File name: Pandora103s1_Downsview_20180118_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T224909.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180118_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180118T211531.0Z 6592.885776 4 1 36.01 2 82.56 232.25 69.12 218.39 0.00 1 0.00 1 0 15 9.787e-03 9.706e-03 9.119e-03 9.055e-03 1.062467e+03 4.798239e+02 5.398717e+01 -6.000000e+00 4.856086e+02 271.77 -2.00 20.00 -2.00 505.22 0.00e+00 3.853335e-03 2.361707e-04 1.992822e-04 -6.000000e+00 2.610981e-04 271.77 -2.00 20.00 -2.00 500.11 0.00e+00 9.310429e-01 1.772151e-01 3.196985e-02 -6.000000e+00 1.888780e-01 223.53 -2.00 3.57 -2.00 501.74 0.00e+00 7.164 0.007 489.00 513.00 1 9.5541e+00 1.3496e-02 1.1360e-02 -6.0000e+00 1.4369e-02 4.9468e-02 3.5937e-03 6.6994e-04 -6.0000e+00 3.8356e-03 4.5414e-05 1.4997e-03 6.9192e-04 4.9495e-05 -6.0000e+00 7.6316e-04 2.0690e-02 2.0654e-05 12 8 8 10 0 0 -9.39 15.00 1.50 0.02069 0.03109 9 1 1 4 0 4000.000 21.98 15.00 19.08 -2578 -2206 -458 213 328 1885 -491 -49 -616 1271 -471 22 339 925 -1326 -826 31 658 -623 -147 899 858 304 -236 715 -571 1718 410 292 307 -36 -1855 857 -373 626 -163 615 -370 -1137 -643 -1428 731 -1369 596 -787 1048 330 584 572 323 -1269 1283 -1500 -498 91 442 383 1537 787 596 463 1235 1553 -256 -263 -535 1460 -1212 -1828 -328 237 -358 1122 49 1447 -1319 1356 -1184 -1359 -1172 1014 -264 581 -763 -2001 568 -1284 -567 -403 -2310 -292 178 894 1082 450 1183 -717 -9 -895 -448 -198 -426 -381 1795 671 1227 212 900 -807 336 -223 -1010 961 -367 1473 -1 953 -196 849 -340 1591 -571 2790 -2265 790 -947 4 -577 500 -1230 -1636 661 -415 196 868 -780 1072 -492 -1390 -42 4 455 -388 1105 342 -187 -251 25 -832 -801 900000 -2511 -2171 -459 221 348 2006 -546 -54 -691 1378 -508 23 352 939 -1362 -844 32 686 -677 -161 972 927 330 -258 781 -633 1853 445 311 312 -36 -1870 856 -393 679 -179 662 -396 -1210 -673 -1509 763 -1477 640 -867 1139 360 627 604 334 -1287 1234 -1457 -481 90 453 403 1613 830 625 485 1294 1631 -273 -279 -558 1463 -1228 -1845 -321 227 -345 1078 48 1427 -1326 1296 -1132 -1290 -1105 938 -250 547 -729 -1957 547 -1255 -547 -387 -2260 -282 174 886 1080 447 1148 -696 -9 -823 -400 -174 -378 -349 1680 650 1173 201 829 -745 310 -212 -984 935 -366 1451 -1 952 -199 841 -334 1509 -544 2557 -2205 753 -917 4 -555 473 -1191 -1582 611 -379 175 766 -708 984 -467 -1343 -41 4 436 -377 1064 333 -181 -238 23 -745 -715 900000 SO 20180118T211729.0Z 6592.887141 6 1 36.00 2 82.84 232.61 69.33 218.83 0.00 1 0.00 1 0 15 1.139e-02 1.118e-02 1.018e-02 1.011e-02 1.900648e+03 5.536015e+02 1.718056e+02 -6.000000e+00 5.651366e+02 271.77 -2.00 20.00 -2.00 505.22 0.00e+00 4.624298e-03 2.630478e-04 2.500973e-04 -6.000000e+00 3.038297e-04 271.77 -2.00 20.00 -2.00 500.09 0.00e+00 8.692197e-01 1.985743e-01 3.571590e-02 -6.000000e+00 2.197795e-01 223.53 -2.00 3.57 -2.00 501.72 0.00e+00 7.403 0.008 489.00 513.00 1 9.6291e+00 1.5106e-02 1.2250e-02 -6.0000e+00 1.6720e-02 5.4662e-02 4.0225e-03 7.0184e-04 -6.0000e+00 4.4625e-03 4.0431e-05 1.1946e-03 7.6829e-04 6.4843e-05 -6.0000e+00 8.8808e-04 1.8219e-02 4.4679e-05 12 8 8 10 0 0 6.11 15.00 1.14 0.01822 0.02651 9 1 1 4 0 4000.000 22.09 15.00 19.09 -593 -1169 -1317 687 857 -48 488 156 1666 -398 98 551 -85 -1286 1078 -571 -709 592 442 -419 828 -154 -1866 1768 -248 1653 161 977 -1095 -1483 -1449 1279 413 -199 -776 1053 832 1569 682 -2340 474 -1027 -158 -166 885 -358 925 -899 2117 -1276 -420 1057 -980 -1727 -759 -1626 559 704 -185 -677 -1019 1371 394 667 1253 1 1550 -1480 -419 -122 -1085 -364 -1195 -784 -1310 1307 -108 29 -401 1038 -95 3213 -842 42 472 -64 -1152 -1817 2850 -950 441 946 -393 -376 1178 24 196 -802 -278 -179 -2023 -736 -1259 122 189 1190 -939 -2245 -2215 893 380 1922 136 1450 200 1398 -327 267 -278 73 -1546 1525 -526 32 818 1421 621 579 1291 1838 -1537 120 311 -1330 -2136 -3233 2099 -1201 715 -908 1508 -682 963 891 1042 29 1398 -313 -1390 -1375 900000 -569 -1143 -1335 713 909 -53 539 174 1834 -440 105 582 -89 -1336 1084 -583 -731 617 476 -460 895 -168 -2061 1893 -273 1793 177 1057 -1179 -1531 -1453 1250 414 -209 -853 1145 893 1647 713 -2490 492 -1091 -169 -180 962 -396 1006 -981 2210 -1344 -425 1022 -952 -1695 -761 -1708 590 749 -198 -722 -1089 1442 420 709 1314 1 1561 -1511 -419 -120 -1058 -353 -1179 -782 -1331 1287 -105 27 -378 961 -89 2944 -804 40 451 -62 -1124 -1773 2646 -914 421 912 -393 -379 1159 23 188 -754 -253 -158 -1794 -650 -1151 116 183 1132 -894 -2120 -2063 816 357 1815 133 1415 198 1378 -329 269 -278 71 -1508 1418 -496 30 777 1342 592 549 1211 1725 -1482 111 282 -1206 -1935 -3000 1903 -1144 675 -879 1429 -659 920 856 1002 28 1299 -286 -1246 -1227 900000 SO 20180118T211923.0Z 6592.888461 8 1 36.00 2 83.12 232.97 69.54 219.25 0.00 1 0.00 1 0 15 1.247e-02 1.245e-02 1.048e-02 1.040e-02 1.814209e+03 5.681244e+02 1.352539e+02 -6.000000e+00 6.186049e+02 271.77 -2.00 20.00 -2.00 505.22 0.00e+00 3.792684e-03 2.708736e-04 2.051530e-04 -6.000000e+00 3.326025e-04 271.77 -2.00 20.00 -2.00 500.11 0.00e+00 9.428752e-01 2.039726e-01 3.197713e-02 -6.000000e+00 2.406472e-01 223.53 -2.00 3.57 -2.00 501.73 0.00e+00 7.649 0.009 489.00 513.00 1 9.6319e+00 1.5510e-02 1.2029e-02 -6.0000e+00 1.8306e-02 5.1652e-02 4.1328e-03 7.2586e-04 -6.0000e+00 4.8887e-03 3.9222e-05 9.4628e-04 7.9195e-04 5.2627e-05 -6.0000e+00 9.7191e-04 1.9381e-02 3.3758e-06 12 8 8 10 0 0 -8.04 15.00 0.53 0.01938 0.02595 9 1 1 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