File name: Pandora103s1_Downsview_20180121_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T225457.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v2d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180121_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180121T125058.0Z 6595.535394 1 1 36.00 2 89.87 118.19 115.80 74.18 0.00 1 0.00 1 0 15 5.041e-02 4.933e-02 4.536e-02 4.479e-02 5.503214e+02 2.331880e+03 6.659655e+01 -6.000000e+00 2.502538e+03 271.77 -2.00 20.00 -2.00 505.23 0.00e+00 3.433780e-03 1.157453e-03 1.608827e-04 -6.000000e+00 1.344825e-03 271.77 -2.00 20.00 -2.00 500.09 0.00e+00 2.705035e+00 8.749075e-01 3.037164e-02 -6.000000e+00 9.727159e-01 223.64 -2.00 3.57 -2.00 501.71 0.00e+00 20.554 0.169 489.00 513.00 1 9.2235e+00 6.6571e-02 3.7379e-02 -6.0000e+00 7.4008e-02 1.1686e-01 1.7725e-02 2.0869e-03 -6.0000e+00 1.9739e-02 8.6728e-06 3.0630e-04 3.4281e-03 4.2765e-05 -6.0000e+00 3.9310e-03 6.0657e-03 1.5473e-04 12 8 8 10 0 0 0.03 15.00 4.00 0.00607 0.00819 9 1 1 4 0 4000.000 21.79 15.00 18.76 -6146 -9111 6674 1672 779 4878 1691 1650 -632 7125 5092 -769 1168 780 -3822 6538 1331 6164 -1705 4852 394 3168 -6208 -179 4113 5807 -2204 -4851 -1341 2422 -4505 6529 -1349 4430 3383 1277 -3759 -9599 608 -8263 -555 -444 2116 -704 -261 93 981 -242 4444 -2041 2568 -162 4189 1479 -6970 3132 -6853 3865 -5445 978 2495 5978 -3611 -5114 -7073 7547 -1938 2158 -3625 2918 -2109 -6474 3180 -1196 1102 4368 2952 -5439 -1339 123 1766 -3452 4489 -9348 11862 -5474 3641 -1780 8697 10425 929 -563 2208 -8479 -3084 3722 140 -3347 216 11687 -8240 2494 -7745 2352 -829 7302 -7023 -5570 -8700 5665 1056 -6061 -6366 5796 -3038 -3053 1201 6919 9700 -343 8203 4487 7660 1865 607 -3779 8032 7541 8944 -6409 2224 -9079 -348 2946 1856 -6324 4208 3554 -1801 -4665 3445 8515 -7279 4717 1405 2303 8207 368 -8354 -1251 900000 -6137 -9498 6184 1698 819 5021 1835 1814 -709 7304 5213 -823 1208 796 -4035 6240 1351 6117 -1887 5115 432 3380 -7249 -197 4396 6124 -2502 -5622 -1468 2439 -4711 6139 -1394 4513 3627 1409 -4290 -11418 646 -9460 -590 -475 2238 -777 -291 103 1076 -265 4573 -2184 2537 -159 3879 1411 -7442 3152 -7802 3996 -6145 1028 2577 6012 -4007 -5748 -8031 7297 -2011 2118 -3726 2766 -2064 -6618 2986 -1190 1088 4145 2765 -5396 -1264 113 1610 -3343 4035 -9635 10058 -5536 3364 -1724 7576 8932 877 -547 2139 -9204 -3143 3491 133 -3216 194 9156 -7731 2127 -7522 2165 -807 6513 -7057 -5398 -8574 4899 977 -6136 -6582 5393 -3098 -3126 1187 6485 8752 -335 7240 4039 6650 1736 578 -3747 7107 6682 7790 -6526 2073 -9237 -318 2573 1624 -6083 3766 3265 -1763 -4743 3244 7631 -7651 4444 1371 2215 7282 340 -8176 -1139 900000 SO 20180121T125256.0Z 6595.536759 3 1 36.01 2 89.55 118.53 115.47 74.55 0.00 1 0.00 1 0 15 3.059e-02 3.038e-02 3.198e-02 3.169e-02 5.791224e+03 1.940778e+03 6.213104e+02 -6.000000e+00 1.517667e+03 271.77 -2.00 20.00 -2.00 505.27 0.00e+00 1.925184e-03 8.295690e-04 7.570170e-05 -6.000000e+00 8.159818e-04 271.77 -2.00 20.00 -2.00 500.12 0.00e+00 9.014637e-01 6.275859e-01 1.159159e-02 -6.000000e+00 5.903843e-01 223.64 -2.00 3.57 -2.00 501.76 0.00e+00 20.067 0.157 489.00 513.00 1 9.0819e+00 4.7722e-02 3.5619e-02 -6.0000e+00 4.4913e-02 1.3619e-01 1.2634e-02 2.0114e-03 -6.0000e+00 1.1990e-02 1.2385e-05 -3.6532e-03 2.3812e-03 7.2320e-05 -6.0000e+00 2.3849e-03 2.0029e-02 1.9392e-05 12 8 8 10 0 0 8.74 15.00 2.56 0.02003 -0.00531 9 1 1 4 0 4000.000 21.88 15.00 18.78 -2768 -247 -6691 4905 -411 -7 782 1185 2424 -204 2300 582 -1221 1464 -5504 76 1139 -699 3381 -7696 1768 1807 -1802 2513 1603 -3349 1206 -260 2792 -683 -430 517 -2856 4840 843 -392 -2125 614 -299 -1608 -4221 1064 1015 868 1576 1428 715 3216 -677 -139 -4401 -4381 -3532 1850 -6864 5098 496 4016 -2049 1856 5170 -583 5000 3524 282 -1535 1440 -3657 -4687 243 2113 -808 4505 -242 4725 -316 2072 1776 -6817 4242 -3639 -3590 -2636 -750 4110 5284 -1076 4059 2760 1847 2316 778 -1953 2022 1452 100 5905 4763 3000 174 5676 -5656 -1069 -525 -3912 2442 3562 935 900 627 -3252 -4189 5221 -3082 -391 -6852 864 -1039 1688 -448 -2343 490 -2193 2921 -1539 -5605 1643 -2296 508 -940 -4609 161 -1954 1045 -3300 2354 -66 -2094 -2974 3443 -3790 -1234 5123 1440 2313 4141 392 -4178 5904 993 900000 -2666 -233 -6946 4749 -432 -8 846 1297 2629 -225 2420 615 -1293 1483 -5893 77 1149 -733 3524 -9133 1912 1951 -2011 2690 1744 -3844 1319 -287 2945 -715 -432 512 -2958 4819 914 -437 -2387 660 -320 -1721 -4616 1111 1073 930 1701 1552 781 3387 -729 -146 -4656 -4480 -3504 1735 -7175 4941 519 4111 -2223 1924 5163 -619 5064 3622 297 -1624 1449 -3801 -4871 237 1991 -781 4171 -238 4510 -317 1985 1661 -6837 3793 -3508 -3490 -2557 -716 3789 4878 -1058 3780 2586 1741 2178 751 -1979 1993 1418 96 5237 4148 2586 150 4569 -5118 -953 -491 -3949 2341 3336 880 831 581 -3191 -4225 4863 -3138 -389 -7262 857 -1061 1677 -447 -2332 464 -2097 2673 -1490 -5649 1543 -2238 478 -900 -4579 149 -1808 928 -3031 2065 -61 -2019 -2924 3219 -3832 -1219 4777 1399 2233 3912 378 -4084 5073 886 900000 SO 20180121T125450.0Z 6595.538079 5 1 36.01 2 89.25 118.86 115.14 74.91 0.00 1 0.00 1 0 22 2.377e-02 2.352e-02 2.314e-02 2.298e-02 4.150280e+03 1.346436e+03 1.839533e+02 -6.000000e+00 1.180051e+03 271.77 -2.00 20.00 -2.00 505.28 0.00e+00 4.582978e-03 5.999110e-04 2.324666e-04 -6.000000e+00 6.341943e-04 271.77 -2.00 20.00 -2.00 500.23 0.00e+00 1.683697e+00 4.505084e-01 6.765169e-02 -6.000000e+00 4.587531e-01 223.64 -2.00 3.57 -2.00 501.85 0.00e+00 19.460 0.144 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