File name: Pandora103s1_Downsview_20171215_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T223543.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20171215_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171215T125128.0Z 6558.535741 1 1 36.00 2 89.87 123.36 66.69 142.41 0.00 1 0.00 1 0 22 9.728e-02 9.512e-02 9.727e-02 9.474e-02 2.435627e+03 5.508107e+03 7.017534e+02 -6.000000e+00 4.866713e+03 273.75 -2.00 20.00 -2.00 505.23 0.00e+00 2.018316e-03 2.512293e-03 1.367294e-04 -6.000000e+00 2.607971e-03 273.75 -2.00 20.00 -2.00 499.98 0.00e+00 1.858595e+00 1.884497e+00 1.749936e-01 -6.000000e+00 1.870624e+00 222.18 -2.00 3.57 -2.00 501.65 0.00e+00 20.532 0.169 489.00 513.00 1 1.0065e+01 1.4363e-01 3.9286e-02 -6.0000e+00 1.4246e-01 1.4031e-01 3.7991e-02 2.9684e-03 -6.0000e+00 3.7942e-02 3.9973e-06 -1.0327e-02 7.1295e-03 6.7252e-05 -6.0000e+00 7.5868e-03 1.3446e-02 1.4681e-04 12 8 8 10 0 0 97.33 15.00 7.11 0.01345 -0.05819 9 1 1 4 0 4000.000 21.98 15.00 19.02 1372 -5759 -4914 -6245 13159 1270 -4697 10176 -2115 8189 1635 -764 -13610 -3465 -8364 890 -4912 4327 -7333 4525 23616 611 -20 -5940 -7996 -4400 -1205 1989 6404 -4719 13502 -2953 5696 -21 12422 3868 -6293 2039 -13588 -4855 20057 5642 5078 19214 -1091 8903 9499 -16616 -12297 9303 -5362 14377 3554 2513 -5169 13011 -7139 7240 -10643 12465 7649 -2760 21472 10897 4762 4495 -10450 2100 1938 793 -8608 2974 8990 6875 -1677 6564 4780 3864 4995 -11948 -10346 -4857 7657 -578 4598 9180 1947 -19090 -4080 6236 5184 -1307 -2775 -6155 -24210 16952 -4216 11009 5010 6532 2161 5866 -4728 8532 -330 18981 766 -3397 -6000 20041 7692 5901 790 11010 12541 -1557 -11607 -5907 20083 1765 16477 4266 2454 65 12628 -3313 -17984 -8756 15065 -10299 2733 7554 8279 -2561 -4370 3421 -27752 9611 -11121 -3863 -2530 18841 -550 -2091 -8636 13853 4094 -4256 -1560 31059 900000 1303 -5852 -5075 -6805 12324 1361 -5443 10402 -2451 8533 1780 -837 -16684 -3779 -9428 912 -5346 4381 -8575 4853 21122 681 -22 -7038 -9717 -5205 -1378 2195 6703 -5307 12176 -3080 5508 -22 12117 4216 -7524 2211 -16906 -5471 17624 5715 5226 17446 -1222 9128 9688 -21595 -15084 9088 -5859 12529 3350 2367 -5319 11679 -8055 7235 -12682 11787 7520 -3007 18651 10497 4850 4530 -11925 2081 1901 777 -9060 2774 7961 6287 -1696 6174 4494 3562 4476 -12512 -10632 -4763 6711 -549 4191 8110 1851 -22181 -4079 5625 4731 -1279 -2810 -6557 -30612 14114 -4219 9276 4347 5435 1834 4795 -4371 7240 -319 15433 733 -3318 -5881 15184 6669 5313 760 9714 10970 -1564 -12915 -6271 16579 1712 13597 3888 2238 61 10603 -3255 -20337 -9052 12293 -10739 2524 6564 6967 -2354 -4040 2936 -33029 8182 -11731 -3841 -2504 15182 -535 -2081 -9199 11868 3806 -4167 -1439 20540 900000 SO 20171215T125326.0Z 6558.537107 3 1 36.01 2 89.57 123.70 66.48 142.87 0.00 1 0.00 1 0 36 8.832e-02 8.590e-02 8.783e-02 8.579e-02 -4.948354e+03 4.518288e+03 5.520370e+02 -6.000000e+00 4.417293e+03 273.75 -2.00 20.00 -2.00 505.22 0.00e+00 6.117560e-03 2.258739e-03 2.694827e-04 -6.000000e+00 2.367294e-03 273.75 -2.00 20.00 -2.00 499.97 0.00e+00 4.433476e+00 1.701802e+00 4.275809e-02 -6.000000e+00 1.697330e+00 222.18 -2.00 3.57 -2.00 501.61 0.00e+00 20.078 0.158 489.00 513.00 1 9.7939e+00 1.2999e-01 3.6372e-02 -6.0000e+00 1.2928e-01 1.0942e-01 3.4245e-02 2.0159e-03 -6.0000e+00 3.4412e-02 4.4336e-06 -1.5612e-02 6.3755e-03 1.0496e-04 -6.0000e+00 6.8872e-03 2.0672e-02 1.3641e-04 12 8 8 10 0 0 -3.37 15.00 8.50 0.02067 -0.08762 9 1 1 4 0 4000.000 21.98 15.00 19.02 -10669 -4683 -14699 4824 -7003 -3654 -8592 8042 -197 16223 -5563 4251 -4737 -5707 -1154 -1860 1635 1998 2829 -1859 6545 -11303 15521 -2010 18564 -1646 5653 -5110 6752 -1969 17065 4345 772 -12297 -2942 7541 6881 -2221 -7409 17303 -4170 2428 -7968 4940 5093 4958 -338 13704 118 2636 -8502 3220 8235 2836 15584 2269 -4284 3171 -8005 15834 -1831 3003 -2750 11168 -4669 -1322 9216 -16415 4892 -4410 8387 5977 5899 -19863 9772 8970 19085 -11596 -7167 3150 -4397 3590 847 14035 4936 15008 -9830 -14798 -5267 6040 3606 7743 3788 5378 -6920 -5584 11521 9338 -5028 118 -3457 -4091 -5735 4081 -878 -722 -449 -2806 11074 -13230 790 -2222 4503 10660 7659 3510 8113 -9731 22955 2533 13880 2397 9764 -5939 6102 -10580 5922 -10622 518 2675 207 9992 -5189 600 -1483 6303 -15219 25656 -1431 -5959 12349 6648 1746 13891 -17070 1847 -12018 -16887 8979 -109 900000 -11541 -4732 -16699 4718 -8001 -4138 -10405 8454 -226 15807 -6569 4470 -5361 -6403 -1218 -1961 1667 2055 2962 -2099 6864 -14034 14831 -2275 17301 -1888 6054 -6052 7080 -2183 14986 4216 779 -14369 -3282 7881 7245 -2511 -8683 15748 -4636 2540 -9338 5179 5413 5341 -385 13523 131 2804 -9815 3203 7588 2713 13254 2275 -4747 3343 -9461 14758 -2009 3142 -3065 10895 -5295 -1435 8850 -19771 4720 -4602 7572 5442 5378 -23439 8776 8206 15632 -12417 -7198 2837 -4240 3214 785 11431 4389 12199 -10190 -16033 -5173 5303 3249 6734 3485 5003 -7357 -5849 10181 8351 -5030 109 -3192 -3749 -5372 3561 -830 -684 -416 -2588 8736 -13104 694 -2060 4017 9203 6938 3341 7419 -10586 18039 2382 11472 2189 8225 -5845 5430 -11131 5305 -11195 488 2471 197 8605 -5062 542 -1340 5233 -15814 18495 -1367 -6008 10488 5956 1636 11647 -19502 1764 -13014 -18625 7413 -96 900000 SO 20171215T125520.0Z 6558.538426 5 1 36.01 2 89.29 124.03 66.28 143.31 0.00 1 0.00 1 0 15 8.423e-02 8.190e-02 7.598e-02 7.439e-02 1.427106e+03 4.032634e+03 1.921237e+02 -6.000000e+00 4.214650e+03 273.75 -2.00 20.00 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