File name: Pandora103s1_Downsview_20180803_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010752.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180803_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180803T101525.0Z 6789.427373 207 1 32.01 2 89.76 65.71 39.64 182.26 0.00 1 0.00 1 0 26 1.381e-01 1.211e-01 1.245e-01 1.184e-01 1.072457e+04 8.339864e+03 1.113279e+03 -6.000000e+00 7.283996e+03 287.20 -2.00 20.00 -2.00 505.21 0.00e+00 -1.699006e-03 3.243800e-03 1.174603e-04 -6.000000e+00 3.821032e-03 287.20 -2.00 20.00 -2.00 499.83 0.00e+00 -2.205937e+00 2.391339e+00 4.054435e-02 -6.000000e+00 2.661259e+00 232.36 -2.00 3.57 -2.00 501.52 0.00e+00 19.976 0.155 489.00 513.00 1 1.0632e+01 1.8265e-01 3.5687e-02 -6.0000e+00 2.0350e-01 2.3254e-01 4.8379e-02 2.1638e-03 -6.0000e+00 5.3998e-02 3.3734e-06 -1.9320e-03 8.3449e-03 9.1542e-05 -6.0000e+00 1.0757e-02 9.8129e-02 -9.3623e-04 12 8 8 10 0 0 84.37 15.00 3.49 0.09813 0.08473 8 1 1 4 0 4000.000 22.29 15.00 19.23 900000 -470 -537 9348 -7866 5031 -3522 -3314 -5359 23154 -8835 7997 -7258 -13245 -17990 -444 12828 36358 -4648 -10678 11233 4177 -9303 10145 6843 -2567 -15894 4095 3735 -16251 12005 7264 13775 9785 -14506 3859 -2623 -901 -750 20856 6389 2119 19419 -2004 -6666 -2202 9225 16260 7244 -4564 2403 -10087 -410 26155 16993 -11883 5040 -9720 14649 4221 -9679 -2462 5777 8544 -14968 14097 16070 -1860 -2725 16245 -13798 -8335 20178 7772 25303 55661 13963 -9790 -10258 -16981 32643 913 8350 12280 6897 1018 3298 -4372 2798 -5807 -11526 16074 4118 -6124 -7762 19430 7085 3424 19972 23732 -16796 18587 -6584 -10176 -3741 30760 6327 13633 4583 3615 9752 4025 -3228 -12797 9982 17008 -6671 -16730 12295 -20808 -8656 14571 29580 -12575 11135 -10165 3405 -21953 -3700 10607 11447 -8599 5028 -11809 31098 -11489 13511 -4694 -9284 -9826 6703 7612 -12111 -12218 22055 1876 4713 18930 -11062 -1617 34591 900000 -474 -552 9071 -9338 5373 -4163 -3986 -6624 21648 -11040 8355 -8678 -16470 -23040 -477 12146 27909 -5455 -13694 11735 4658 -11791 10622 7408 -3058 -21421 4521 4100 -20945 11255 7004 12548 9475 -18579 4273 -3083 -1024 -839 18641 6488 2238 17478 -2235 -7863 -2507 9409 15339 7333 -5087 2433 -11109 -400 19494 13956 -13366 4992 -11329 13563 4290 -11154 -2648 5781 8352 -18323 12910 14170 -1910 -2790 13733 -15307 -8689 16093 7074 19851 33092 12209 -10460 -10788 -18869 22421 854 7354 10477 6263 997 3189 -4548 2703 -6056 -12698 13652 3985 -6632 -8450 15765 6244 3020 14609 16404 -16794 13229 -6114 -10283 -3779 23115 6022 11914 4268 3349 8584 3802 -3296 -14352 8970 14220 -7015 -19660 11050 -25518 -9233 12107 20717 -13037 9274 -10435 3055 -25106 -3521 8736 9375 -8431 4202 -11400 19744 -10947 10349 -4396 -9192 -9880 5821 6586 -12702 -12879 16733 1721 4164 14271 -10777 -1407 21241 SO 20180803T101945.0Z 6789.430382 211 1 32.01 2 89.05 66.45 39.67 183.92 0.00 1 0.00 1 0 36 8.878e-02 8.019e-02 7.154e-02 6.949e-02 6.442775e+03 4.635205e+03 3.296281e+01 -6.000000e+00 4.685254e+03 287.20 -2.00 20.00 -2.00 505.21 0.00e+00 1.835958e-03 1.888191e-03 1.072433e-04 -6.000000e+00 2.457085e-03 287.20 -2.00 20.00 -2.00 499.85 0.00e+00 2.302724e+00 1.403048e+00 1.018871e-01 -6.000000e+00 1.710184e+00 232.36 -2.00 3.57 -2.00 501.51 0.00e+00 18.635 0.126 489.00 513.00 1 9.8972e+00 1.0741e-01 3.2563e-02 -6.0000e+00 1.3080e-01 1.3081e-01 2.8091e-02 2.3683e-03 -6.0000e+00 3.4661e-02 5.8874e-06 -9.6998e-03 5.1830e-03 2.8790e-05 -6.0000e+00 6.9152e-03 1.4307e-03 -2.8443e-04 12 8 8 10 0 0 0.09 15.00 4.45 0.00143 -0.06585 8 1 1 4 0 4000.000 22.19 15.00 19.23 900000 -1191 -2896 3962 726 -9422 10004 -8371 4760 -6426 -862 8488 -2429 646 6266 -7387 13072 -2569 -3715 -7510 -1523 325 9824 -998 840 -1039 5638 11521 -7471 11474 -7271 -226 -6743 -2032 2585 10534 -1034 7313 -1829 6502 -12761 10102 -6725 8779 -363 676 -1379 -2460 1503 -80 7854 -3266 -5802 1970 -4231 8582 3530 21 -1149 -6328 26755 -3651 3388 -5578 12899 2794 -2007 21704 1249 13130 -2677 -11963 -5672 3209 -8295 6467 13299 -4165 -11316 835 -1689 -2778 -14077 13930 -12767 6565 12030 4757 -8612 846 4212 -235 -8523 3589 4652 7075 -10175 -3327 4084 4086 -4451 414 34571 -4262 5775 -9732 -5871 16160 176 -3112 9440 -9706 -1859 21606 6909 -9078 -1468 5455 3821 17730 9619 -7740 -10 9976 -8034 16677 16 -2679 -10306 3996 -14199 1916 -4102 20179 -2476 -720 -5646 -1633 396 8197 25907 -1377 -3962 2408 6170 -9634 14112 -13748 11272 -11956 166 900000 -1177 -2940 3890 767 -11296 10117 -10338 5247 -7907 -992 8742 -2744 698 6294 -8379 12128 -2802 -4193 -9100 -1771 370 10197 -1149 950 -1207 6158 11826 -9176 11501 -8356 -235 -7435 -2169 2740 10809 -1202 7724 -2078 6718 -15691 9907 -7824 8870 -406 757 -1584 -2842 1647 -87 7779 -3482 -6132 1891 -4295 7907 3551 22 -1258 -7258 22066 -4025 3506 -6328 12224 2901 -2145 18032 1244 11528 -2696 -12956 -5764 3016 -8837 6070 11651 -4212 -11943 772 -1588 -2635 -15025 11388 -13558 5851 10282 4361 -8936 795 3818 -223 -8858 3386 4373 6382 -10544 -3137 3476 3388 -3910 342 20692 -3835 4969 -10142 -5932 13005 162 -2901 7814 -9860 -1781 16675 6190 -9513 -1430 5017 3611 14606 8423 -7852 -9 8212 -7934 13115 15 -2542 -10513 3525 -14997 1730 -3838 14591 -2205 -626 -5207 -1493 362 7028 18955 -1322 -3910 2245 5575 -10164 11773 -14769 9212 -11891 146 SO 20180803T102357.0Z 6789.433299 215 1 32.01 2 88.35 67.17 39.71 185.53 0.00 1 0.00 1 0 22 4.590e-02 4.429e-02 4.200e-02 4.119e-02 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