File name: Pandora103s1_Downsview_20171216_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T223616.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20171216_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171216T125211.0Z 6559.536238 1 1 36.00 2 89.87 123.42 74.35 134.10 0.00 1 0.00 1 0 29 1.335e-01 1.213e-01 1.154e-01 1.101e-01 -7.073786e+03 5.747259e+03 1.987496e+02 -6.000000e+00 6.674342e+03 273.66 -2.00 20.00 -2.00 505.14 0.00e+00 7.290433e-03 2.908259e-03 3.448788e-04 -6.000000e+00 3.578475e-03 273.66 -2.00 20.00 -2.00 499.75 0.00e+00 3.349209e+00 2.219409e+00 1.317869e-01 -6.000000e+00 2.568807e+00 222.20 -2.00 3.57 -2.00 501.42 0.00e+00 20.531 0.169 489.00 513.00 1 1.0051e+01 1.6963e-01 3.9276e-02 -6.0000e+00 1.9560e-01 1.6522e-01 4.5441e-02 2.9654e-03 -6.0000e+00 5.2145e-02 3.4071e-06 3.8967e-03 8.1782e-03 9.5883e-05 -6.0000e+00 1.0410e-02 1.9391e-02 5.6714e-05 12 8 8 10 0 0 1.51 15.00 12.90 0.01939 0.04642 9 1 1 4 0 4000.000 21.69 15.00 18.65 1102 -12959 8764 -14423 3215 -3353 27813 -13957 19920 15263 5710 7413 8308 -589 3311 -5893 23505 -12154 1556 3395 -10675 377 1718 13340 -577 344 -13142 13686 -17798 15853 -12529 15749 -10332 12433 9810 -4422 -6094 10552 9794 -4351 2305 -3433 218 -13272 4885 -13228 21846 -15673 14434 4256 10924 1073 -10333 5677 12319 -4095 -9829 7153 8135 5278 4890 29372 -16988 16432 -2013 11371 -2206 20276 -8587 24140 -14595 34032 1478 9616 -15071 -5044 -8582 12214 92 1783 -12916 22612 15573 -6004 5010 -4333 5454 -6649 13786 10412 10190 -17690 10376 7520 10165 -2992 19798 -11162 8534 -5130 -13672 4628 6613 13588 4768 2005 11602 -2556 4667 12028 -21932 6252 -2422 28751 -9061 9543 -13845 8276 -12323 7888 -688 -18469 4213 27028 -4660 -10008 -2801 -16216 5932 3242 -8203 1266 54411 -19474 27789 -3800 2447 6822 23775 -17992 17057 -8857 16498 10595 24956 -1839 -1834 821 -12935 11338 900000 1096 -15061 8579 -18424 3538 -4002 25024 -18956 19355 15190 6093 7669 8363 -635 3404 -6624 20085 -15037 1733 3741 -13384 424 1906 13290 -665 393 -17075 13603 -23294 14265 -14482 13898 -11976 12091 10125 -5240 -7216 10472 9662 -4882 2437 -3882 242 -17035 5326 -17241 20144 -20471 13840 4385 10188 1071 -11348 5387 11338 -4583 -11884 7372 8267 5471 5085 24288 -22060 15373 -2224 10815 -2342 17053 -9431 18925 -16377 23908 1433 8740 -17559 -5264 -9007 10262 86 1637 -13715 17164 12618 -5984 4520 -4284 4883 -6654 11304 8843 8717 -20197 9285 7035 9290 -3107 16404 -12148 7406 -4917 -14013 3989 5707 11258 4296 1805 9258 -2288 3868 9438 -24524 5477 -2376 21316 -9779 8637 -15663 7463 -13268 6849 -643 -20322 3739 19558 -4597 -10378 -2711 -17789 5258 2968 -8320 1145 28799 -20561 18373 -3455 2155 5867 17507 -19899 13375 -8882 13021 8927 18371 -1735 -1677 702 -12288 8526 900000 SO 20171216T125408.0Z 6559.537593 3 1 36.00 2 89.58 123.76 74.11 134.50 0.00 1 0.00 1 0 22 1.084e-01 1.008e-01 1.029e-01 9.951e-02 -3.521630e+02 5.252745e+03 7.009493e+02 -6.000000e+00 5.420121e+03 273.66 -2.00 20.00 -2.00 505.09 0.00e+00 8.727739e-03 2.648394e-03 4.085103e-04 -6.000000e+00 2.905130e-03 273.66 -2.00 20.00 -2.00 499.79 0.00e+00 7.468303e-01 2.005301e+00 1.608164e-01 -6.000000e+00 2.084991e+00 222.20 -2.00 3.57 -2.00 501.44 0.00e+00 20.082 0.158 489.00 513.00 1 1.0174e+01 1.5433e-01 3.8741e-02 -6.0000e+00 1.5877e-01 2.0745e-01 4.0317e-02 2.7253e-03 -6.0000e+00 4.2306e-02 3.7885e-06 -6.5463e-03 7.5553e-03 1.4691e-04 -6.0000e+00 8.4532e-03 3.2392e-02 5.2392e-06 12 8 8 10 0 0 -10.15 14.99 5.48 0.03239 -0.01302 9 1 1 4 0 4000.000 21.79 14.99 18.66 -8129 -7131 10667 -921 -3361 10526 -8636 -7166 1247 15046 -683 -8130 -13594 -8731 2465 -10035 4859 7712 -2591 -1330 -2656 -150 9951 62 20178 2053 1794 -10223 9539 6630 9892 -249 -10314 9567 -7057 5452 11148 1930 -6111 8108 -58 4480 -14120 9583 1124 -7366 -850 -275 2791 28367 -2369 25076 6552 16228 18273 14241 -11155 12352 21141 8813 9531 19202 4098 -15429 5701 -16168 -4649 17252 -1058 433 -5101 -3521 -1935 1516 -9326 12092 13278 -4656 -9103 -9423 -25013 1313 2868 19922 -15442 -4999 11373 -3158 -9342 23378 -14839 436 -8545 11035 -9162 -18 2017 2748 -5294 -11680 10768 -1481 -5424 -4099 1195 2740 14752 4839 -1551 38602 79 -3465 24194 3318 10920 9933 15725 -6250 6852 1565 10586 29800 -3824 434 -4017 16357 271 3396 2582 1268 10416 -3039 -5878 18479 -561 -8119 -8279 65 8018 -116 -17763 4220 -6820 8919 -6669 2737 2995 -22419 -5855 -986 900000 -8886 -7748 10047 -1013 -3909 10888 -10961 -9083 1457 15157 -781 -9796 -16975 -10190 2543 -11613 4881 7652 -2921 -1510 -3041 -167 10014 69 18577 2272 1988 -12668 9611 6580 9111 -251 -11559 9132 -8282 5782 11066 2058 -6953 7945 -61 4589 -17599 9654 1249 -8978 -974 -310 3005 23413 -2550 20050 6134 13779 15534 13102 -13542 12127 19081 8902 9517 17557 4368 -19878 5951 -20534 -5170 15231 -1101 438 -5329 -3598 -1958 1500 -10400 10979 11657 -4728 -9515 -9813 -30189 1236 2668 15674 -17165 -5057 9801 -3107 -9672 17584 -16170 414 -9094 9940 -10046 -18 1936 2561 -5169 -11743 8493 -1307 -5044 -3892 1109 2494 11704 4130 -1384 23501 71 -3320 18181 3109 9614 8869 13334 -6563 6281 1479 8997 20714 -3634 399 -3907 13080 253 3073 2341 1168 8789 -2862 -5543 13512 -485 -7548 -7887 58 6731 -106 -19294 3689 -6623 7476 -6516 2432 2602 -24018 -5152 -815 900000 SO 20171216T125603.0Z 6559.538924 5 1 36.00 2 89.29 124.10 73.87 134.89 0.00 1 0.00 1 0 15 9.543e-02 9.377e-02 8.846e-02 8.558e-02 5.743158e+03 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