File name: Pandora39s1_DearbornMI_20241105_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250218T035812.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20241105_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241105T132624.0Z 9075.560000 74 1 6.42 2 78.59 124.21 120.29 103.19 0.00 1 0.00 1 0 25 2.077e-01 1.402e-02 2.582e-01 8.176e-03 5.119271e-01 4.240078e-03 6.066855e-03 -6.000000e+00 1.188900e-01 223.67 -2.00 3.54 -2.00 320.38 0.00e+00 2.862754e-03 1.568037e-03 1.806927e-03 -6.000000e+00 5.241447e-03 279.49 -2.00 20.00 -2.00 319.81 0.00e+00 4.888 0.002 302.00 328.00 3 2.5969e+00 1.2765e-02 5.4678e-02 -6.0000e+00 2.9288e-01 -2.6983e-02 1.6067e-02 2.7838e-02 -6.0000e+00 3.1843e-01 -3.3105e-03 1.5122e-02 1.5850e-02 -6.0000e+00 1.8990e-01 -9.2103e-03 7.6590e-03 5.9861e-03 -6.0000e+00 8.1517e-02 2.0695e-04 1.3466e-03 2.4577e-04 7.5852e-05 -6.0000e+00 5.8519e-03 4.8615e-04 1.4574e-04 12 9 9 12 1 1 11.74 22.17 0.30 0.00049 0.01061 7 14 1 5 0 801.630 26.21 20.00 22.17 25.20 22.9 989.12 -32643 36675 102826 -17113 1755 -2066 -67139 -101765 72039 -84059 -66761 -79825 -37601 -15277 13782 11436 33391 -11536 6488 35075 8006 28612 1851 8820 -336 -3843 -16840 -121 24411 -678 6718 -5716 4524 -3007 6011 -10582 -18191 -3459 6273 -2354 -2962 -2217 3030 3131 400 3133 -3759 -387 -9379 -916 -2791 3031 5881 3760 1279 3164 -2214 -2358 -150 1338 -150 2144 3092 3577 574 2062 -2048 -1258 1361 -1360 1713 778 -292 1986 -2634 318 -2292 -366 -307 -1629 -1504 1505 -942 -1294 -1266 -381 1031 1669 1103 1377 662 578 2069 501 1552 481 -611 1307 494 -677 -1236 -1107 147 1332 -10277 -279 -569 -129 798 813 607 -90 218 -294 160 22 140 446 -149 208 -175 61 -123 632 1167 822 -128 1510 966 147 -221 -1054 447 -885 188 -45 -272 1174 97 46 -500 -574 -204 -285 292 820 -143 14 -16 -969 -2250 574 -1858 -1307 -2054 -790 -321 277 261 710 -401 202 864 264 778 70 336 -15 -187 -899 -6 867 -34 360 -384 311 -231 406 -862 -1797 -351 675 -326 -459 -364 495 524 70 545 -712 -73 -1908 -182 -623 705 1444 1018 374 941 -712 -757 -46 406 -48 714 1147 1453 247 844 -855 -533 616 -695 933 446 -168 1063 -1359 150 -1031 -162 -149 -901 -960 1016 -710 -1038 -1052 -335 942 1563 1042 1252 565 477 1600 398 1337 461 -655 1556 619 -857 -1486 -1258 153 1428 -12442 -335 -700 -169 1083 1214 961 -145 361 -469 240 32 205 679 -236 345 -294 100 -196 967 1754 1194 -182 2146 1512 250 -396 -1972 859 -1762 395 -97 -610 2580 217 103 -1073 -1211 -416 SS 20241105T133127.4Z 9075.563511 77 1 49.16 2 77.82 125.18 119.43 103.90 0.00 1 0.00 1 0 17 1.103e-01 4.900e-03 6.652e-02 2.369e-03 4.911677e-01 1.245157e-03 5.701649e-03 -6.000000e+00 6.309764e-02 223.67 -2.00 3.54 -2.00 320.58 0.00e+00 3.694429e-03 4.842235e-04 4.449270e-04 -6.000000e+00 2.784539e-03 279.49 -2.00 20.00 -2.00 320.01 0.00e+00 4.603 0.002 302.00 328.00 3 1.9196e+00 3.8492e-03 5.1577e-02 -6.0000e+00 1.5544e-01 -6.7285e-03 4.8542e-03 2.6254e-02 -6.0000e+00 1.6905e-01 -1.6255e-02 4.5265e-03 1.4262e-02 -6.0000e+00 1.0081e-01 -6.1000e-03 2.2684e-03 6.5017e-03 -6.0000e+00 4.3235e-02 5.3570e-04 9.6926e-05 7.3402e-05 7.0163e-05 -6.0000e+00 3.1097e-03 4.0440e-03 3.0801e-05 10 0 0 10 0 0 97.09 22.18 0.36 0.00404 0.00477 141 31 1 5 0 348.620 26.21 20.00 22.18 25.39 22.9 991.74 -62257 -26779 -46344 -13123 -18132 -48173 -42908 -23858 2685 -30557 -37248 -22225 -26335 -3291 -15439 -12317 -10346 -7216 6891 -1916 3296 -9298 -3079 -4698 -7147 -2922 -1758 -9358 -2930 -6971 -962 2354 188 -233 -3392 -1981 -4332 498 -672 1319 -2374 83 614 -1720 323 1271 1482 1362 -605 2039 739 987 2081 3230 651 442 301 -1256 176 1055 417 1086 2379 1966 237 30 -401 -107 400 928 290 882 41 593 -560 -247 -1419 -1597 -756 -1305 -683 -922 -1740 -1306 -551 -238 287 498 588 831 723 762 -315 413 -283 -450 562 843 206 -450 -44 -551 -513 207 -79 -1316 -1040 -773 -125 567 219 61 45 264 -277 334 360 286 223 -218 -499 -5 407 108 237 194 -247 1003 562 -244 25 -429 -243 -117 194 -200 -259 671 -81 -36 -3 -96 -177 -811 -276 -603 -116 -156 -567 -523 -271 26 -436 -595 -350 -537 -66 -392 -351 -319 -235 208 -66 110 -356 -117 -194 -322 -132 -79 -440 -128 -344 -52 141 13 -17 -241 -141 -354 46 -76 172 -329 12 92 -271 51 202 238 223 -104 362 146 214 483 797 173 121 85 -358 48 288 120 341 826 753 95 11 -151 -41 166 437 151 476 22 303 -267 -106 -573 -645 -331 -668 -401 -611 -1265 -1002 -450 -207 262 467 553 753 611 599 -237 310 -234 -423 555 939 249 -547 -50 -580 -540 217 -83 -1488 -1236 -976 -170 836 352 103 76 423 -419 478 512 424 352 -365 -846 -8 652 167 351 277 -342 1391 855 -414 47 -839 -462 -232 409 -448 -600 1573 -193 -83 -6 -205 -364 SS 20241105T133722.6Z 9075.567623 80 1 48.98 2 76.94 126.32 118.41 104.72 0.00 1 0.00 1 0 17 8.186e-02 5.142e-03 4.162e-02 1.695e-03 4.637095e-01 8.793139e-04 5.391554e-03 -6.000000e+00 4.681473e-02 223.67 -2.00 3.54 -2.00 320.33 0.00e+00 2.744051e-03 3.139568e-04 2.919141e-04 -6.000000e+00 2.065743e-03 279.49 -2.00 20.00 -2.00 319.74 0.00e+00 4.312 0.001 302.00 328.00 3 1.6738e+00 2.6277e-03 4.8333e-02 -6.0000e+00 1.1532e-01 -1.5632e-02 3.2505e-03 2.4587e-02 -6.0000e+00 1.2542e-01 -1.7352e-03 2.9421e-03 1.2861e-02 -6.0000e+00 7.4795e-02 -1.1773e-02 1.4997e-03 5.3149e-03 -6.0000e+00 3.2080e-02 9.2586e-04 2.0726e-04 5.2412e-05 5.6554e-05 -6.0000e+00 2.3069e-03 3.6179e-03 4.2419e-05 10 0 0 10 0 0 92.12 22.18 0.32 0.00362 0.00518 208 46 1 5 0 235.460 26.21 20.00 22.18 25.91 22.9 995.05 -12023 -13214 -16272 -38344 -33814 150 -49046 14709 -37147 -4364 -27386 -7078 -19902 -4318 5198 -11449 7089 -6156 9003 -3881 7751 86 3812 -2234 -4149 3036 -5148 587 -8122 2108 -437 1515 1657 -2577 -899 -4150 880 -5210 1313 -2923 -591 -1606 -945 -723 -409 471 -525 1746 -1440 1934 845 755 1352 1005 870 125 694 -572 1638 -859 1495 557 2304 1828 -132 669 -281 138 398 775 357 750 40 635 -209 -867 -392 -1972 -389 -1486 -751 -1139 -1689 -1363 -942 -553 -65 711 775 891 459 1162 64 440 370 -168 867 724 182 -525 85 -822 -47 214 -874 -1073 -809 -648 -348 686 86 260 -34 263 -57 82 461 -114 520 -320 -559 -51 362 -63 310 252 -430 1278 422 13 -44 -413 -268 -103 108 -135 -130 537 -7 -227 146 -160 -125 -123 -153 -201 -557 -435 1 -814 153 -689 -62 -508 -122 -476 -109 144 -412 232 -249 334 -172 311 4 169 -113 -228 163 -301 31 -464 116 -28 110 130 -217 -71 -346 78 -583 167 -456 -99 -291 -178 -139 -79 92 -105 345 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