File name: Pandora103s1_Downsview_20180917_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013252.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180917_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180917T110529.1Z 6834.462142 407 1 32.15 2 89.75 87.23 156.45 344.22 0.00 1 0.00 1 0 15 3.593e-02 3.548e-02 2.958e-02 2.921e-02 1.089133e+04 2.007663e+03 5.717241e+02 -6.000000e+00 1.877694e+03 284.63 -2.00 20.00 -2.00 505.27 0.00e+00 2.598822e-03 7.869307e-04 1.256603e-04 -6.000000e+00 9.880931e-04 284.63 -2.00 20.00 -2.00 500.06 0.00e+00 1.969251e+00 5.757230e-01 1.042165e-01 -6.000000e+00 6.881118e-01 228.82 -2.00 3.57 -2.00 501.70 0.00e+00 20.048 0.157 489.00 513.00 1 8.8383e+00 4.4085e-02 3.6768e-02 -6.0000e+00 5.2626e-02 1.1952e-01 1.1363e-02 2.8622e-03 -6.0000e+00 1.3896e-02 1.4152e-05 2.7419e-03 2.1213e-03 5.6999e-05 -6.0000e+00 2.7920e-03 -1.6612e-02 2.0864e-05 12 8 8 10 0 0 -7.15 15.00 4.29 -0.01661 0.00241 8 1 1 4 0 4000.000 22.19 15.00 19.28 900000 -6081 -2124 -4421 1900 -4629 3625 -2630 4206 -2377 3061 -2220 6650 36 2644 -288 -3129 -2305 2086 -3543 2323 714 -353 -3411 5703 2691 -1730 1231 -6254 -1040 -837 -2174 -3045 3684 -2790 1913 2105 5276 -4860 6381 2735 1998 152 1101 -1942 305 2073 2971 591 -1742 1815 -3035 -2245 -493 1804 1536 5410 1685 3844 274 1036 -2971 3695 -3222 702 4404 -1956 3226 -980 985 -2981 2005 1611 2331 -2627 3413 2042 -4015 -7386 3072 -7082 -442 -3669 540 -3446 2670 218 5459 5032 -775 5728 -3308 1683 -6535 -2150 -763 2917 -1516 3342 -4701 -1094 -4954 -1317 1472 10404 2916 3559 -3681 -3457 -3982 270 880 1908 518 872 4552 1746 3200 -4928 2264 -1223 4668 -510 4862 -1362 3306 599 4204 -6734 2134 3589 2659 -4175 1450 -788 -9921 1895 -2458 6892 -790 3056 -6346 5743 -2615 6052 -5174 5692 -4359 -2771 -2832 -2388 900000 -6162 -2137 -4750 1979 -5228 3865 -3025 4537 -2701 3231 -2434 6594 37 2647 -296 -3332 -2491 2234 -4090 2527 789 -393 -3919 6047 2953 -1973 1358 -7296 -1104 -855 -2244 -3211 3777 -3187 2120 2300 5498 -5515 6408 2838 2101 165 1197 -2205 340 2270 3185 638 -1883 1832 -3106 -2233 -481 1765 1568 5477 1790 3993 292 1091 -3273 3841 -3581 746 4443 -2054 3165 -992 963 -2974 1901 1546 2253 -2709 3312 1960 -3976 -7448 2774 -7035 -415 -3572 506 -3401 2513 210 4966 4552 -737 5122 -3268 1617 -6843 -2110 -714 2542 -1334 2737 -4069 -900 -4269 -1135 1307 8889 2717 3264 -3554 -3270 -3797 252 830 1799 497 834 4204 1677 3082 -5152 2173 -1186 4168 -470 4281 -1291 3000 559 3787 -6702 1955 3241 2367 -3884 1266 -700 -9759 1712 -2362 6110 -766 2882 -6583 5324 -2640 5617 -5331 5191 -4261 -2596 -2633 -2237 SO 20180917T110944.0Z 6834.465093 411 1 32.01 2 88.98 87.97 156.64 346.55 0.00 1 0.00 1 0 15 1.247e-02 1.245e-02 1.218e-02 1.209e-02 1.196134e+04 8.330150e+02 8.173406e+02 -6.000000e+00 6.514076e+02 284.63 -2.00 20.00 -2.00 505.34 0.00e+00 3.322783e-03 3.257959e-04 1.821155e-04 -6.000000e+00 3.427899e-04 284.63 -2.00 20.00 -2.00 500.31 0.00e+00 1.978868e+00 2.359855e-01 7.466619e-02 -6.000000e+00 2.387528e-01 228.82 -2.00 3.57 -2.00 501.92 0.00e+00 18.555 0.124 489.00 513.00 1 8.1186e+00 1.8043e-02 3.2238e-02 -6.0000e+00 1.8259e-02 7.7050e-02 4.6471e-03 2.4939e-03 -6.0000e+00 4.8221e-03 3.5388e-05 -2.8290e-04 8.7829e-04 8.5429e-05 -6.0000e+00 9.6871e-04 -1.3519e-02 -6.4974e-06 12 8 8 10 0 0 -11.84 15.00 0.83 -0.01352 -0.01548 8 1 1 4 0 4000.000 22.19 15.00 19.28 900000 -1052 -574 -1495 -463 -490 -1028 -1319 400 1469 243 1156 -1774 -403 874 -2703 -145 -645 2023 441 -65 -569 -491 3010 1803 -672 -1242 -1883 308 -875 -1496 448 -1315 1171 932 322 -559 -1509 1669 294 918 1096 -37 551 451 1281 3145 2420 1082 656 -1935 -1576 299 -130 -304 -2346 -528 1148 1117 541 299 1718 1358 -717 518 -888 -888 1486 -537 1104 -2990 -271 -573 1038 2027 243 235 -397 -2191 -860 -1343 252 294 -3462 -1005 1095 -464 -1933 438 -463 147 385 -306 2234 2379 1577 1165 324 1409 -2261 -2822 -846 -1967 1497 -899 1433 180 883 -627 -397 -129 968 13 -729 -1119 -917 1453 1383 553 348 1076 1139 -396 980 261 255 1942 -768 618 -428 322 -1184 -243 244 -841 -929 -312 -305 -619 80 665 1497 -246 175 -134 -873 1512 -226 -2321 -1823 -1164 900000 -977 -546 -1498 -475 -512 -1104 -1445 433 1561 256 1190 -1855 -409 864 -2758 -146 -662 2090 475 -70 -617 -532 3154 1926 -742 -1373 -2087 331 -913 -1508 440 -1328 1193 997 354 -615 -1648 1746 308 952 1141 -39 592 492 1398 3370 2584 1153 689 -2020 -1586 289 -126 -300 -2455 -560 1219 1187 575 316 1802 1440 -776 552 -946 -927 1489 -543 1085 -2999 -264 -563 1017 2001 245 232 -383 -2118 -813 -1270 236 278 -3391 -973 1052 -453 -1905 417 -442 140 368 -301 2168 2265 1462 1047 284 1191 -1937 -2386 -704 -1707 1327 -860 1369 173 831 -587 -370 -123 927 13 -720 -1112 -909 1423 1380 561 349 1050 1084 -375 916 249 245 1838 -747 590 -414 309 -1134 -225 223 -773 -863 -296 -296 -609 79 663 1489 -250 178 -137 -894 1495 -221 -2257 -1745 -1117 SO 20180917T111352.0Z 6834.467963 415 1 32.01 2 88.24 88.68 156.79 348.85 0.00 1 0.00 1 0 29 7.132e-03 6.984e-03 2.859e-03 2.847e-03 1.698016e+04 2.002382e+02 1.128751e+03 -6.000000e+00 3.726601e+02 284.63 -2.00 20.00 -2.00 505.42 0.00e+00 3.676177e-03 7.701268e-05 2.060035e-04 -6.000000e+00 1.961180e-04 284.63 -2.00 20.00 -2.00 500.70 0.00e+00 1.462240e+00 5.441911e-02 1.050664e-01 -6.000000e+00 1.365043e-01 228.82 -2.00 3.57 -2.00 502.25 0.00e+00 16.642 0.090 489.00 513.00 1 6.8159e+00 4.1575e-03 2.8395e-02 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