File name: Pandora39s1_DearbornMI_20240921_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T034135.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20240921_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20240921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240921T120202.7Z 9030.501420 237 1 49.01 2 82.99 95.88 51.92 261.99 0.00 1 0.00 1 0 17 6.676e-01 1.919e-02 4.719e-01 1.496e-02 8.764614e-01 8.966364e-03 9.617258e-03 -6.000000e+00 3.936658e-01 228.31 -2.00 3.54 -2.00 322.29 0.00e+00 3.016277e-03 5.844234e-03 1.431309e-03 -6.000000e+00 2.050060e-02 285.12 -2.00 20.00 -2.00 321.84 0.00e+00 7.517 0.008 302.00 328.00 3 1.3535e+00 3.8661e-02 8.8833e-02 -6.0000e+00 9.7903e-01 4.4282e-01 5.7908e-02 5.2601e-02 -6.0000e+00 1.0636e+00 -6.5727e-01 5.7326e-02 2.8275e-02 -6.0000e+00 6.2987e-01 2.5794e-01 2.5309e-02 1.0493e-02 -6.0000e+00 2.7101e-01 4.1015e-05 -1.9934e-04 4.4386e-04 1.5107e-04 -6.0000e+00 1.9417e-02 7.9590e-03 1.2988e-04 12 9 8 11 8 0 15.65 22.27 0.54 0.00796 0.00646 50 11 1 5 0 980.090 26.32 20.01 22.27 25.87 22.5 977.90 -249203 900000 -117300 900000 -220846 900000 -172132 -148297 900000 -201510 900000 -256536 900000 -154358 900000 -83308 90452 141247 -161437 900000 -51257 109275 -69247 54467 -118426 900000 -78063 79431 -6164 -47415 900000 230067 175661 -6715 -34821 -71349 872 35164 8969 133369 -34472 74293 11366 45158 -394 11008 -24629 20668 71650 40309 20024 281 68772 2068 44765 -5519 50514 5454 -2229 8637 9680 35316 -6195 28045 16312 41533 16514 127 13975 5760 20932 5893 28313 -767 17497 -377 12623 876 6450 7255 -687 4553 -7294 8148 -4148 9098 -7262 4039 -1944 4894 3563 -1451 -1087 -5187 -1039 -3843 -3347 -1491 -1431 -2488 -1201 -679 -773 2370 -2163 1459 -4284 -1547 -390 -1699 957 -680 883 -866 1553 -1232 445 -542 140 1464 -1163 956 1299 445 -1176 1677 776 1679 -16 1047 589 -379 613 -12 540 -753 491 318 -317 -572 -172 724 -1350 -3628 900000 -1708 900000 -3215 900000 -2506 -2159 900000 -2934 900000 -5433 900000 -2247 900000 -1213 1317 2056 -4701 900000 -746 1591 -1008 793 -2821 900000 -1353 1156 -90 -690 900000 3350 2558 -121 -797 -2374 16 536 218 1942 -1643 1339 402 1158 -16 412 -1304 774 1739 1481 981 19 2718 167 2518 -537 2875 480 -204 692 794 2501 -771 2840 1986 3958 2077 19 2070 1068 3670 1246 4678 -158 2702 -62 1838 145 1172 1589 -195 1421 -2730 2798 -1724 3521 -3463 1764 -900 2040 1411 -575 -445 -2262 -501 -2264 -2325 -1186 -1258 -2238 -1009 -512 -527 1538 -1561 1078 -3568 -1366 -381 -1934 1211 -916 1211 -1199 2031 -1676 601 -742 201 2143 -1722 1379 1792 599 -1555 2099 961 2168 -25 1737 1108 -791 1359 -29 1385 -2073 1372 905 -907 -1573 -440 1714 -3111 SS 20240921T121310.7Z 9030.509152 240 1 49.03 2 80.95 97.79 53.88 264.02 0.00 1 0.00 1 0 25 5.650e-01 1.485e-02 2.845e-01 4.632e-03 7.278116e-01 2.633371e-03 8.451537e-03 -6.000000e+00 3.330208e-01 228.30 -2.00 3.54 -2.00 321.74 0.00e+00 -1.987820e-03 1.503002e-03 6.595705e-03 -6.000000e+00 1.490236e-02 285.12 -2.00 20.00 -2.00 321.22 0.00e+00 6.025 0.004 302.00 328.00 3 1.3039e+00 1.0037e-02 8.0253e-02 -6.0000e+00 8.2849e-01 -4.8467e-03 1.5068e-02 6.5584e-02 -6.0000e+00 8.9880e-01 -6.8203e-02 1.5723e-02 2.6473e-02 -6.0000e+00 5.3135e-01 2.2103e-02 7.1386e-03 7.6676e-03 -6.0000e+00 2.2664e-01 2.1159e-04 5.5314e-04 1.3924e-04 8.7670e-05 -6.0000e+00 1.6300e-02 8.8184e-03 8.0859e-05 12 8 8 10 0 0 96.90 22.27 0.37 0.00882 0.01297 115 26 1 5 0 426.260 26.32 20.00 22.27 26.87 22.4 983.96 900000 -216888 -113186 -132688 -241860 900000 -265161 900000 -239700 120293 -228211 -90423 -102298 -99309 3507 -159656 -23046 -80926 25653 -37617 5884 -74409 -16733 -81818 -71667 13012 -43195 36111 -49775 13028 -52494 -3695 -25537 -12137 -5888 -30362 6400 -19549 9656 -8849 19093 693 3605 8627 2576 14389 -5916 21200 -5572 7796 -3958 18550 2360 9065 4979 3201 4621 2192 12875 -2277 8913 5641 5899 2190 2938 6290 -766 3058 1943 3813 -648 4402 49 2519 2478 -1074 946 -3550 1855 -1198 151 -2149 -1143 -859 297 471 868 1066 1295 2042 79 2025 -343 1652 -214 -371 541 -198 583 -1188 -234 -2031 -95 -87 -12748 -579 -769 26 9 1467 520 1010 133 386 -219 -50 393 182 401 -7 551 -37 662 575 989 391 -126 1756 438 41 -82 3 -364 72 -138 -317 -362 545 43 -303 231 -589 77 900000 -1424 -511 -599 -1985 900000 -3374 900000 -3246 543 -3372 -408 -672 -815 16 -3304 -151 -1063 126 -371 39 -1130 -158 -1679 -1471 123 -727 267 -878 139 -1314 -68 -681 -299 -133 -910 152 -677 341 -416 769 36 193 448 144 736 -383 1101 -405 546 -354 1500 249 989 609 421 622 302 1550 -315 1150 836 1001 401 562 1156 -153 623 450 1001 -196 1322 15 716 643 -261 214 -870 491 -390 57 -958 -556 -446 164 277 533 671 812 1224 45 1074 -182 902 -134 -272 458 -194 618 -1285 -237 -1896 -79 -73 -12953 -553 -779 28 11 1949 724 1498 201 571 -311 -68 536 259 603 -11 854 -56 953 863 1420 547 -172 2459 650 69 -155 6 -787 164 -338 -827 -970 1476 116 -799 569 -1381 173 SS 20240921T122446.2Z 9030.517201 245 1 49.12 2 78.83 99.81 55.93 266.07 0.00 1 0.00 1 0 17 3.042e-01 5.862e-03 1.113e-01 2.172e-03 6.223063e-01 1.181508e-03 7.134004e-03 -6.000000e+00 1.770510e-01 228.30 -2.00 3.54 -2.00 321.15 0.00e+00 2.609781e-03 5.695629e-04 1.864141e-03 -6.000000e+00 7.860425e-03 285.12 -2.00 20.00 -2.00 320.56 0.00e+00 4.982 0.002 302.00 328.00 3 1.1810e+00 4.0449e-03 5.9359e-02 -6.0000e+00 4.3996e-01 -5.0240e-03 5.5499e-03 3.4943e-02 -6.0000e+00 4.7646e-01 -1.2928e-02 5.5386e-03 1.9212e-02 -6.0000e+00 2.8408e-01 -6.5758e-03 2.6407e-03 6.5807e-03 -6.0000e+00 1.2126e-01 6.6585e-04 3.9569e-04 6.4981e-05 8.9195e-05 -6.0000e+00 8.5859e-03 6.8355e-03 1.1104e-04 11 1 0 11 8 0 74.46 22.27 0.24 0.00684 0.00981 209 47 1 5 0 234.990 26.32 19.99 22.27 27.92 22.7 990.06 -137417 -96811 -124128 -68430 -94150 -94395 -112202 -108401 -99540 -21054 -48634 -104668 -55866 -55627 -12488 -43367 -19173 -10550 -19366 -9634 -10501 -11206 -22289 1064 -20389 -14581 -3251 -8742 -12596 -11650 -6643 -9299 5093 -15145 -1694 -12809 -3704 1356 -934 3003 -2651 -3770 -4828 3255 752 2626 -214 2387 2449 2589 5775 1427 3092 2376 1628 297 1646 90 582 823 645 2239 2112 3544 1156 1319 57 951 1067 792 1259 628 834 451 85 -1068 -907 -1923 -655 -1916 -1339 -1033 -2632 -1507 -958 -464 346 771 838 1079 1059 514 -65 -512 210 -839 880 644 335 -423 -113 -945 -812 196 -1262 -1275 -1092 -731 -81 601 472 334 385 215 -86 -25 498 119 214 108 -469 84 136 40 120 615 -750 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