File name: Pandora103s1_Downsview_20180609_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T002540.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v3d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180609_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180609T094259.0Z 6734.404850 279 1 40.00 2 89.76 57.60 64.70 112.72 0.00 1 0.00 1 0 29 7.190e-02 7.007e-02 6.650e-02 6.558e-02 1.445515e+02 3.461003e+03 1.560255e+02 -6.000000e+00 3.741040e+03 283.42 -2.00 20.00 -2.00 505.34 0.00e+00 2.961489e-03 1.758994e-03 4.289623e-05 -6.000000e+00 1.970071e-03 283.42 -2.00 20.00 -2.00 500.54 0.00e+00 3.851023e+00 1.237811e+00 1.867885e-02 -6.000000e+00 1.383138e+00 232.49 -2.00 3.57 -2.00 502.12 0.00e+00 20.075 0.158 489.00 513.00 1 9.5299e+00 9.4604e-02 3.5823e-02 -6.0000e+00 1.0570e-01 4.3338e-02 2.4502e-02 1.9893e-03 -6.0000e+00 2.7931e-02 6.2085e-06 1.1813e-02 4.9811e-03 2.2775e-05 -6.0000e+00 5.5839e-03 4.1699e-02 -3.0370e-04 12 8 8 10 0 0 12.87 15.00 7.10 0.04170 0.12364 10 1 1 4 0 4000.000 22.09 15.00 19.16 900000 -4413 6495 5144 -8495 2728 3178 -572 -7721 -9857 -11753 9252 4483 10435 -10395 7334 -3687 7882 3067 1234 -2967 12307 5277 9365 -2742 -9738 -691 12021 8541 -1962 11901 5219 2800 -2556 12660 -8317 -4535 947 5247 1943 -367 -11829 -4351 49 9960 -14571 1477 7780 -3459 5158 -822 -4690 4050 4918 106 -7410 -958 10435 -6708 11235 -5002 8285 -2414 5921 2481 -2059 -11779 24249 -2642 -3640 7265 -9319 124 1224 12743 -7026 7227 -3300 -1175 -6239 -4932 1665 280 2885 12589 -2386 -208 15560 -303 132 3423 9455 5321 -1891 7810 -9487 -3069 4811 5952 -11190 -7972 15391 -7613 14961 -4072 -3033 -14005 8483 -359 -5166 -7862 1441 -8750 -316 -1011 1372 3857 -810 216 10607 4270 -7132 1428 7906 6588 5059 -2176 1878 4210 -5774 3843 1402 5501 13474 3151 503 -429 -684 -1024 5675 256 -8235 -6786 2924 -1827 13857 -51 5863 -4378 -6809 -8860 900000 -4201 5800 4842 -9328 2743 3248 -611 -8803 -11263 -13457 8543 4263 9237 -11216 6698 -3811 7518 3157 1301 -3249 11642 5342 9179 -3051 -11593 -751 11442 8132 -1980 10348 4884 2758 -2785 12250 -9831 -5088 993 5210 1979 -384 -13984 -4851 53 9906 -18411 1583 7724 -3763 5017 -818 -4723 3704 4531 106 -8281 -1025 10019 -7570 10577 -5525 8107 -2628 5921 2535 -2155 -13284 19033 -2661 -3634 6454 -9791 121 1195 11217 -7373 6422 -3188 -1105 -6140 -4823 1542 263 2659 10692 -2355 -201 12808 -290 126 3196 8496 5083 -1941 7195 -10189 -3035 4283 5093 -11047 -7600 11903 -7651 12598 -4175 -3034 -15269 7280 -334 -5122 -8188 1399 -9554 -321 -1041 1388 3835 -841 219 9548 4027 -7417 1372 7246 6145 4792 -2215 1830 4021 -6119 3669 1339 4969 11128 2876 483 -429 -696 -1060 5551 265 -9266 -7594 3002 -1969 12693 -52 5459 -4418 -7078 -9607 SO 20180609T094757.0Z 6734.408299 283 1 40.00 2 89.00 58.45 63.88 113.71 0.00 1 0.00 1 0 15 3.673e-02 3.604e-02 2.784e-02 2.762e-02 1.321423e+04 1.862768e+03 7.735599e+02 -6.000000e+00 1.911259e+03 283.42 -2.00 20.00 -2.00 505.49 0.00e+00 3.244330e-03 7.442975e-04 1.807920e-04 -6.000000e+00 1.006027e-03 283.42 -2.00 20.00 -2.00 500.89 0.00e+00 2.021752e+00 5.219791e-01 1.134772e-01 -6.000000e+00 7.039810e-01 232.49 -2.00 3.57 -2.00 502.44 0.00e+00 18.606 0.125 489.00 513.00 1 8.9579e+00 3.9876e-02 3.3063e-02 -6.0000e+00 5.3850e-02 -8.4735e-04 1.0092e-02 3.0113e-03 -6.0000e+00 1.4133e-02 1.5113e-05 3.2248e-04 2.0047e-03 9.1174e-05 -6.0000e+00 2.8460e-03 -1.2372e-02 1.2976e-04 12 8 8 10 0 0 11.11 15.00 3.36 -0.01237 -0.01014 10 1 1 4 0 4000.000 22.09 15.00 19.17 -8538 -3633 1039 -6414 1917 256 2202 1763 -3739 1954 6175 -5205 3188 -8365 -846 -4844 -4949 -115 4505 -977 -145 121 1596 -2132 -1779 4322 -4309 4280 -1636 614 242 1884 -3112 4353 -4502 1403 1397 5333 2821 1815 4125 -1439 -2042 -326 1060 4565 6089 939 -386 6227 4946 -3224 5627 -1643 -2013 -304 -2161 -679 3880 -2645 3841 -6319 940 679 5821 519 -860 -2999 -591 1903 -4998 10839 -4605 5830 1902 1808 -2919 1952 -4603 6182 -1896 39 -3243 5580 -5177 -2587 -1152 332 -616 1881 4467 -40 755 1987 3381 -420 3251 -6179 322 -5578 5595 68 -954 3134 6469 946 -601 -2664 -1895 1437 6254 -3085 1358 3101 -1522 4123 280 590 -3801 6322 -7755 4516 -3736 -1614 -2111 -4847 -2329 9115 -1792 1629 -216 1856 3295 -2973 -5186 -2048 2669 -1258 3246 -1290 3656 3617 443 -948 -2934 868 1565 -5919 -2440 -2733 73 -7710 -3163 895 -6214 1768 244 2116 1729 -3883 1900 5648 -5259 2929 -8464 -788 -4691 -4846 -110 4269 -998 -147 122 1591 -2211 -1858 4284 -4634 4223 -1684 592 226 1733 -3054 4132 -4883 1460 1438 5206 2791 1794 3985 -1481 -2144 -342 1113 4674 6133 984 -404 5989 4663 -3191 5015 -1572 -1987 -308 -2298 -722 3944 -2847 3872 -7089 991 718 5829 539 -887 -3111 -594 1840 -5085 9446 -4712 5473 1890 1796 -2965 1842 -4573 5488 -1817 37 -3197 5073 -5308 -2621 -1151 325 -602 1786 4147 -39 755 1973 3232 -402 2892 -5833 279 -5016 4452 58 -851 2858 6017 944 -605 -2691 -1871 1381 5869 -3230 1375 3099 -1593 4095 293 629 -4256 6325 -8700 4384 -3863 -1648 -2199 -5208 -2452 8599 -1871 1654 -223 1839 3155 -3012 -5362 -2088 2682 -1339 3345 -1414 3866 3851 490 -1068 -3371 958 1690 -6698 -2606 -2914 76 SO 20180609T095247.0Z 6734.411655 287 1 40.00 2 88.26 59.27 63.10 114.69 0.00 1 0.00 1 0 15 1.265e-02 1.260e-02 1.006e-02 1.001e-02 9.064212e+03 6.437832e+02 6.304574e+02 -6.000000e+00 6.585248e+02 283.42 -2.00 20.00 -2.00 505.44 0.00e+00 2.319643e-03 2.697788e-04 1.228698e-04 -6.000000e+00 3.466386e-04 283.42 -2.00 20.00 -2.00 500.79 0.00e+00 2.006119e+00 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