File name: Pandora103s1_Downsview_20180806_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T010702.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180806_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180806 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180806T101839.0Z 6792.429618 276 1 32.01 2 89.76 66.87 40.11 122.74 0.00 1 0.00 1 0 22 4.508e-02 4.414e-02 4.911e-02 4.832e-02 1.156274e+04 3.423654e+03 5.856924e+02 -6.000000e+00 2.380658e+03 287.26 -2.00 20.00 -2.00 505.29 0.00e+00 1.356390e-03 1.303575e-03 7.115958e-05 -6.000000e+00 1.247705e-03 287.26 -2.00 20.00 -2.00 500.00 0.00e+00 2.445658e+00 9.636282e-01 9.228457e-02 -6.000000e+00 8.662898e-01 232.24 -2.00 3.57 -2.00 501.65 0.00e+00 19.977 0.155 489.00 513.00 1 9.3267e+00 7.3593e-02 3.6300e-02 -6.0000e+00 6.6291e-02 1.1172e-01 1.9118e-02 2.7271e-03 -6.0000e+00 1.7514e-02 8.5785e-06 -4.2865e-03 3.5007e-03 4.7093e-05 -6.0000e+00 3.5051e-03 -7.9611e-03 -6.7014e-05 12 8 8 10 0 0 -10.82 15.00 4.26 -0.00796 -0.03769 8 1 1 4 0 4000.000 22.29 15.00 19.43 900000 -3033 -2348 -4110 3506 -6578 1538 4034 -1785 1804 5863 -575 10825 -2777 110 3042 -1207 -4585 -1087 -337 -8521 -3240 -3399 3377 -5697 11660 1695 4837 -165 -1256 1664 4029 2460 499 -1644 2270 -2034 -3066 -1620 568 -1857 -1041 1697 4513 2963 -7316 4852 8813 -4049 1005 5858 -2171 -3626 -663 3551 -2066 -63 1041 2868 1145 1912 -3574 1184 4213 301 -424 -2143 -7682 753 554 1501 3637 -2135 7400 3163 1093 -2368 1721 -3269 -2294 7033 -7693 -7409 812 1481 2094 453 -4440 -2085 -4731 2936 10079 4519 4018 1735 -2205 -3571 4289 5823 -5593 1075 1584 722 1078 7268 -1085 -292 -7093 336 7 2451 8457 -5275 -4113 3627 352 -3438 -956 858 9869 -734 8566 -2597 -6130 10345 -2451 7416 -6091 4466 1885 -861 -7707 -3408 -1589 -1626 -4125 -3587 -11689 480 870 7244 -1826 9872 -6414 3490 -2085 11665 1120 917 -2102 -966 900000 -2972 -2338 -4336 3567 -7539 1663 4344 -2051 1993 6112 -628 10459 -3009 114 3052 -1267 -5055 -1195 -379 -10446 -3765 -3953 3673 -6798 11850 1895 5219 -185 -1380 1697 3951 2467 523 -1844 2529 -2356 -3525 -1812 613 -2034 -1132 1815 4747 3205 -8830 5207 9011 -4619 1071 5788 -2236 -3687 -646 3361 -2145 -67 1108 3009 1212 1993 -3934 1253 4339 321 -450 -2266 -8395 748 545 1436 3375 -2105 6723 3048 1084 -2391 1621 -3166 -2177 6055 -7666 -7425 754 1377 1967 435 -4453 -2025 -4675 2687 8657 4170 3780 1649 -2105 -3330 3576 4649 -4882 861 1262 595 930 6272 -1048 -279 -7148 309 7 2213 7344 -5291 -4099 3354 336 -3420 -945 844 8821 -712 7405 -2441 -5929 8638 -2334 6418 -6022 3963 1711 -807 -7624 -3147 -1423 -1450 -3780 -3358 -12159 449 822 6525 -1809 8771 -6713 3323 -2093 10145 1055 840 -1950 -889 SO 20180806T102258.0Z 6792.432616 280 1 32.01 2 89.05 67.62 39.47 123.96 0.00 1 0.00 1 0 15 2.764e-02 2.711e-02 1.875e-02 1.863e-02 6.041430e+03 1.158240e+03 4.600734e+02 -6.000000e+00 1.459345e+03 287.26 -2.00 20.00 -2.00 505.19 0.00e+00 4.134224e-03 5.007777e-04 1.872610e-04 -6.000000e+00 7.646849e-04 287.26 -2.00 20.00 -2.00 500.27 0.00e+00 1.432954e+00 3.613970e-01 4.118294e-02 -6.000000e+00 5.288930e-01 232.24 -2.00 3.57 -2.00 501.84 0.00e+00 18.629 0.126 489.00 513.00 1 8.5731e+00 2.7659e-02 3.2054e-02 -6.0000e+00 4.0513e-02 1.0721e-01 7.2101e-03 1.9407e-03 -6.0000e+00 1.0630e-02 2.3053e-05 -1.7084e-03 1.3828e-03 6.6323e-05 -6.0000e+00 2.1432e-03 4.3967e-03 -2.9326e-05 12 8 8 10 0 0 91.49 15.00 9.02 0.00440 -0.00745 8 1 1 4 0 4000.000 22.29 15.00 19.44 -5553 -6103 -5070 1973 -1859 1417 -364 290 1344 -91 2190 -333 -4246 -597 -3343 -717 -3927 1376 1783 -874 992 2462 1870 4408 -154 2352 2626 1334 3254 -5929 -2368 -5156 1887 570 339 1148 3914 -2114 1767 -2287 -45 -132 2950 1173 3395 -201 2622 2632 2368 -339 -1293 -631 -2042 -221 -3146 750 -449 1192 2184 1270 3226 5802 -942 2865 -1357 -1282 -3332 871 190 652 -1221 -2860 472 -1381 2494 2982 -3412 -617 -2125 315 591 -858 -3784 -891 -788 -3708 3279 261 2055 -21 -1425 3298 699 3735 742 5095 -59 4275 464 -4233 -4248 -3360 -6058 870 3424 -877 919 -183 -515 -3887 -3498 2524 211 5158 -1227 3525 5593 -2423 5192 765 3576 -2736 5131 -2628 1997 -4244 4988 1092 687 -1565 383 571 4603 -4131 -4316 -4701 -3218 -1287 -84 2686 -1736 669 469 1580 1749 1067 -1858 1143 -4558 -1375 -4027 -5282 -5875 -4983 1889 -1916 1442 -385 311 1430 -98 2239 -344 -4497 -598 -3402 -708 -4035 1368 1826 -942 1049 2558 1956 4500 -166 2495 2773 1421 3355 -6426 -2378 -5289 1826 579 362 1247 4093 -2312 1836 -2445 -47 -139 3051 1254 3607 -223 2833 2814 2499 -361 -1345 -630 -2023 -214 -3211 768 -481 1278 2320 1354 3357 5923 -1038 3048 -1500 -1396 -3629 893 194 654 -1226 -2905 468 -1414 2504 2989 -3568 -610 -2102 303 564 -837 -3831 -879 -785 -3853 3184 260 1995 -21 -1431 3197 713 3751 760 4872 -58 3903 428 -3991 -3928 -3090 -5882 829 3330 -901 917 -181 -460 -3596 -3295 2289 199 4686 -1195 3282 5149 -2448 4867 738 3286 -2623 4473 -2492 1835 -4166 4470 1019 640 -1495 361 525 3971 -3841 -3986 -4392 -3050 -1226 -80 2522 -1720 648 457 1533 1701 1042 -1841 1066 -4363 -1260 -3830 SO 20180806T102711.0Z 6792.435544 284 1 32.01 2 88.34 68.34 38.85 125.18 0.00 1 0.00 1 0 36 2.373e-02 2.363e-02 8.525e-03 8.508e-03 5.285852e+03 5.096302e+02 3.222702e+02 -6.000000e+00 1.252893e+03 287.26 -2.00 20.00 -2.00 505.27 0.00e+00 3.038333e-03 2.311751e-04 1.425777e-04 -6.000000e+00 6.566155e-04 287.26 -2.00 20.00 -2.00 500.66 0.00e+00 1.340724e+00 1.618737e-01 4.981098e-02 -6.000000e+00 4.551432e-01 232.24 -2.00 3.57 -2.00 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