File name: Pandora39s1_DearbornMI_20240610_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T024800.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20240610_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20240610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240610T125204.9Z 8927.536167 135 1 48.73 2 60.26 84.83 98.00 50.89 0.00 1 0.00 1 0 17 4.100e-02 7.381e-03 3.618e-02 5.313e-03 3.470396e-01 2.764116e-03 4.105379e-03 -6.000000e+00 2.424540e-02 232.60 -2.00 3.54 -2.00 318.76 0.00e+00 7.085399e-04 5.894192e-04 5.540746e-04 -6.000000e+00 1.057078e-03 284.57 -2.00 20.00 -2.00 317.99 0.00e+00 2.007 0.000 302.00 328.00 3 5.7740e+00 7.6098e-03 2.7245e-02 -6.0000e+00 6.0896e-02 6.3217e-02 8.7031e-03 1.8466e-02 -6.0000e+00 6.5740e-02 -7.4077e-03 5.9033e-03 9.0442e-03 -6.0000e+00 3.9041e-02 -7.4648e-03 3.0569e-03 2.5291e-03 -6.0000e+00 1.6508e-02 1.4041e-04 3.8212e-04 1.6167e-04 2.8285e-05 -6.0000e+00 1.1584e-03 4.3582e-03 6.0284e-05 11 8 0 10 0 0 99.96 22.20 0.37 0.00436 0.00723 25 6 1 5 0 1948.750 26.21 19.99 22.20 18.74 20.7 979.79 7759 -568 -13371 9679 -15285 -18177 -15454 19808 11437 11917 -8750 2101 -3653 -4485 -11602 -1605 -231 2208 2843 166 1952 1297 2444 -108 2645 2502 -6030 3140 -3567 2916 2030 3860 726 -2119 919 3968 736 -2195 191 -3218 -1627 -1200 -675 -52 -439 -282 -949 -1469 -626 -441 775 1278 -830 1750 1392 67 1356 -136 117 116 1754 558 2143 1087 1143 436 -840 -553 303 443 -335 864 580 580 422 -1006 -294 -2510 1322 -747 -517 -1088 -1713 -1153 -474 -719 724 677 -245 547 -285 994 120 778 -190 -650 1200 443 814 -1295 -214 -1102 -1129 366 -1869 -692 -933 -89 -675 1033 315 109 -101 1064 125 125 -13 -331 1079 -420 494 415 515 171 129 114 -582 975 132 649 -287 -967 -857 80 201 -226 56 581 42 13 -345 -19 -275 320 -28 -748 397 -735 -900 -810 855 569 615 -560 131 -279 -405 -1251 -173 -26 256 343 21 250 167 325 -16 393 386 -1003 449 -520 425 314 644 136 -416 165 697 148 -536 55 -1107 -600 -462 -267 -21 -174 -112 -375 -577 -243 -175 326 576 -406 885 731 36 742 -75 63 62 959 333 1376 726 761 284 -525 -342 200 317 -263 699 467 447 313 -680 -180 -1521 817 -534 -416 -940 -1598 -1125 -491 -797 831 802 -294 625 -304 960 112 708 -178 -681 1381 571 1112 -1789 -276 -1319 -1266 410 -2305 -892 -1263 -125 -978 1575 515 184 -167 1626 185 174 -18 -473 1619 -654 778 646 809 259 185 156 -768 1264 184 969 -461 -1570 -1427 137 363 -432 110 1158 85 25 -657 -34 -488 SS 20240610T154537.1Z 8927.656679 248 1 12.39 2 29.32 122.56 70.39 78.61 0.00 1 0.00 1 0 17 1.090e-02 7.617e-03 7.589e-03 4.202e-03 2.053261e-01 2.204819e-03 2.479813e-03 -6.000000e+00 6.444884e-03 232.61 -2.00 3.54 -2.00 315.77 0.00e+00 4.137946e-04 2.201168e-04 3.801402e-05 -6.000000e+00 2.810743e-04 284.59 -2.00 20.00 -2.00 315.09 0.00e+00 1.146 0.000 302.00 328.00 3 5.9036e+00 5.7520e-03 1.5781e-02 -6.0000e+00 1.6187e-02 3.7673e-02 6.3870e-03 1.0778e-02 -6.0000e+00 1.7476e-02 -3.9206e-03 3.6588e-03 5.2288e-03 -6.0000e+00 1.0379e-02 -2.8030e-03 1.6557e-03 1.4499e-03 -6.0000e+00 4.3878e-03 3.6388e-04 2.3238e-04 1.2326e-04 1.8511e-05 -6.0000e+00 3.0802e-04 3.9065e-03 -1.2048e-05 12 9 1 12 9 1 99.97 22.18 0.27 0.00391 0.00565 3 4 1 5 0 3095.990 26.21 20.00 22.18 22.67 20.8 1004.81 -2696 -2138 537 -3104 -663 -736 -2131 587 5109 -1522 -2154 -1090 -817 -331 159 -360 -1064 807 1461 826 632 1845 541 -400 -1103 -781 1538 -1341 1991 -27 1608 1802 1578 -1598 -899 558 -2465 1240 -1944 -178 -1788 1146 -294 -291 112 -426 -841 -894 87 -17 853 193 600 648 145 1141 828 997 -74 1003 636 381 1543 1397 -720 413 389 -1514 922 -283 41 604 -121 217 84 -504 -1038 -453 861 76 -1515 -1459 -1867 -1578 -1206 -684 -212 -55 362 171 1237 27 -899 938 355 376 112 1618 -164 -440 -399 -1042 -627 803 -535 -1241 -892 -315 71 671 984 163 1004 731 -459 -347 -234 -327 242 147 -353 328 420 245 40 796 -250 516 875 -126 -53 -615 -371 187 -223 553 -221 932 32 105 -280 -448 -1096 -645 -537 130 -733 -137 -150 -473 141 1275 -399 -557 -290 -241 -109 56 -136 -415 318 590 345 265 760 232 -181 -504 -365 687 -593 795 -11 668 793 740 -744 -403 247 -1194 673 -1208 -124 -1322 853 -227 -225 86 -325 -627 -644 62 -12 617 149 468 529 122 962 708 845 -62 834 549 342 1429 1357 -699 374 337 -1300 817 -268 42 624 -126 223 80 -449 -865 -367 711 68 -1489 -1525 -2023 -1736 -1414 -831 -262 -70 462 210 1467 30 -958 938 372 416 134 2036 -215 -572 -502 -1259 -714 924 -656 -1580 -1182 -423 99 956 1427 241 1450 1011 -603 -436 -290 -419 322 204 -495 468 585 329 52 1005 -311 629 1083 -163 -71 -837 -511 264 -324 821 -341 1455 50 165 -426 -661 -1626 SS 20240610T155037.7Z 8927.660159 252 1 49.82 2 28.55 124.33 69.52 79.38 0.00 1 0.00 1 0 17 1.307e-02 7.160e-03 6.664e-03 2.973e-03 2.046239e-01 1.546681e-03 2.478188e-03 -6.000000e+00 7.726964e-03 232.61 -2.00 3.54 -2.00 316.55 0.00e+00 1.592890e-04 1.822510e-04 7.296802e-05 -6.000000e+00 3.369691e-04 284.59 -2.00 20.00 -2.00 315.80 0.00e+00 1.138 0.000 302.00 328.00 3 6.1454e+00 4.0738e-03 1.5730e-02 -6.0000e+00 1.9408e-02 3.9172e-02 4.5402e-03 1.0787e-02 -6.0000e+00 2.0953e-02 -3.5720e-03 2.6329e-03 5.2432e-03 -6.0000e+00 1.2443e-02 -4.0637e-03 1.2279e-03 1.4369e-03 -6.0000e+00 5.2608e-03 2.8871e-04 3.5026e-04 8.8715e-05 1.7898e-05 -6.0000e+00 3.6927e-04 4.1109e-03 4.5806e-06 11 8 0 10 0 0 99.99 22.18 0.49 0.00411 0.00674 19 4 1 5 0 2621.570 26.21 20.00 22.18 22.91 21.2 1006.94 3651 -3410 1647 -6407 3584 -2681 124 1281 -1194 666 -2183 3971 -2610 2507 262 -1054 -612 -1137 647 -1346 1115 -1344 3775 -581 -846 -562 -574 1265 -1385 1390 -289 2464 -659 395 -3067 -868 -1462 -4 -182 -1301 -100 -1386 456 -1096 410 -480 -16 692 -1081 397 -173 467 847 1886 -279 1426 184 779 670 -117 1755 308 1684 1238 767 -537 496 -733 1294 412 210 517 -943 923 -365 118 -588 -913 62 -1812 -379 -2009 -1574 -1585 -356 -866 113 -204 464 532 -15 795 -841 622 335 118 161 790 -38 -441 139 -1281 -245 -328 -349 -999 -504 -471 -433 775 455 357 4 516 -624 560 -39 -209 416 -212 -165 -112 610 -42 921 374 46 943 711 348 150 -244 -370 377 -125 544 -263 809 145 -511 -67 -1048 -598 620 -656 297 -1183 538 -423 20 232 -241 135 -447 793 -618 634 72 -315 -187 -359 207 -450 366 -449 1283 -208 -315 -214 -214 447 -468 452 -100 880 -258 153 -1145 -318 -594 -2 -97 -802 -66 -953 314 -769 282 -330 -11 441 -682 247 -114 323 611 1408 -218 1112 147 614 519 -91 1389 254 1473 1138 693 -450 396 -577 1057 366 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