File name: Pandora39s1_DearbornMI_20241117_L2Fit_fout2c1d20210608p1-8.txt File generation date: 20241119T083145.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v1d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20241117_L1_smca1c1d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20241117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241117T142809.6Z 9087.602889 319 1 48.48 2 72.87 138.23 87.79 305.61 0.00 1 0.00 1 0 17 4.568e-02 8.951e-03 3.032e-02 2.975e-03 3.750961e-01 1.507689e-03 4.474150e-03 -6.000000e+00 2.602664e-02 222.83 -2.00 3.54 -2.00 319.37 0.00e+00 1.307387e-03 3.914347e-04 5.131633e-04 -6.000000e+00 1.145741e-03 278.02 -2.00 20.00 -2.00 318.75 0.00e+00 3.345 0.001 302.00 328.00 3 3.8657e+00 4.1976e-03 3.7850e-02 -6.0000e+00 6.4027e-02 1.9625e-02 4.8956e-03 1.9874e-02 -6.0000e+00 6.9700e-02 -5.3256e-03 3.7400e-03 9.6997e-03 -6.0000e+00 4.1555e-02 -1.1183e-02 1.9668e-03 3.2568e-03 -6.0000e+00 1.7825e-02 2.7801e-04 -2.9611e-04 9.1157e-05 3.4893e-05 -6.0000e+00 1.2871e-03 4.9417e-03 -1.4083e-05 11 8 0 10 0 0 99.94 22.11 0.24 0.00494 0.00272 34 8 1 5 0 1425.700 26.21 19.99 22.11 15.65 22.1 937.31 -27264 -676 -10530 10557 -18889 -16800 4750 -17515 -3987 -16080 -7427 -6830 10239 -2256 -260 -2325 2006 7784 4136 6929 -1748 3967 -890 2856 869 -2338 3272 -5358 -3327 -6190 3798 -2701 1012 -292 2226 -938 -1179 1744 -3300 43 -2810 -1408 -152 -729 -804 -1249 -572 -131 1223 1 2687 -862 771 1231 663 760 229 1915 -741 593 377 830 648 1717 -637 693 1072 -249 1079 268 1115 337 112 418 508 74 -539 -626 -357 -167 -1992 -824 -2369 -1295 -1083 -172 -171 -166 511 82 808 159 156 -112 316 -332 302 672 -121 -174 -45 -488 -702 150 6999 -1755 -1210 -1000 -677 -90 92 -352 313 61 73 155 331 380 -152 -229 -709 56 35 51 103 776 -24 741 462 -522 70 -357 -189 -17 401 144 -233 517 -9 59 -57 -157 -481 -935 -19 -341 274 -567 -496 131 -640 -141 -672 -290 -291 435 -129 -17 -175 155 603 350 594 -165 356 -88 290 95 -275 363 -614 -360 -716 441 -372 148 -44 312 -137 -192 307 -738 11 -799 -416 -46 -225 -250 -393 -178 -40 374 0 903 -325 306 519 292 344 106 868 -338 266 176 419 361 1021 -390 396 582 -137 631 179 765 243 81 303 340 45 -302 -342 -208 -111 -1528 -660 -2077 -1185 -1059 -179 -187 -187 573 89 809 148 136 -96 288 -340 347 817 -158 -226 -55 -584 -787 169 7919 -2184 -1573 -1372 -984 -141 147 -580 503 99 109 217 459 547 -234 -375 -1190 92 55 78 151 1086 -32 998 669 -830 118 -607 -331 -31 769 293 -468 1054 -19 119 -117 -308 -920 SS 20241117T145325.0Z 9087.620428 328 1 49.23 2 69.93 143.70 91.31 309.63 0.00 1 0.00 1 0 17 1.940e-02 5.552e-03 1.328e-02 2.026e-03 3.212408e-01 1.018773e-03 3.887922e-03 -6.000000e+00 1.104865e-02 222.83 -2.00 3.54 -2.00 318.81 0.00e+00 9.649373e-04 2.215086e-04 1.278107e-04 -6.000000e+00 4.866260e-04 278.02 -2.00 20.00 -2.00 318.17 0.00e+00 2.883 0.000 302.00 328.00 3 3.7115e+00 2.7624e-03 3.2473e-02 -6.0000e+00 2.7180e-02 -1.5582e-03 3.1679e-03 1.6537e-02 -6.0000e+00 2.9591e-02 3.8057e-04 2.2114e-03 8.2925e-03 -6.0000e+00 1.7642e-02 -9.3041e-03 1.1615e-03 2.5696e-03 -6.0000e+00 7.5654e-03 5.4376e-04 -2.2565e-04 6.2169e-05 2.9890e-05 -6.0000e+00 5.4667e-04 5.6976e-03 -7.4936e-05 10 0 0 10 0 0 99.94 22.11 0.21 0.00570 0.00400 63 14 1 5 0 781.360 26.21 20.00 22.11 15.70 22.1 937.58 -8183 -174 -7017 1602 -7050 -8299 -3921 -6091 1346 -2721 -7553 -4209 -1080 -3236 -908 -1645 649 -177 -2392 3217 -124 1399 324 3141 -2492 1266 163 -1977 1223 -604 307 57 253 -2886 -2140 -2130 -2634 -1480 -1159 -1053 -1076 -494 -1875 -726 -160 999 -133 394 -143 -201 923 521 876 341 936 1364 1242 393 238 483 1143 1406 1749 2175 100 165 267 -153 1337 518 310 253 236 763 -325 -70 -474 -947 -354 -948 -1259 -1068 -2298 -981 -950 -707 -103 220 365 269 579 566 266 387 630 17 228 895 -218 -344 -260 -864 -314 502 -908 -1076 -659 -612 -329 472 80 -63 165 37 -48 172 515 123 351 68 -521 -11 262 276 314 586 23 1203 827 -110 320 -303 -119 -17 324 -28 -211 453 -189 -258 -89 -236 -468 -407 -9 -377 73 -319 -380 -187 -334 75 -165 -485 -283 -82 -278 -88 -177 72 -21 -303 399 -16 179 44 438 -387 196 25 -296 169 -87 48 10 47 -564 -393 -395 -545 -356 -334 -352 -391 -187 -745 -288 -63 392 -52 152 -55 -80 388 237 421 166 471 699 648 206 123 260 605 804 1090 1441 67 104 159 -91 843 372 243 207 192 593 -237 -46 -299 -582 -219 -667 -1003 -943 -2104 -934 -969 -770 -117 258 429 304 607 545 250 356 612 17 264 1146 -288 -450 -335 -1035 -352 568 -1125 -1416 -867 -849 -481 734 128 -103 263 57 -70 234 693 173 524 108 -855 -17 413 420 453 807 31 1646 1159 -167 518 -515 -198 -29 590 -53 -404 884 -375 -502 -174 -443 -858 SS 20241117T150835.6Z 9087.630968 338 1 6.59 2 68.34 147.14 93.33 312.13 0.00 1 0.00 1 0 17 2.403e-02 7.715e-03 1.826e-02 4.673e-03 2.992760e-01 2.344295e-03 3.638125e-03 -6.000000e+00 1.369155e-02 222.83 -2.00 3.54 -2.00 317.73 0.00e+00 5.333677e-04 3.798290e-04 1.269654e-04 -6.000000e+00 6.028785e-04 278.01 -2.00 20.00 -2.00 317.09 0.00e+00 2.685 0.000 302.00 328.00 3 4.0731e+00 6.1774e-03 3.0190e-02 -6.0000e+00 3.3682e-02 -2.4124e-03 6.9850e-03 1.5257e-02 -6.0000e+00 3.6668e-02 -4.8546e-03 4.3848e-03 7.6085e-03 -6.0000e+00 2.1861e-02 -5.7418e-03 2.2363e-03 2.2392e-03 -6.0000e+00 9.3759e-03 4.7282e-04 3.1777e-05 1.3873e-04 2.5784e-05 -6.0000e+00 6.7726e-04 5.5053e-03 -3.8642e-05 12 9 1 12 9 1 97.26 22.11 0.18 0.00551 0.00574 4 8 1 5 0 1317.330 26.21 19.99 22.11 15.83 22.1 938.15 -4223 2688 -10019 6780 -9378 -8066 -1681 1852 7264 -12644 -4867 -3914 1408 -521 3940 -6282 2650 -935 -1713 -184 -1579 2032 1916 -455 2387 26 2138 -1701 -1230 403 2431 2029 2334 -803 -62 -1007 -2370 -1096 381 -786 -1315 -1461 -2042 -183 149 -444 -573 -619 -1054 246 1983 -144 1868 1317 454 2823 904 441 602 342 1012 1637 2510 1669 331 -658 313 -606 1263 521 -439 395 571 99 -708 -757 -871 -621 171 -959 -2060 -1427 -2620 -2431 6 -984 -650 -392 44 -74 274 1531 -6 1074 904 526 -102 923 -46 -455 236 -495 -120 369 -600 -860 -750 -361 -187 357 1257 73 160 176 -130 -251 939 178 699 -432 -746 307 633 -475 66 871 -142 1306 -9 -85 -21 -220 -272 -177 -9 335 -309 302 -107 -1 -305 -84 -309 -354 226 -961 530 -784 -665 -141 169 690 -1449 -518 -443 174 -76 629 -1162 493 -181 -348 -38 -335 416 409 -106 566 6 520 -404 -276 91 579 529 658 -236 -17 -282 -748 -384 158 -365 -641 -746 -1081 -96 78 -233 -297 -316 -537 126 1067 -85 1104 827 297 1847 613 299 399 227 694 1160 1923 1323 265 -513 228 -441 968 438 -392 365 525 87 -607 -607 -638 -454 126 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