File name: Pandora103s1_Downsview_20180709_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T005719.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180709_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180709 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180709T095152.0Z 6764.411019 286 1 32.01 2 89.77 58.50 58.61 101.38 0.00 1 0.00 1 0 15 3.390e-02 3.414e-02 3.184e-02 3.163e-02 2.771585e+03 1.849872e+03 2.263255e+02 -6.000000e+00 1.783324e+03 286.24 -2.00 20.00 -2.00 505.33 0.00e+00 5.515011e-04 8.540697e-04 2.576559e-05 -6.000000e+00 9.355638e-04 286.24 -2.00 20.00 -2.00 500.43 0.00e+00 2.618283e+00 6.071217e-01 1.668262e-02 -6.000000e+00 6.510709e-01 233.02 -2.00 3.57 -2.00 502.04 0.00e+00 20.009 0.156 489.00 513.00 1 8.8937e+00 4.6490e-02 3.5647e-02 -6.0000e+00 4.9814e-02 7.2698e-02 1.2104e-02 1.9924e-03 -6.0000e+00 1.3140e-02 1.3372e-05 1.7198e-03 2.3878e-03 2.5273e-05 -6.0000e+00 2.6321e-03 -3.2818e-02 2.0295e-04 12 8 8 10 0 0 -4.35 15.00 2.47 -0.03282 -0.02089 8 1 1 4 0 4000.000 22.19 15.00 19.31 900000 -6904 4421 -1193 -1030 5397 1092 154 4658 -4768 -1406 1386 3543 332 -1472 -2284 -1499 1844 -2251 -560 724 451 1662 -4640 -2202 2311 -5512 99 -2402 6698 -5574 3929 -3540 3952 -4717 6494 5009 4269 -8234 1178 -1310 2378 2370 2879 -1590 6487 2074 1763 1697 4754 721 -1036 -4659 -3009 1990 -3990 -2079 3852 4085 3129 1241 774 -1551 2016 620 -2988 -3920 -1621 -3216 1816 332 888 -86 -1606 -3493 -4727 -5688 -1885 -456 1413 4211 5672 2584 748 -301 1405 -1733 2634 1968 3042 3293 3814 -126 -2196 -462 1861 5284 -6660 -974 -3722 967 -7572 1481 169 5817 -542 36 -3634 4555 -717 -872 -3514 -1335 608 72 3234 96 2750 -4222 -3410 5564 -404 1139 5213 -2732 2633 2874 4229 -700 3602 -848 2962 1427 -3011 261 -1014 -4305 1628 241 -8114 1201 -4186 -3822 -3392 3902 2895 4469 -5451 5688 -1113 3989 900000 -6691 3963 -1180 -1048 5256 1135 164 4771 -5298 -1484 1407 3476 330 -1476 -2306 -1517 1851 -2436 -609 777 486 1767 -5252 -2454 2475 -6340 108 -2625 6419 -5814 3732 -3668 3956 -5376 6735 5208 4402 -9457 1219 -1383 2435 2453 3002 -1753 6649 2210 1860 1764 4691 715 -1012 -4613 -2927 1892 -4188 -2204 3901 4121 3160 1271 801 -1651 2073 643 -3154 -4091 -1627 -3248 1721 313 834 -83 -1585 -3574 -4887 -5795 -1803 -425 1285 3730 5007 2366 701 -288 1340 -1707 2480 1859 2844 3081 3594 -127 -2262 -463 1782 4790 -6601 -889 -3402 834 -7163 1325 161 5448 -542 35 -3607 4100 -682 -846 -3564 -1345 607 72 3170 98 2751 -4499 -3542 5200 -393 1079 4794 -2747 2511 2737 3968 -686 3401 -837 2758 1320 -2874 240 -954 -4318 1577 240 -8873 1208 -4447 -4071 -3627 3902 2916 4358 -5671 5162 -1071 3701 SO 20180709T095617.0Z 6764.414086 290 1 32.01 2 89.09 59.26 57.84 102.21 0.00 1 0.00 1 0 22 1.254e-02 1.235e-02 4.620e-03 4.577e-03 1.292591e+04 2.987820e+02 8.565792e+02 -6.000000e+00 6.596803e+02 286.24 -2.00 20.00 -2.00 505.48 0.00e+00 3.908588e-03 1.252174e-04 2.043853e-04 -6.000000e+00 3.460795e-04 286.24 -2.00 20.00 -2.00 501.36 0.00e+00 1.668117e+00 8.499157e-02 9.207383e-02 -6.000000e+00 2.408592e-01 233.02 -2.00 3.57 -2.00 502.78 0.00e+00 18.749 0.128 489.00 513.00 1 7.0293e+00 6.5052e-03 3.3214e-02 -6.0000e+00 1.8428e-02 -4.1900e-02 1.6389e-03 2.7840e-03 -6.0000e+00 4.8618e-03 1.0402e-04 9.5381e-04 3.3162e-04 1.1167e-04 -6.0000e+00 9.7366e-04 -6.6630e-03 3.6319e-05 12 8 8 10 0 0 99.51 15.01 2.64 -0.00666 -0.00005 8 1 1 4 0 4000.000 22.29 15.01 19.31 900000 -3783 -2524 -190 -1214 120 59 987 1019 1768 330 -68 -834 -1728 -1008 -1438 -868 226 1032 459 466 295 830 259 1211 1125 1305 747 684 -1578 -2904 -2461 -770 -284 717 1590 1281 -12 473 -435 -332 252 463 714 953 2114 1227 1247 1357 -70 -723 -1409 -2211 -2216 -1384 -208 1295 1773 2015 375 1254 1824 1295 917 1015 1059 -5 -359 -134 -1409 -585 -1596 -1634 -680 107 -262 -1302 -1828 -1850 -1542 -1332 -607 -1149 -646 -1516 -768 368 -321 56 64 230 1939 1490 1504 916 1285 118 665 -1325 -1414 -3032 -2156 -1684 -353 1369 768 -57 -912 -1281 -1771 3 -541 1569 1011 1372 969 2584 1588 2286 252 1046 -472 7 319 577 270 939 354 635 57 -286 -389 -995 -1315 -640 -1256 -632 451 262 996 254 573 134 978 1079 1380 342 -1264 -1867 -2461 -2072 900000 -3243 -2215 -171 -1142 114 53 890 922 1574 292 -60 -731 -1504 -863 -1237 -751 199 932 427 434 276 773 244 1143 1073 1242 714 645 -1459 -2630 -2218 -694 -265 699 1566 1254 -12 456 -420 -320 245 456 714 967 2145 1257 1264 1357 -70 -702 -1337 -2077 -2082 -1330 -207 1311 1815 2061 388 1286 1879 1356 968 1067 1098 -5 -365 -135 -1420 -576 -1588 -1645 -690 110 -271 -1329 -1830 -1830 -1513 -1302 -595 -1142 -643 -1548 -791 375 -328 57 65 232 1953 1546 1576 944 1275 114 621 -1236 -1295 -2782 -1986 -1605 -354 1425 820 -57 -895 -1243 -1741 3 -550 1582 1033 1401 998 2661 1690 2435 271 1091 -488 8 325 596 281 979 373 664 61 -305 -406 -1025 -1353 -654 -1312 -678 490 288 1110 289 656 155 1131 1250 1589 393 -1439 -2087 -2755 -2347 SO 20180709T100012.1Z 6764.416807 294 1 6.18 2 88.48 59.93 57.16 102.95 0.00 1 0.00 1 0 22 9.235e-03 9.040e-03 1.667e-03 1.661e-03 1.329210e+04 1.079960e+02 8.767545e+02 -6.000000e+00 4.858821e+02 286.24 -2.00 20.00 -2.00 505.42 0.00e+00 4.002713e-03 4.517146e-05 2.231430e-04 -6.000000e+00 2.547957e-04 286.24 -2.00 20.00 -2.00 501.04 0.00e+00 1.374573e+00 3.101724e-02 9.297564e-02 -6.000000e+00 1.768279e-01 233.02 -2.00 3.57 -2.00 502.54 0.00e+00 17.246 0.100 489.00 513.00 1 4.8091e+00 2.3695e-03 2.9534e-02 -6.0000e+00 1.3541e-02 -4.5534e-02 6.0540e-04 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