File name: Pandora103s1_Downsview_20180928_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015822.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180928_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180928T111804.0Z 6845.470880 283 1 32.08 2 89.74 93.16 56.19 251.36 0.00 1 0.00 1 0 15 8.394e-02 8.128e-02 3.024e-02 2.969e-02 9.590866e+03 1.965588e+03 1.021707e+03 -6.000000e+00 4.361414e+03 283.25 -2.00 20.00 -2.00 505.30 0.00e+00 2.042790e-03 7.989200e-04 1.965063e-04 -6.000000e+00 2.302981e-03 283.25 -2.00 20.00 -2.00 500.22 0.00e+00 7.012278e-01 5.826353e-01 2.820479e-02 -6.000000e+00 1.616108e+00 227.50 -2.00 3.57 -2.00 501.85 0.00e+00 20.084 0.158 489.00 513.00 1 9.1774e+00 4.4372e-02 3.6107e-02 -6.0000e+00 1.2341e-01 1.2323e-01 1.1725e-02 2.0651e-03 -6.0000e+00 3.2824e-02 1.1054e-05 -3.8878e-04 2.1957e-03 9.1967e-05 -6.0000e+00 6.5494e-03 4.8592e-02 -6.9359e-05 12 9 9 12 4 4 99.95 36.26 8.44 0.04859 0.04589 9 2 1 4 0 3563.410 42.30 36.26 39.12 10556 -8100 75 8351 4861 5885 13437 -16801 6230 27995 -2400 -1474 6614 58 2162 -11337 -1761 -6118 -7223 -7945 10106 -9035 4881 4030 -5396 -7061 7322 -4613 -5825 4268 -802 5081 3671 -4223 8900 3142 9984 7927 9015 -7432 -6468 13571 -6646 14011 10959 -3091 1063 4668 -7011 -8077 -11224 -2519 -5537 -6340 -5729 -8372 5135 4312 13333 -870 4605 4947 3174 -1915 -4546 3561 -10945 -4340 3242 8893 932 4377 12805 -142 1199 -978 7727 15056 -7168 14810 2718 -1295 415 -4078 5620 2768 -11166 -52 2614 4326 -17437 628 -983 17123 784 2149 19133 1302 -4728 3269 -19306 -882 13910 456 14211 6459 5497 7639 -15526 2743 3688 13905 12713 -3919 -5438 -605 3129 -16178 315 -7672 -7581 919 4391 -1851 -7217 7799 3065 2959 -4475 2963 4232 -9398 -1701 -7632 3375 -1258 -2214 13323 -1006 24625 6043 -8090 -5677 -5895 282 754 6398 15137 -9430 12607 900000 8842 -8249 73 7844 4842 5909 12822 -21718 6447 23126 -2606 -1568 6406 59 2130 -12732 -1823 -6783 -8367 -9399 10007 -10763 5076 4236 -6266 -8350 7500 -5275 -6583 4179 -803 4815 3591 -4654 8994 3379 9904 7904 8777 -8386 -7234 12604 -7594 13294 10846 -3516 1155 4835 -7997 -9090 -12578 -2519 -5603 -6499 -6025 -9395 5191 4429 12519 -929 4658 5028 3301 -2090 -5047 3592 -12442 -4562 3140 8023 895 4075 11106 -142 1201 -993 7024 12448 -7270 12068 2490 -1245 394 -4074 5191 2655 -12239 -50 2472 4014 -20044 615 -999 14612 764 2000 14633 1148 -4319 2702 -19651 -764 10875 430 12215 6016 5102 6803 -17037 2545 3462 12005 11193 -4067 -5723 -609 3080 -19453 322 -8315 -8022 874 3989 -1805 -7484 6997 2883 2777 -4485 2779 3897 -9617 -1586 -7475 2963 -1176 -2151 11317 -992 19220 5685 -8752 -6030 -6296 283 750 5904 12452 -9602 10347 900000 SO 20180928T112232.0Z 6845.473982 287 1 32.05 2 88.94 93.94 56.92 252.28 0.00 1 0.00 1 0 29 2.354e-02 2.346e-02 9.548e-03 9.503e-03 6.500567e+03 5.912334e+02 4.701657e+02 -6.000000e+00 1.223105e+03 283.25 -2.00 20.00 -2.00 505.42 0.00e+00 4.179495e-03 2.568702e-04 1.940944e-04 -6.000000e+00 6.458524e-04 283.25 -2.00 20.00 -2.00 500.71 0.00e+00 3.025603e+00 1.806665e-01 5.316120e-02 -6.000000e+00 4.528972e-01 227.50 -2.00 3.57 -2.00 502.27 0.00e+00 18.486 0.123 489.00 513.00 1 8.0102e+00 1.3814e-02 3.1791e-02 -6.0000e+00 3.4592e-02 6.9859e-03 3.5491e-03 2.0549e-03 -6.0000e+00 9.1904e-03 3.6787e-05 5.2005e-03 7.1738e-04 7.1230e-05 -6.0000e+00 1.8368e-03 1.2166e-02 2.1233e-04 12 9 9 12 4 4 99.98 36.30 5.33 0.01217 0.04824 9 2 1 4 0 3560.560 42.43 36.30 39.16 -2897 -3899 -2460 -756 -7432 1799 -83 1810 -95 4258 -1901 769 2390 -4478 -2036 503 1137 -1927 -882 -1413 30 1771 375 2773 -696 1163 940 1337 -858 -657 997 27 -408 -61 2829 1006 2530 -1560 691 3008 -682 -2850 -1863 280 1116 373 2481 -594 -1442 -1011 5464 -6218 -291 668 596 676 1950 4181 37 1177 1675 -168 911 5496 -1349 699 -1134 -5508 -124 1185 1479 936 1489 760 -2883 -800 116 -513 -2955 1148 3959 2015 -3439 761 -1217 982 -175 -1824 3901 170 2471 -1319 671 1415 4242 -2531 -556 1253 -2157 1178 -3944 1435 1928 159 3420 1024 3289 -2527 -4549 -1258 2331 1244 -3053 -328 -2271 4774 -510 1223 -2549 1434 -2326 1542 -760 905 -3689 -894 2350 -1046 1822 1963 1450 -2721 -2719 -2186 -338 2922 -1072 3416 -1734 5368 1007 1342 -1586 238 592 -1162 -1295 1734 -5546 -3401 900000 -2556 -3558 -2307 -726 -7753 1758 -85 1818 -97 4087 -1902 743 2238 -4413 -1953 474 1081 -1945 -907 -1468 31 1786 383 2792 -731 1202 971 1365 -867 -635 936 26 -403 -62 2921 1053 2574 -1629 698 2960 -699 -3015 -1983 296 1187 400 2592 -630 -1517 -1031 5080 -6297 -277 639 592 695 2019 4255 39 1220 1734 -178 962 5542 -1433 716 -1160 -5799 -123 1140 1406 901 1441 754 -2982 -799 112 -489 -2861 1065 3595 1878 -3381 725 -1196 950 -170 -1791 3612 163 2341 -1322 673 1401 4000 -2480 -521 1124 -1951 1011 -3545 1253 1751 154 3279 997 3086 -2459 -4494 -1228 2251 1233 -3191 -336 -2380 4722 -537 1275 -2723 1451 -2392 1504 -758 904 -3870 -916 2343 -1073 1822 1974 1447 -2758 -2723 -2163 -330 2840 -1111 3440 -1856 5441 1067 1425 -1742 258 640 -1265 -1378 1743 -5876 -3559 900000 SO 20180928T112634.4Z 6845.476787 291 1 10.83 2 88.21 94.64 57.59 253.11 0.00 1 0.00 1 0 29 1.208e-02 1.197e-02 4.021e-03 4.009e-03 1.213264e+04 2.595764e+02 8.204864e+02 -6.000000e+00 6.279812e+02 283.25 -2.00 20.00 -2.00 505.40 0.00e+00 3.862823e-03 1.083682e-04 2.086398e-04 -6.000000e+00 3.316142e-04 283.25 -2.00 20.00 -2.00 500.89 0.00e+00 1.526607e+00 7.554732e-02 8.513504e-02 -6.000000e+00 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