File name: Pandora103s1_Downsview_20180716_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010700.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180716_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180716T095731.0Z 6771.414942 334 1 32.01 2 89.78 60.00 123.12 25.15 0.00 1 0.00 1 0 50 1.520e-01 1.392e-01 1.320e-01 1.254e-01 6.172266e+03 8.127897e+03 1.619982e+02 -6.000000e+00 8.012880e+03 286.85 -2.00 20.00 -2.00 505.21 0.00e+00 3.624820e-03 3.396168e-03 8.073941e-05 -6.000000e+00 4.202026e-03 286.85 -2.00 20.00 -2.00 499.93 0.00e+00 2.502210e+00 2.463462e+00 1.511583e-01 -6.000000e+00 2.926466e+00 233.04 -2.00 3.57 -2.00 501.57 0.00e+00 19.993 0.156 489.00 513.00 1 1.0259e+01 1.8830e-01 3.7413e-02 -6.0000e+00 2.2385e-01 1.2752e-01 4.8649e-02 3.1520e-03 -6.0000e+00 5.9228e-02 3.1908e-06 2.3962e-02 9.4722e-03 1.3503e-05 -6.0000e+00 1.1822e-02 8.3031e-02 -6.7940e-04 12 8 8 10 0 0 12.29 15.00 8.86 0.08303 0.24924 8 1 1 4 0 4000.000 22.29 15.00 19.41 900000 3798 3091 11484 -6083 16983 -2360 -11107 -14460 23979 -8721 24833 -5317 3941 -8473 6225 -8358 12055 -8337 3113 -5541 23003 10966 -2187 -6595 7956 6197 19935 -11142 9550 4609 7849 20195 -3354 1203 -8663 3394 411 191 -6721 5438 -17228 -8990 -10353 23379 -5466 -12713 30726 -719 11013 -22476 17638 -13585 10360 -8489 28450 4682 40333 -1426 33465 -5337 11531 -21143 6797 13116 7041 -10279 13215 4040 3204 -4457 5999 12381 4071 20267 -3402 16336 -15051 -14199 -17853 -214 12654 9896 -17849 32787 6662 10562 -15906 8120 -9260 -20024 -3273 17203 5601 -11312 9624 -11782 3003 151 -9920 12133 28908 -369 31095 -7047 20968 -24632 -5273 22893 33688 -485 -12623 -13682 14855 2564 13043 17015 16105 -592 24963 19530 658 13767 -17106 -8512 3444 -4760 3175 -9830 15921 35293 -7587 -10285 6513 17607 -24910 29419 15341 23164 -10770 -28109 12839 -2536 24749 716 29396 1023 18541 122 10760 -17715 900000 3753 3207 11288 -7206 16451 -2788 -14273 -18895 21180 -10418 21133 -5946 3990 -9665 6229 -9857 12065 -10296 3430 -6627 20902 11209 -2562 -8081 8441 6647 18310 -13192 8993 4552 7639 18197 -3953 1365 -10658 3662 450 207 -7790 5659 -22559 -11030 -13031 21364 -6555 -16141 25250 -781 10318 -28187 14753 -15380 9611 -9802 23638 4928 30019 -1576 26341 -6142 11339 -28457 6920 12338 6875 -11668 11836 3884 3054 -4569 5613 11055 3995 16900 -3466 13428 -16523 -15363 -19985 -204 10681 8599 -20503 23345 6082 9223 -17774 7176 -9704 -23609 -3355 14563 5203 -12042 8151 -11904 2563 129 -9215 9213 19320 -344 22171 -7256 16244 -28979 -5069 16921 22936 -466 -13830 -15266 12625 2458 11428 14492 13766 -583 18854 15211 607 11323 -19150 -8771 3169 -4729 2906 -10253 12921 23238 -7383 -10161 5441 13414 -29422 20985 12656 17946 -11633 -35955 11119 -2559 19235 698 21308 944 14066 110 8873 -19678 SO 20180716T100147.0Z 6771.417905 338 1 32.01 2 89.11 60.73 122.81 26.29 0.00 1 0.00 1 0 15 5.200e-02 5.127e-02 4.829e-02 4.772e-02 7.197375e+03 3.111394e+03 6.065608e+02 -6.000000e+00 2.741759e+03 286.85 -2.00 20.00 -2.00 505.28 0.00e+00 3.301427e-03 1.293237e-03 1.665692e-04 -6.000000e+00 1.437312e-03 286.85 -2.00 20.00 -2.00 500.25 0.00e+00 2.167636e+00 9.390226e-01 3.701992e-02 -6.000000e+00 1.000263e+00 233.04 -2.00 3.57 -2.00 501.85 0.00e+00 18.765 0.129 489.00 513.00 1 9.4740e+00 7.2024e-02 3.2345e-02 -6.0000e+00 7.6525e-02 9.1436e-02 1.8651e-02 1.9878e-03 -6.0000e+00 2.0224e-02 8.7489e-06 -7.0591e-04 3.5491e-03 7.5550e-05 -6.0000e+00 4.0422e-03 1.3784e-02 -2.0042e-04 12 8 8 10 0 0 31.81 15.00 8.07 0.01378 0.00889 8 1 1 4 0 4000.000 22.29 15.00 19.42 900000 -1075 -7140 6143 542 2466 4776 -2422 4065 -896 108 4603 8338 -4677 6497 -9341 8845 -3508 -2210 -2875 10918 -7443 6964 3239 -861 1011 -2000 503 4958 -5038 -2195 -6300 -836 7543 4251 -1614 5938 919 -4850 1509 -9077 4978 -3460 1684 -907 4254 -1314 -3635 -5778 3027 1609 -5563 3642 2897 4812 -4179 5908 660 9357 874 4230 -1690 7473 -4367 7220 -5361 2077 4141 3639 -9100 -4451 -5588 -5056 -8581 -3090 3286 -6562 2416 1720 9296 -5611 -7541 -8014 2598 -5916 -2414 4350 347 3817 10749 -2931 2336 619 4120 18 8393 -1236 511 -1924 -7323 10244 -5282 3996 -12535 163 3885 2330 -4946 2938 -2921 5043 -1865 1723 -2395 -8616 -2762 2136 -3145 8975 7807 556 3457 -2573 3259 4463 8729 1665 -2121 -3957 10899 3803 4424 4856 3845 -6609 -2312 4465 734 3865 3607 -2128 -1856 -5626 1509 3158 342 -7467 -8542 9505 -3545 5963 900000 -1011 -7328 5783 558 2539 4912 -2720 4307 -988 116 4641 8001 -5000 6150 -10279 8200 -3739 -2402 -3227 10724 -8727 7092 3420 -953 1108 -2251 551 5135 -5529 -2247 -6651 -846 7258 4429 -1823 6179 988 -5442 1571 -10424 5013 -3829 1796 -1007 4530 -1477 -4134 -6607 3117 1629 -5835 3413 2713 4510 -4451 5892 704 9189 925 4309 -1831 7464 -4900 7206 -5964 2105 4035 3525 -9851 -4516 -5698 -5164 -9185 -3190 3203 -6898 2262 1595 7941 -5516 -7602 -8178 2395 -5983 -2391 4042 333 3520 9212 -2872 2195 604 3944 18 7419 -1166 460 -1727 -6758 7808 -4689 3325 -12871 156 3627 2187 -4894 2639 -2773 4514 -1822 1649 -2409 -9245 -2803 2084 -3274 8336 7233 542 3203 -2482 2977 4089 7703 1575 -2084 -3935 9391 3527 4006 4271 3373 -6370 -2149 3995 698 3607 3417 -2155 -1881 -5936 1495 3085 343 -7969 -8958 8108 -3385 5234 SO 20180716T100600.0Z 6771.420833 342 1 32.01 2 88.44 61.45 122.49 27.40 0.00 1 0.00 1 0 50 3.044e-02 3.013e-02 1.999e-02 1.992e-02 6.968979e+03 1.244552e+03 3.976917e+02 -6.000000e+00 1.605164e+03 286.85 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