File name: Pandora39s1_DearbornMI_20250725_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250726T054901.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20250725_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20250725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250725T124912.1Z 9337.534168 113 1 1.39 2 64.24 86.42 72.45 79.25 0.00 1 0.00 1 0 17 2.824e-02 9.108e-03 2.326e-02 7.300e-03 3.093822e-01 3.801780e-03 3.687461e-03 -6.000000e+00 1.669306e-02 232.57 -2.00 3.54 -2.00 317.20 0.00e+00 1.771030e-04 5.401773e-04 2.545034e-04 -6.000000e+00 7.387221e-04 288.01 -2.00 20.00 -2.00 316.38 0.00e+00 2.287 0.000 302.00 328.00 3 3.3962e+00 1.0104e-02 2.7866e-02 -6.0000e+00 4.1873e-02 4.3981e-03 1.1313e-02 1.6309e-02 -6.0000e+00 4.5182e-02 -4.6695e-03 6.7546e-03 7.8679e-03 -6.0000e+00 2.6890e-02 -4.6319e-03 3.3065e-03 2.1395e-03 -6.0000e+00 1.1406e-02 1.2895e-03 1.0502e-03 2.1462e-04 2.4807e-05 -6.0000e+00 7.9804e-04 5.2997e-03 6.1715e-06 12 9 1 12 1 1 999.00 22.42 0.14 0.00530 0.01319 1 16 1 5 0 692.590 26.41 20.00 22.42 30.59 25.7 1018.24 -7159 12400 -6354 7475 -14663 10096 -906 -1362 3608 -4054 7447 -4471 -5997 -8624 4134 -327 736 -2061 3326 4280 -2193 -1545 1798 1049 -3837 6224 -1036 599 1711 -449 -1315 2479 3025 -2816 -442 -4054 -496 -271 431 -736 -670 -1813 -264 -591 -1127 43 -1121 1283 -985 1480 -118 -1054 286 734 -137 2609 435 667 774 -643 1024 467 2772 2412 -134 283 537 -307 881 1677 -803 722 -514 997 560 -421 -55 -1911 60 -598 -1657 -1673 -1182 -1255 -537 -1127 -358 134 679 1319 -643 -551 415 -65 1009 -555 748 487 -278 -1363 -365 -352 -317 265 -1226 -1295 -404 -478 108 2 731 1019 -713 -321 686 234 1603 6 1355 11 -224 -602 -425 1057 71 1554 -817 1417 1 447 -415 337 123 -430 493 -950 -133 145 -100 -39 -162 -429 -172 -803 1230 -761 741 -1599 897 -95 -161 447 -562 924 -650 -1017 -1682 811 -73 166 -502 802 1060 -585 -411 483 293 -1183 1795 -317 169 468 -128 -397 786 1002 -996 -149 -1391 -183 -111 205 -387 -372 -1065 -157 -347 -665 26 -667 733 -572 859 -72 -685 190 514 -97 1851 321 488 555 -467 761 360 2275 2019 -113 233 427 -244 729 1487 -764 689 -494 923 502 -351 -44 -1493 48 -517 -1564 -1678 -1239 -1361 -597 -1324 -431 163 822 1550 -740 -603 433 -66 1064 -623 894 625 -368 -1802 -466 -429 -371 316 -1548 -1674 -533 -654 152 3 1093 1550 -1074 -466 955 313 2132 8 1911 17 -333 -891 -622 1513 100 2071 -1084 1869 2 637 -613 507 186 -671 795 -1573 -225 248 -173 -65 -271 -704 -278 SU 20250725T141518.6Z 9337.593965 171 1 49.40 2 48.41 101.77 57.23 93.07 0.00 1 0.00 1 0 17 1.018e-02 6.344e-03 4.927e-03 2.046e-03 2.075797e-01 1.063930e-03 2.509139e-03 -6.000000e+00 6.014741e-03 232.57 -2.00 3.54 -2.00 316.80 0.00e+00 1.800067e-04 1.339684e-04 5.351389e-05 -6.000000e+00 2.662742e-04 288.01 -2.00 20.00 -2.00 315.98 0.00e+00 1.504 0.000 302.00 328.00 3 5.1891e+00 2.8106e-03 1.8501e-02 -6.0000e+00 1.5087e-02 1.7082e-02 3.1353e-03 1.0997e-02 -6.0000e+00 1.6281e-02 -5.3011e-04 1.8265e-03 5.3184e-03 -6.0000e+00 9.6894e-03 -5.4122e-03 8.6388e-04 1.4551e-03 -6.0000e+00 4.1088e-03 5.3454e-04 2.5104e-04 6.1403e-05 1.7990e-05 -6.0000e+00 2.8766e-04 7.3476e-03 6.6050e-06 10 0 0 10 0 0 99.90 22.41 0.44 0.00735 0.00923 40 9 1 5 0 1234.780 26.41 20.00 22.41 34.03 25.8 1039.29 -3469 115 -1189 -4203 -1760 -2146 1181 -685 799 -2391 -1725 -1153 -2607 361 -149 -136 621 791 448 2176 333 694 1108 1256 1174 470 -157 -925 696 340 1717 1526 954 -859 -2403 -938 -2878 -432 -600 -713 -750 -188 -690 -1053 82 -1154 -327 -255 -751 487 546 628 929 951 536 1349 695 256 147 167 824 1188 1680 1429 -127 -282 140 -836 1250 228 218 439 358 658 -30 -35 -873 -948 -84 -1238 -1520 -930 -2305 -1617 -749 -685 99 392 331 327 484 196 168 428 268 164 561 784 45 -468 -343 -794 -472 450 -433 -1353 -313 -871 -180 675 389 27 166 185 -93 123 356 286 365 -112 -565 -82 424 224 306 749 17 1139 873 39 339 -415 -37 -169 183 133 -246 593 -129 -158 -206 -425 -693 -583 20 -204 -673 -248 -300 172 -113 142 -449 -316 -219 -559 85 -39 -38 178 233 137 671 105 217 356 423 412 170 -56 -309 214 104 544 515 345 -315 -837 -323 -1119 -191 -301 -411 -466 -120 -454 -698 53 -755 -206 -156 -449 289 340 414 642 688 399 1012 531 195 110 125 637 980 1415 1265 -112 -238 109 -644 1001 198 206 431 350 619 -26 -29 -662 -682 -63 -1031 -1415 -901 -2408 -1760 -865 -810 122 499 422 402 574 213 166 405 265 177 669 982 60 -616 -425 -961 -540 525 -551 -1761 -421 -1233 -264 994 601 43 251 271 -126 155 459 367 500 -166 -866 -124 628 319 412 1000 22 1425 1148 53 478 -607 -54 -258 281 216 -413 1012 -224 -270 -342 -685 -1092 SU 20250725T143558.4Z 9337.608315 184 1 14.26 2 44.71 106.13 53.56 96.72 0.00 1 0.00 1 0 17 8.064e-03 6.285e-03 1.269e-03 7.302e-04 1.930577e-01 3.830873e-04 2.334170e-03 -6.000000e+00 4.765780e-03 232.57 -2.00 3.54 -2.00 315.72 0.00e+00 2.614987e-04 3.805630e-05 4.696180e-05 -6.000000e+00 2.109790e-04 288.01 -2.00 20.00 -2.00 314.97 0.00e+00 1.405 0.000 302.00 328.00 3 2.7026e+00 9.9803e-04 1.7223e-02 -6.0000e+00 1.1954e-02 8.0845e-04 1.1078e-03 1.0164e-02 -6.0000e+00 1.2900e-02 -2.7710e-03 6.3351e-04 4.9113e-03 -6.0000e+00 7.6774e-03 -3.4789e-03 2.8504e-04 1.3433e-03 -6.0000e+00 3.2556e-03 7.3179e-03 2.8008e-04 2.1537e-05 1.7715e-05 -6.0000e+00 2.2792e-04 7.2537e-03 6.9545e-06 12 1 1 12 1 1 99.98 22.41 0.27 0.00725 0.00936 114 88 1 5 0 123.960 26.41 20.00 22.41 32.05 25.9 1026.49 -922 -384 -865 -2561 -1324 -1224 -549 580 656 -1274 -1533 -450 -624 -412 433 -337 34 280 810 1279 328 1040 1187 459 413 797 -120 -46 225 1124 903 1324 1288 -1874 -2174 -1537 -2055 -915 -353 -806 -1153 -448 -557 -720 26 -340 -488 -273 -740 294 691 412 1134 1179 615 1073 747 313 504 661 890 1231 1384 1434 -241 -169 -68 -413 852 392 113 402 52 513 -107 -132 -329 -920 -67 -1014 -1261 -1349 -2304 -1557 -912 -693 -254 115 359 134 273 447 -127 410 511 -51 474 847 -26 -480 -149 -853 -460 432 -546 -1180 -530 -455 -299 490 385 234 165 119 -41 256 492 281 585 249 -417 8 307 163 432 619 -68 1172 737 127 193 -305 -117 -44 218 -31 -225 424 -141 -276 -114 -491 -678 -239 -96 -233 -634 -291 -266 -127 148 182 -368 -434 -131 -186 -138 159 -133 14 116 343 554 144 451 529 200 187 369 -55 -21 95 468 394 609 584 -873 -1022 -721 -994 -510 -217 -570 -824 -329 -419 -544 19 -252 -352 -202 -536 211 519 308 883 959 515 908 642 268 424 557 775 1075 1297 1405 -234 -151 -60 -353 762 373 111 408 53 502 -104 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