File name: Pandora103s1_Downsview_20180109_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225415.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180109_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180109T125718.0Z 6583.539792 1 1 36.01 2 89.87 121.50 52.55 202.62 0.00 1 0.00 1 0 27 1.315e-01 1.218e-01 1.270e-01 1.219e-01 2.541377e+03 6.843174e+03 2.336352e+02 -6.000000e+00 6.535516e+03 272.17 -2.00 20.00 -2.00 505.14 0.00e+00 1.702332e-03 3.200204e-03 1.427357e-04 -6.000000e+00 3.511848e-03 272.17 -2.00 20.00 -2.00 499.93 0.00e+00 -4.994082e-01 2.394872e+00 1.134792e-01 -6.000000e+00 2.536255e+00 223.16 -2.00 3.57 -2.00 501.56 0.00e+00 20.552 0.169 489.00 513.00 1 1.0504e+01 1.8105e-01 3.8142e-02 -6.0000e+00 1.9298e-01 2.0467e-01 4.9180e-02 2.5858e-03 -6.0000e+00 5.1510e-02 3.0680e-06 -5.9971e-03 9.2509e-03 5.7110e-05 -6.0000e+00 1.0249e-02 -4.3014e-02 3.8991e-04 12 8 8 10 0 0 -8.04 15.00 15.65 -0.04301 -0.08461 9 1 1 4 0 4000.000 21.98 15.00 18.98 -299 28020 -2287 6121 -8292 16790 -2144 3397 -10369 13389 -8089 1096 -5091 -10952 -22649 9631 -1640 16312 -2556 6679 16292 22625 3932 14304 4332 -13825 -346 -12970 9391 -1112 23624 12866 19146 -18885 28699 15028 4359 13237 -5839 -5515 -16602 -2427 8366 -4492 -14541 12368 -3429 18896 956 -1380 4067 -5936 -15432 5456 -13464 -9794 -16200 6677 -4598 2621 19506 15716 13382 23340 6427 4483 -5264 8334 -10123 -2697 -8645 4962 6959 9432 19955 7623 20032 -22580 5277 -2038 -5043 7876 8782 20165 20715 -15627 -7287 -4942 -12397 -5167 1251 1054 -10223 3873 -339 2429 -4808 3292 -17242 -1884 1623 22507 36990 41985 -22774 31592 -6672 -5681 -2360 -5643 3993 12416 7905 -14608 7879 9652 7641 -7986 7993 15312 14597 12064 -296 -1876 821 -15363 20718 -2221 -3812 2386 -6587 24599 13480 -10002 6280 4026 -15716 12161 1352 4178 -20508 -1730 5881 6631 -14103 32471 -8035 5339 13627 2584 900000 -297 21194 -2374 6101 -9830 15894 -2486 3800 -13313 13547 -9865 1202 -5851 -13064 -29808 9220 -1758 14956 -2900 7116 15833 20620 4285 14070 4716 -18055 -395 -16643 9585 -1209 19362 11562 16338 -23950 24063 14738 4703 12883 -6739 -6252 -20809 -2659 8342 -5129 -18547 12253 -3956 17365 1029 -1490 4039 -6270 -17433 4992 -15043 -10991 -19988 6715 -5166 2726 17113 14355 12595 19981 6452 4525 -5722 7796 -11199 -2743 -9141 4571 6336 8495 16540 7159 16381 -27101 4764 -1961 -4982 6927 7724 15927 16430 -17842 -7701 -5092 -13663 -5299 1209 1029 -11360 3817 -346 2365 -4918 3035 -18839 -1727 1409 15988 23392 26449 -27971 23184 -6984 -5768 -2271 -5578 3654 10676 7207 -16733 7295 8792 7129 -8725 7464 13090 12304 10213 -277 -1790 772 -16905 16045 -2141 -3703 2182 -6582 17869 10618 -9715 5147 3377 -16362 9907 1236 3755 -23538 -1655 5233 5888 -15346 22478 -8093 4580 10427 2163 900000 SO 20180109T125916.0Z 6583.541157 3 1 36.01 2 89.57 121.84 52.69 203.19 0.00 1 0.00 1 0 59 1.296e-01 1.204e-01 1.093e-01 1.050e-01 2.500174e+03 5.922912e+03 3.215152e+02 -6.000000e+00 6.439542e+03 272.17 -2.00 20.00 -2.00 505.23 0.00e+00 9.098048e-03 2.723182e-03 5.045500e-04 -6.000000e+00 3.455621e-03 272.17 -2.00 20.00 -2.00 500.00 0.00e+00 2.709732e+00 2.057805e+00 8.006815e-02 -6.000000e+00 2.484745e+00 223.16 -2.00 3.57 -2.00 501.62 0.00e+00 20.085 0.158 489.00 513.00 1 1.0070e+01 1.5711e-01 3.8041e-02 -6.0000e+00 1.8925e-01 1.3030e-01 4.0754e-02 2.0743e-03 -6.0000e+00 5.0175e-02 3.5802e-06 1.6556e-02 7.7933e-03 1.6386e-04 -6.0000e+00 1.0073e-02 -5.4392e-02 1.5770e-04 12 8 8 10 0 0 1.28 15.00 9.57 -0.05439 0.06045 9 1 1 4 0 4000.000 21.98 15.00 18.99 900000 9941 -14506 -2461 -1598 882 -13614 7412 -7285 10037 638 -8630 4560 16350 11153 -2344 2648 -1471 16165 -986 1904 -11666 4901 -14271 7671 8191 -4904 -22870 9264 -1188 1580 -9526 26268 9238 3822 17810 -398 1443 126 1758 18767 122 19824 10701 -7194 -4516 2540 14744 6107 -7366 -6807 1102 -17959 6242 -12270 14944 -375 11782 19587 1172 6981 9151 4345 -10913 2794 775 12307 -8357 10365 -13625 -16205 -3064 5828 -9521 20806 -4376 20916 8299 6409 8758 -12176 381 7246 -12439 4014 22590 14578 -4733 -18531 15333 -18109 12906 -588 35698 7828 21362 -5297 -10478 -23664 25340 2008 -8082 7848 20773 -6828 -2597 6019 8481 -7067 1548 12257 -16700 23923 -684 23032 2838 -7130 -19859 13969 -7048 15064 -4133 27071 680 7005 1464 709 3018 12297 26789 12 8010 -9965 42923 -18876 -19076 21814 1013 -21918 15692 -11968 7517 7683 20271 7277 -15153 9337 3209 -7749 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9.902e-02 9.392526e+03 6.494749e+03 8.098175e+02 -6.000000e+00 6.361078e+03 272.17 -2.00 20.00 -2.00 505.24 0.00e+00 5.331797e-03 2.569241e-03 3.763004e-04 -6.000000e+00 3.412952e-03 272.17 -2.00 20.00 -2.00 499.93 0.00e+00 -1.063136e+00 1.990875e+00 6.793261e-02 -6.000000e+00 2.452348e+00 223.16 -2.00 3.57 -2.00 501.59 0.00e+00 19.505 0.145 489.00 513.00 1 1.0411e+01 1.5134e-01 3.5370e-02 -6.0000e+00 1.8682e-01 1.9816e-01 3.9822e-02 2.3401e-03 -6.0000e+00 4.9463e-02 3.8022e-06 8.0435e-03 7.2395e-03 1.0634e-04 -6.0000e+00 9.9499e-03 -7.1598e-02 1.0454e-03 12 8 8 10 0 0 3.41 15.00 10.43 -0.07160 -0.01580 9 1 1 4 0 4000.000 21.98 15.00 19.00 9937 -9044 6933 -7893 23208 1520 13792 -305 6251 -5892 5714 -2559 3579 -7551 3983 -3623 -7801 -8289 -2516 8035 -7228 5473 -16770 1564 -4178 -8980 1734 -2395 -3102 29287 -5225 19492 -9855 3630 -1380 9574 -12190 4975 189 15304 8080 4527 15669 -7088 18258 -1805 25254 -2590 14110 -16391 11733 -10052 3545 -10529 17756 -11883 -6851 7159 8205 -5093 6644 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