File name: Pandora103s1_Downsview_20180506_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241031T235355.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180506_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180506T100947.0Z 6700.423461 271 1 40.00 2 89.74 66.99 64.20 177.47 0.00 1 0.00 1 0 22 8.332e-02 8.085e-02 7.729e-02 7.518e-02 8.012883e+03 4.974205e+03 6.487550e+02 -6.000000e+00 4.272439e+03 279.78 -2.00 20.00 -2.00 505.23 0.00e+00 3.323643e-04 2.000800e-03 3.103102e-05 -6.000000e+00 2.266412e-03 279.78 -2.00 20.00 -2.00 499.84 0.00e+00 3.556037e+00 1.503567e+00 4.022799e-02 -6.000000e+00 1.613880e+00 230.05 -2.00 3.57 -2.00 501.50 0.00e+00 20.167 0.160 489.00 513.00 1 9.7140e+00 1.1490e-01 3.6251e-02 -6.0000e+00 1.2303e-01 1.0401e-01 2.9924e-02 2.3041e-03 -6.0000e+00 3.2803e-02 5.2972e-06 2.2763e-03 5.5906e-03 6.8779e-05 -6.0000e+00 6.5000e-03 -1.2345e-02 2.3772e-04 12 8 8 10 0 0 -2.63 15.00 7.57 -0.01234 0.00344 10 1 1 4 0 4000.000 21.98 15.00 19.00 -1861 -203 15298 1034 -850 -8663 11599 -9595 11526 -11409 13159 -6537 -481 -2925 -8655 -5445 5798 7114 10053 -435 -2706 2390 -457 2902 -1457 8434 -5732 178 3719 10174 -1090 12986 -2911 6676 -13348 12680 -5096 1183 -3735 -8655 13180 13341 -2646 7996 -5117 3953 2080 -1973 8009 -14226 9039 -1095 11825 -4384 26504 -11498 6246 -3178 4860 -3710 -5082 -1686 -593 -1807 2417 -1638 -5589 12759 -12813 3034 1587 4379 -12747 11644 887 2524 -2054 23789 8520 -2246 -5716 -1243 -547 -11505 -4810 6442 -9919 -2176 -5396 6572 -1754 -3621 2142 -636 14772 6017 -2678 3442 8656 -6833 -5351 -6696 -10778 -1107 11698 -9520 6872 -1074 4717 -1538 1265 -2346 5723 1734 661 -1068 2880 23 -3773 10399 9614 4595 -1324 2532 -4502 12506 -1513 -128 10394 4948 10309 -6418 -2130 6288 -755 -1760 9277 -1279 12084 -9703 18507 -14823 12697 -8863 11587 -23356 11381 -5060 -173 19649 900000 -1823 -199 13352 1081 -928 -10398 11694 -12043 11786 -14372 12813 -7629 -521 -3191 -9896 -6045 5842 7277 10341 -503 -3188 2683 -527 3242 -1711 9004 -6984 203 4012 9846 -1146 11933 -3179 6937 -17530 13000 -6116 1315 -4291 -10299 12664 12864 -3011 8300 -6098 4322 2299 -2233 8083 -17373 8485 -1099 10273 -4474 20672 -13474 6306 -3539 4981 -4092 -5662 -1830 -639 -1965 2497 -1727 -5991 11262 -14345 2860 1493 4019 -13948 10219 876 2430 -2009 17657 7246 -2105 -5543 -1164 -512 -12023 -4781 5792 -10434 -2109 -5356 5794 -1682 -3584 2041 -621 12106 5198 -2438 2864 6682 -5990 -4586 -5915 -10330 -1024 9913 -9942 6033 -997 4075 -1423 1161 -2260 5138 1623 625 -1031 2709 23 -3815 8990 8192 4017 -1213 2262 -4346 10232 -1420 -118 8629 4356 8567 -6120 -1915 5171 -664 -1596 7795 -1211 10177 -10245 14969 -16647 10988 -9503 10194 -28686 9775 -4946 -158 14753 900000 SO 20180506T101432.0Z 6700.426759 275 1 40.00 2 88.95 67.81 64.17 178.68 0.00 1 0.00 1 0 22 4.188e-02 4.170e-02 4.109e-02 4.047e-02 4.152565e+03 2.483801e+03 3.830712e+02 -6.000000e+00 2.147509e+03 279.78 -2.00 20.00 -2.00 505.23 0.00e+00 2.814626e-03 1.078080e-03 1.624907e-04 -6.000000e+00 1.139264e-03 279.78 -2.00 20.00 -2.00 499.89 0.00e+00 2.420998e+00 8.122158e-01 2.220678e-02 -6.000000e+00 8.113427e-01 230.05 -2.00 3.57 -2.00 501.56 0.00e+00 18.574 0.125 489.00 513.00 1 9.3605e+00 6.2072e-02 3.1644e-02 -6.0000e+00 6.1850e-02 1.2242e-01 1.6348e-02 1.7721e-03 -6.0000e+00 1.6495e-02 1.0037e-05 -2.1859e-03 3.0423e-03 5.5254e-05 -6.0000e+00 3.2676e-03 1.0891e-02 8.4077e-05 12 8 8 10 0 0 -6.92 15.00 2.48 0.01089 -0.00427 10 1 1 4 0 4000.000 21.98 15.00 19.00 -169 -2924 -650 158 1400 4790 -873 -1146 1079 8539 -3670 -2076 -8650 896 -4190 2925 -4017 -3350 -3491 3425 -3627 4515 -582 5421 792 1950 6314 -1895 -863 -4350 1492 -3795 672 -1010 -2637 -6593 4288 -2921 5648 -2501 -3062 720 7846 4554 6331 6839 164 -3491 2296 3522 3764 -2010 -3080 -2255 428 808 -1669 2061 -3308 3404 3366 5240 -2498 2689 -6734 3496 1588 2871 -6005 7951 1878 -4558 -7091 -1415 -3879 -568 2338 6104 3055 -4597 -5914 2115 1943 -2809 1127 -1219 2560 -2143 7840 -2203 3252 5272 4697 575 7415 1904 101 1838 -8281 3525 4153 -3374 -1597 7646 5287 6402 -4880 4288 -2567 3251 -1943 2203 -3073 -6160 -1530 -10221 3854 -2981 7302 318 -2301 -11271 2872 1560 1686 -3832 4983 1782 -4201 4886 -104 -4982 6725 1246 7043 -481 -2905 -1147 -1734 -5205 826 1140 -2054 1398 3434 3852 -5366 7432 -4408 -936 900000 -163 -2924 -656 166 1491 5020 -988 -1320 1218 8852 -4194 -2304 -10085 934 -4538 2949 -4370 -3702 -3993 3734 -4225 4853 -656 5771 889 2174 6717 -2175 -963 -4802 1500 -4004 688 -1092 -3027 -7981 4607 -3311 5808 -2748 -3374 770 7914 4805 6652 7190 184 -3991 2440 3618 3726 -2036 -3087 -2237 424 830 -1808 2177 -3675 3512 3456 5314 -2748 2809 -7657 3537 1601 2809 -6339 7210 1773 -4571 -7349 -1406 -4015 -567 2215 5426 2760 -4442 -5778 1928 1782 -2703 1055 -1180 2387 -2081 6858 -2120 2973 4782 4379 564 6708 1775 93 1626 -7861 2903 3343 -2943 -1410 6479 4761 5720 -4791 3768 -2369 2846 -1826 2026 -3018 -6298 -1500 -10932 3623 -3022 6666 305 -2220 -11630 2550 1415 1546 -3707 4427 1630 -4050 4330 -97 -4753 5594 1080 5720 -425 -2707 -1073 -1649 -5184 781 1075 -2007 1328 3208 3569 -5338 6319 -4083 -831 900000 SO 20180506T101913.0Z 6700.430012 279 1 40.00 2 88.16 68.61 64.16 179.87 0.00 1 0.00 1 0 15 2.747e-02 2.721e-02 2.523e-02 2.489e-02 6.198932e+03 1.589503e+03 4.482372e+02 -6.000000e+00 1.409075e+03 279.78 -2.00 20.00 -2.00 505.24 0.00e+00 3.248047e-03 6.588830e-04 1.885050e-04 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