 -6.0000e+00 3.7052e-02 5.3194e-04 -8.0869e-05 1.0415e-04 5.8588e-05 -6.0000e+00 2.6189e-03 3.9689e-03 -1.3544e-05 11 1 0 11 8 0 99.98 22.21 0.22 0.00397 0.00336 354 79 1 5 0 138.780 26.21 20.00 22.21 24.53 20.9 1040.97 -56367 -32977 -16124 909 -5808 -40380 -20203 -17153 -30909 -50314 -8150 -20613 -599 -12898 10388 -2557 8840 -5312 -2156 2571 3244 -5999 -8265 -3230 -3484 1222 -7117 -1188 5227 1229 194 -6266 2904 -6580 -802 -2753 -3738 902 -1990 12 -3336 732 -3162 -195 -248 722 -822 -234 3318 1298 1169 -967 3152 -564 -527 1478 762 -46 -725 404 2 1331 711 2035 731 1058 239 322 1598 495 759 -523 -938 601 515 1396 -449 -280 -191 135 -1053 -758 -2104 -1392 -753 -521 -360 262 756 389 1180 472 807 537 268 -94 157 599 57 -445 129 -1154 -334 820 -877 -1519 -885 -617 -76 525 485 135 163 101 -169 383 328 128 148 -114 -345 216 64 104 275 162 -597 773 691 -79 -13 -500 -199 -110 75 -87 -187 636 -88 -96 28 22 -265 -668 -350 -151 7 -46 -436 -197 -185 -430 -910 -102 -334 -10 -280 217 -71 240 -182 -77 92 118 -229 -344 -138 -160 56 -360 -55 223 59 11 -433 207 -507 -59 -211 -308 85 -234 2 -496 111 -524 -32 -41 122 -142 -41 579 245 243 -226 767 -154 -151 430 229 -14 -216 118 1 442 266 823 307 426 95 130 695 248 397 -289 -516 325 256 621 -189 -117 -87 71 -617 -499 -1526 -1062 -611 -450 -326 243 699 348 975 364 589 394 215 -86 163 699 73 -564 153 -1271 -338 823 -959 -1771 -1078 -797 -106 790 793 231 277 165 -259 555 472 192 235 -192 -585 356 102 161 403 228 -816 1056 1029 -131 -23 -954 -394 -217 157 -194 -430 1476 -207 -219 62 45 -532 SS 20240513T120845.9Z 8899.506086 110 1 49.11 2 70.40 82.35 109.39 25.34 0.00 1 0.00 1 0 17 6.111e-02 5.115e-03 1.375e-02 6.661e-04 4.904644e-01 3.507478e-04 5.676085e-03 -6.000000e+00 3.590424e-02 230.85 -2.00 3.54 -2.00 319.97 0.00e+00 1.679106e-03 1.113209e-04 3.682278e-04 -6.000000e+00 1.556615e-03 281.69 -2.00 20.00 -2.00 319.33 0.00e+00 2.947 0.000 302.00 328.00 3 1.2687e+00 1.0199e-03 3.9139e-02 -6.0000e+00 8.9876e-02 -1.0975e-02 1.2330e-03 2.6069e-02 -6.0000e+00 9.7202e-02 -1.3877e-02 1.0562e-03 1.3234e-02 -6.0000e+00 5.7711e-02 -5.4282e-03 5.4409e-04 4.4084e-03 -6.0000e+00 2.4431e-02 4.5152e-03 1.6280e-04 1.9892e-05 4.8323e-05 -6.0000e+00 1.7256e-03 2.1622e-03 7.6918e-06 10 0 0 10 0 0 93.08 22.21 0.24 0.00216 0.00339 628 140 1 5 0 78.180 26.21 20.00 22.21 24.62 20.9 1042.63 -19654 -20918 -9860 -25274 -18664 -22964 -22698 -22796 -16740 -16906 -16225 -16110 -12372 -9262 -6122 -2935 -3499 -2822 -1745 -3206 -3540 -991 -1977 -4063 -2983 -3382 -3089 -3705 -4207 -2272 -1133 563 -669 -2858 -3086 -2622 -3221 -1403 -1653 -1971 -1807 -1033 -1185 -706 82 -49 -336 -430 -130 723 1344 545 1164 1089 725 1122 558 172 94 225 945 1574 2048 2087 681 865 780 -108 1303 567 348 702 170 731 104 -239 -394 -1152 -437 -1089 -1100 -1065 -2158 -1409 -740 -451 142 374 646 632 697 840 145 465 281 -94 427 793 13 -462 -272 -819 -431 293 -864 -1398 -709 -677 -255 345 258 67 36 156 28 316 533 224 321 -91 -519 79 256 31 329 347 -220 1191 670 11 92 -317 -137 -19 83 -194 -277 514 -61 -142 34 -189 -235 -246 -297 -130 -365 -256 -334 -332 -379 -293 -315 -313 -351 -317 -283 -218 -116 -152 -132 -86 -169 -191 -53 -112 -254 -197 -235 -215 -248 -278 -158 -89 46 -62 -279 -289 -249 -344 -175 -251 -354 -358 -215 -258 -156 18 -11 -76 -99 -31 178 360 161 370 373 261 416 213 66 35 83 362 655 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