File name: Pandora103s1_Downsview_20171229_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225310.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20171229_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20171229 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171229T125753.0Z 6572.540197 1 1 36.00 2 89.87 123.21 123.40 343.81 0.00 1 0.00 1 0 22 4.306e-02 4.259e-02 3.922e-02 3.856e-02 -1.954379e+03 2.037234e+03 4.415025e+02 -6.000000e+00 2.145934e+03 272.85 -2.00 20.00 -2.00 505.19 0.00e+00 4.337111e-03 1.013331e-03 2.146613e-04 -6.000000e+00 1.149561e-03 272.85 -2.00 20.00 -2.00 499.83 0.00e+00 2.997332e+00 7.585798e-01 5.387139e-02 -6.000000e+00 8.203596e-01 222.72 -2.00 3.57 -2.00 501.50 0.00e+00 20.547 0.169 489.00 513.00 1 9.0424e+00 5.8156e-02 3.7641e-02 -6.0000e+00 6.2574e-02 1.5285e-01 1.5123e-02 2.0880e-03 -6.0000e+00 1.6444e-02 1.0083e-05 7.3884e-03 2.9202e-03 7.3197e-05 -6.0000e+00 3.3345e-03 1.3679e-02 -3.7038e-05 12 8 8 10 0 0 84.57 15.00 5.21 0.01368 0.06493 9 1 1 4 0 4000.000 21.98 15.00 18.98 -8082 -4638 2172 -954 -2824 1582 1433 -1118 -1692 930 550 -4662 1105 -3862 -2224 -2784 2618 3057 2360 -9707 2114 3189 2724 -1415 2238 2176 -1919 4606 409 2560 -523 653 -5109 98 -8662 11303 3160 -197 1466 6571 -4072 3359 -2276 3511 -1067 1522 1424 2102 871 4127 -103 -5906 5897 -2485 615 2381 7782 5611 3308 -1506 -382 510 5297 -2221 6337 -2129 1800 -5126 -589 3296 -2173 144 -2706 8559 1104 6349 -2449 9605 -5695 -8331 -2661 6190 -9994 -714 -2843 -372 -7756 1885 -5013 1868 -5744 5658 4798 -1454 1474 687 2406 -6859 2383 -5563 1811 724 437 2582 9847 -1921 6614 3167 1374 3268 1258 -1795 5702 2591 9673 7667 -6428 -3220 -5385 3988 -2134 724 2410 3891 -6938 7500 -1540 3760 -1519 6631 -5657 -4082 -6534 3689 804 -2411 -580 -445 3673 -695 -4327 -2122 -1373 -3125 307 -4783 4029 1268 -607 -7320 2652 -8602 -4870 2218 -1046 -3223 1761 1630 -1314 -1990 1045 607 -5350 1177 -4245 -2386 -3009 2716 3246 2598 -12115 2338 3490 2989 -1624 2501 2435 -2224 4968 446 2605 -536 665 -5626 107 -10691 11476 3415 -216 1564 6607 -4557 3529 -2562 3786 -1217 1695 1575 2274 937 4183 -105 -6189 5426 -2505 622 2458 7785 5756 3452 -1633 -410 546 5426 -2439 6323 -2260 1800 -5405 -587 3100 -2125 138 -2693 7752 1086 5851 -2389 8153 -5567 -8314 -2522 5427 -10255 -671 -2755 -354 -7883 1735 -4918 1716 -5712 5128 4489 -1458 1423 661 2240 -6792 2089 -5123 1536 627 391 2351 8440 -1815 5613 2718 1190 2817 1132 -1702 5131 2437 8537 6925 -6681 -3229 -5420 3592 -2011 655 2145 3464 -6896 6465 -1450 3346 -1422 5770 -5497 -3813 -6119 3075 685 -2158 -525 -409 3277 -651 -4197 -2011 -1300 -3031 288 -4677 3514 1094 -520 -6706 2248 SO 20171229T125951.0Z 6572.541562 3 1 36.00 2 89.58 123.55 123.48 344.35 0.00 1 0.00 1 0 22 3.617e-02 3.516e-02 3.526e-02 3.467e-02 6.134780e+01 1.895530e+03 1.640902e+02 -6.000000e+00 1.802640e+03 272.85 -2.00 20.00 -2.00 505.18 0.00e+00 5.368307e-03 9.056025e-04 2.613771e-04 -6.000000e+00 9.675574e-04 272.85 -2.00 20.00 -2.00 499.78 0.00e+00 2.756183e+00 6.955006e-01 4.862945e-02 -6.000000e+00 6.968175e-01 222.72 -2.00 3.57 -2.00 501.45 0.00e+00 20.093 0.158 489.00 513.00 1 8.9969e+00 5.3099e-02 3.6363e-02 -6.0000e+00 5.3038e-02 1.5379e-01 1.4037e-02 2.0262e-03 -6.0000e+00 1.4147e-02 1.1243e-05 1.9035e-03 2.6090e-03 6.6499e-05 -6.0000e+00 2.8205e-03 3.7144e-02 -5.9831e-05 12 8 8 10 0 0 -2.25 15.00 3.73 0.03714 0.05035 9 1 1 4 0 4000.000 21.98 15.00 18.99 -1859 -736 -1680 -5070 4140 -2892 4027 -1006 655 -4639 2111 -1208 -2772 -3019 686 2552 4097 411 59 465 906 266 1439 1340 -2400 2124 2410 -868 -3250 -1932 378 -1099 -3194 2365 -2257 3056 -3026 2577 -4547 -1865 6193 1280 -1337 -1394 1837 1245 1590 8213 3574 779 -642 -1128 5001 -3935 -4312 5888 256 3667 8115 -1843 -353 -2109 4164 -2944 -3927 3441 -3890 -591 -2319 667 -3768 2206 -1642 1094 -1114 -222 -5912 -4974 439 2507 3959 2079 -2659 3061 1594 4192 5508 2363 -1776 1896 4173 3374 -4816 -4938 5598 4361 4720 7535 -5245 -5855 -5931 1586 -806 868 1056 -273 -3707 5057 -3179 -2051 2309 3533 -4445 -3123 3460 -4467 1104 4174 -1754 6934 5079 -6527 2457 4151 -6347 4685 -1598 3015 -91 545 -3282 2623 -232 2719 -7025 -8447 6258 -1683 4455 -498 4156 -6216 -1799 1614 3671 -110 -1458 2997 3836 -8261 900000 -1864 -742 -1774 -5772 4413 -3359 4463 -1182 754 -5523 2301 -1342 -3072 -3293 714 2609 4168 444 66 524 1009 298 1590 1488 -2790 2370 2670 -987 -3681 -2059 383 -1133 -3422 2507 -2599 3354 -3467 2752 -5135 -2031 6250 1369 -1487 -1574 2036 1393 1763 8414 3765 823 -663 -1137 4666 -4028 -4575 5876 276 3855 8135 -2020 -380 -2329 4343 -3279 -4372 3496 -4152 -601 -2372 650 -3770 2084 -1624 1068 -1125 -220 -6022 -4902 406 2261 3523 1900 -2546 2774 1479 3810 4924 2163 -1683 1732 3744 3102 -4913 -5093 5159 4007 4245 6412 -4899 -5342 -5336 1337 -715 789 977 -253 -3470 4251 -2862 -1849 2043 3157 -4378 -3080 3218 -4506 1061 3891 -1709 6084 4461 -6319 2171 3659 -6246 4137 -1501 2698 -84 501 -3113 2293 -204 2287 -6441 -7972 5266 -1558 3923 -464 3701 -6114 -1703 1488 3323 -102 -1341 2544 3140 -7593 900000 SO 20171229T130146.0Z 6572.542894 5 1 36.00 2 89.29 123.88 123.57 344.88 0.00 1 0.00 1 0 22 2.908e-02 2.903e-02 2.789e-02 2.749e-02 4.111916e+03 1.648082e+03 2.812492e+02 -6.000000e+00 1.449638e+03 272.85 -2.00 20.00 -2.00 505.23 0.00e+00 4.509820e-03 7.193743e-04 2.306328e-04 -6.000000e+00 7.778107e-04 272.85 -2.00 20.00 -2.00 499.90 0.00e+00 2.710402e+00 5.473075e-01 4.589936e-02 -6.000000e+00 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