File name: Pandora103s1_Downsview_20180804_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010708.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180804_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180804T101629.0Z 6790.428113 211 1 32.01 2 89.76 66.09 36.24 163.50 0.00 1 0.00 1 0 22 4.244e-02 4.221e-02 3.426e-02 3.383e-02 7.180929e+03 2.220998e+03 4.120349e+02 -6.000000e+00 2.240656e+03 287.22 -2.00 20.00 -2.00 505.26 0.00e+00 2.010186e-03 9.118250e-04 1.011539e-04 -6.000000e+00 1.174340e-03 287.22 -2.00 20.00 -2.00 500.07 0.00e+00 2.206612e+00 6.662366e-01 6.354357e-02 -6.000000e+00 8.144316e-01 232.32 -2.00 3.57 -2.00 501.71 0.00e+00 19.978 0.155 489.00 513.00 1 8.9750e+00 5.1030e-02 3.5946e-02 -6.0000e+00 6.2336e-02 1.1986e-01 1.3221e-02 2.3478e-03 -6.0000e+00 1.6446e-02 1.2396e-05 3.1865e-03 2.5019e-03 4.5565e-05 -6.0000e+00 3.2968e-03 1.2949e-04 -3.4135e-05 12 8 8 10 0 0 86.50 15.00 3.19 0.00013 0.02223 8 1 1 4 0 4000.000 22.19 15.00 19.28 900000 -407 2262 2150 1749 1296 3704 4735 -7658 482 -8685 -3131 269 5664 -3951 3984 -7885 -220 -3926 1875 -6140 1669 -249 -3087 3628 834 7253 -3807 3207 2046 2247 1069 941 -3282 5244 900 3667 -6246 1114 -3860 4378 2459 4884 4105 2167 3178 1079 6306 838 1570 -1491 1803 -6714 -3932 -6362 2859 -4072 6988 5297 1796 -2864 2254 721 2327 -5466 1273 -202 2844 -1172 -2326 -2188 -4654 -3079 1478 4061 6636 3202 -360 -3949 -8790 -2859 -6525 -6546 -3365 5655 905 992 -1924 290 5948 4548 381 6088 2974 3369 -778 -2822 10423 -8642 52 -6412 -261 -6305 4593 -2271 10385 -9060 4078 -4291 3481 -2909 -2459 -5130 8057 3913 9736 5656 -2109 4072 1379 4707 -2137 -2609 2597 -147 2836 3481 -6891 -186 -4651 1057 3190 2453 -1898 4988 -3589 4648 -2897 -2050 -467 5364 -330 -42 -2489 1346 3562 -4648 -1936 -1525 -5237 585 900000 -392 2191 2178 1829 1385 3956 5080 -9275 533 -10276 -3467 283 5573 -4224 3940 -8834 -235 -4484 2061 -7276 1832 -278 -3548 3941 934 7596 -4418 3409 2103 2230 1071 959 -3625 5570 1009 3946 -7284 1193 -4283 4474 2576 5057 4336 2362 3447 1190 6517 898 1633 -1543 1750 -6936 -3952 -6729 2877 -4506 7014 5392 1875 -3116 2348 767 2433 -6119 1312 -207 2779 -1179 -2328 -2148 -4679 -3075 1433 3902 6192 3011 -342 -3829 -8864 -2718 -6486 -6542 -3271 5102 864 947 -1877 274 5318 4133 365 5636 2852 3156 -737 -2649 8346 -8119 44 -5672 -220 -5833 4036 -2222 9034 -9395 3644 -4090 3090 -2805 -2401 -5197 7225 3659 8618 5264 -2143 3886 1327 4292 -2036 -2463 2351 -138 2592 3166 -6919 -174 -4562 979 2827 2143 -1713 4186 -3320 4092 -2798 -1985 -452 4937 -322 -41 -2505 1306 3367 -4673 -1838 -1404 -4965 531 SO 20180804T102045.0Z 6790.431076 215 1 32.01 2 89.06 66.82 36.02 165.22 0.00 1 0.00 1 0 15 1.922e-02 1.924e-02 1.378e-02 1.372e-02 8.363020e+03 9.013175e+02 5.275497e+02 -6.000000e+00 1.014658e+03 287.22 -2.00 20.00 -2.00 505.35 0.00e+00 2.609680e-03 3.725006e-04 1.217772e-04 -6.000000e+00 5.317862e-04 287.22 -2.00 20.00 -2.00 500.45 0.00e+00 1.815067e+00 2.651275e-01 6.438928e-02 -6.000000e+00 3.687495e-01 232.32 -2.00 3.57 -2.00 502.05 0.00e+00 18.659 0.127 489.00 513.00 1 8.2422e+00 2.0287e-02 3.2213e-02 -6.0000e+00 2.8224e-02 7.1378e-02 5.2335e-03 2.2413e-03 -6.0000e+00 7.4453e-03 3.1657e-05 -1.6000e-04 1.0179e-03 5.9271e-05 -6.0000e+00 1.4928e-03 -9.6907e-03 3.5676e-05 12 8 8 10 0 0 -12.70 15.00 4.07 -0.00969 -0.01080 8 1 1 4 0 4000.000 22.19 15.00 19.28 900000 -6642 -1299 -3790 975 -397 739 1259 238 749 1207 -1052 -668 -3367 -984 -1942 -2333 886 -1302 1035 -1271 5212 -2423 838 1010 1490 -1916 3405 163 313 -4102 747 848 928 3064 2327 1881 1589 264 -452 -433 -720 1193 -2621 2243 -733 2060 1991 175 -2 1104 -4992 -399 -2375 -2222 1438 2791 3547 -69 3728 418 1752 927 3323 55 2096 1022 -89 434 -1967 -2464 -1119 -1427 2238 -2598 1454 -2908 -872 -2413 -1629 -2581 62 -1497 -56 1538 -1566 660 -588 165 -1348 -957 920 4089 -1237 1547 735 2930 656 -219 -1256 -2056 -2059 -1662 -89 779 167 500 -1783 296 -70 -364 199 -882 1124 -548 1423 1341 3438 570 4026 1589 2331 -1165 67 1208 1888 1143 517 -2239 720 158 -1011 -816 -2382 -1825 -2364 162 -2684 -756 -191 1006 148 1093 727 2962 -1680 1224 -1285 -1821 -3865 -1671 900000 -6414 -1228 -3832 973 -409 769 1326 254 788 1239 -1090 -681 -3458 -976 -1940 -2358 887 -1377 1095 -1374 5293 -2646 888 1077 1592 -2108 3548 172 318 -4187 724 832 942 3191 2487 2000 1668 277 -472 -450 -756 1244 -2873 2380 -806 2205 2108 186 -2 1103 -5119 -383 -2315 -2213 1440 2845 3641 -74 3795 437 1819 977 3427 58 2146 1036 -90 430 -1970 -2437 -1089 -1405 2156 -2669 1439 -2936 -840 -2327 -1548 -2469 58 -1438 -53 1457 -1549 640 -574 159 -1311 -929 887 3906 -1257 1506 700 2654 590 -194 -1095 -1777 -1792 -1486 -82 752 164 486 -1739 278 -66 -351 194 -882 1111 -552 1409 1342 3420 584 3937 1558 2219 -1128 64 1165 1814 1108 504 -2229 699 154 -980 -771 -2264 -1715 -2255 155 -2704 -757 -193 1014 151 1110 745 2977 -1760 1230 -1285 -1780 -3815 -1633 SO 20180804T102452.0Z 6790.433935 219 1 32.01 2 88.37 67.53 35.83 166.88 0.00 1 0.00 1 0 36 1.919e-02 1.892e-02 2.939e-03 2.921e-03 1.137023e+04 1.880512e+02 7.547951e+02 -6.000000e+00 1.013094e+03 287.22 -2.00 20.00 -2.00 505.44 0.00e+00 3.509644e-03 8.014677e-05 1.720223e-04 -6.000000e+00 5.309531e-04 287.22 -2.00 20.00 -2.00 501.23 0.00e+00 1.513395e+00 5.442745e-02 8.072221e-02 -6.000000e+00 3.680892e-01 232.32 -2.00 3.57 -2.00 502.67 0.00e+00 16.951 0.095 489.00 513.00 1 6.7849e+00 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