File name: Pandora103s1_Downsview_20180929_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015708.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180929_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180929 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180929T111905.0Z 6846.471586 276 1 32.01 2 89.77 93.68 45.39 243.62 0.00 1 0.00 1 0 22 6.550e-02 6.443e-02 2.763e-02 2.721e-02 1.254491e+04 1.887669e+03 4.964086e+02 -6.000000e+00 3.402753e+03 283.12 -2.00 20.00 -2.00 505.35 0.00e+00 3.284355e-03 7.287009e-04 1.777405e-04 -6.000000e+00 1.796322e-03 283.12 -2.00 20.00 -2.00 500.31 0.00e+00 2.298296e+00 5.323383e-01 1.470176e-01 -6.000000e+00 1.259157e+00 227.38 -2.00 3.57 -2.00 501.92 0.00e+00 20.125 0.159 489.00 513.00 1 8.7188e+00 4.0601e-02 3.7951e-02 -6.0000e+00 9.6183e-02 7.3502e-02 1.0457e-02 3.3479e-03 -6.0000e+00 2.5531e-02 1.5141e-05 1.5075e-03 1.9994e-03 6.8871e-05 -6.0000e+00 5.1097e-03 9.5496e-03 2.8023e-04 12 9 9 12 4 4 -5.66 33.93 11.11 0.00955 0.02001 8 1 1 4 0 4000.000 40.17 33.93 37.01 -4621 -1066 -7011 -8277 -359 849 3331 11168 6314 -6785 -8879 17883 -56 155 -7910 1661 -2988 11591 -743 -1381 653 -2827 -6566 -9126 6708 1498 1971 3608 2245 7974 -7369 4771 10030 10880 5885 -2390 6065 -7363 6540 -10789 -5967 -1751 406 -3904 1524 8570 3895 -2470 1166 6695 7557 2364 -1833 3732 -2571 6890 -7279 -5441 -705 3623 563 -1565 -893 -5837 3661 4015 -166 17953 -8388 -254 251 620 -8765 4050 -9226 10926 9406 1616 262 5924 -5244 -1200 4943 10596 6238 3280 -3681 -10371 7817 -12043 11054 6134 -676 -6315 -5740 -1175 251 -7069 3090 6402 4358 3659 9023 -2770 13999 -6808 -1339 9214 -2055 -1235 2921 -7645 -1208 6558 -7839 16426 -9584 7552 6925 2390 -4578 -71 4678 3404 -757 423 -8795 689 2673 -3227 7372 -690 1565 -581 -1488 -5120 -16728 10897 1672 9694 8134 -4891 3620 -915 -1862 -3085 8322 -11471 2650 1889 900000 -4383 -997 -7233 -9011 -370 882 3455 10840 6406 -7680 -10070 15465 -56 155 -8455 1624 -3099 10746 -801 -1512 698 -3133 -7540 -10803 6875 1618 2110 3777 2312 7419 -7803 4518 9240 10423 6126 -2696 6208 -8467 6487 -12555 -6653 -1893 436 -4436 1663 8752 4134 -2749 1232 6531 7055 2259 -1801 3513 -2668 6772 -8391 -6192 -763 3733 598 -1713 -974 -6668 3773 4045 -171 15269 -9122 -251 244 602 -9431 3915 -10253 9844 8359 1516 246 5238 -5177 -1149 4469 9142 5703 3106 -3713 -11059 6915 -12886 9507 5639 -676 -6615 -5786 -1091 222 -6519 2526 4959 3427 2962 7282 -2664 11844 -7069 -1301 7918 -1953 -1182 2745 -8065 -1205 6080 -8355 13912 -10652 7211 6619 2340 -4680 -68 4234 3163 -740 409 -9338 665 2524 -3248 6617 -652 1429 -539 -1397 -5107 -19195 9679 1646 8964 7693 -5278 3615 -957 -1963 -3262 7703 -12507 2475 1784 900000 SO 20180929T112316.0Z 6846.474491 280 1 32.01 2 89.02 94.40 46.05 244.64 0.00 1 0.00 1 0 29 1.853e-02 1.841e-02 7.214e-03 7.185e-03 1.106739e+04 4.694622e+02 7.357231e+02 -6.000000e+00 9.623118e+02 283.12 -2.00 20.00 -2.00 505.39 0.00e+00 2.850124e-03 1.934028e-04 1.475364e-04 -6.000000e+00 5.082352e-04 283.12 -2.00 20.00 -2.00 500.73 0.00e+00 8.582087e-01 1.366662e-01 7.590268e-02 -6.000000e+00 3.567203e-01 227.37 -2.00 3.57 -2.00 502.28 0.00e+00 18.674 0.127 489.00 513.00 1 7.6464e+00 1.0415e-02 3.2483e-02 -6.0000e+00 2.7240e-02 4.4358e-02 2.7108e-03 2.4923e-03 -6.0000e+00 7.2446e-03 6.1203e-05 -1.3913e-03 5.2907e-04 9.0869e-05 -6.0000e+00 1.4458e-03 4.7983e-02 -6.2751e-05 12 9 9 12 4 4 61.55 33.93 1.91 0.04798 0.03833 8 1 1 4 0 4000.000 40.17 33.93 37.00 -1737 -277 634 -1332 452 3504 -2520 1245 838 1878 -310 5453 181 -2514 -585 -518 -3560 -5 -1109 1125 473 1020 1458 604 2121 -183 760 2841 73 -1341 -582 -2836 -1015 2625 -1265 2922 1928 -441 -2652 -3376 -2356 185 511 -1187 608 1123 715 920 3165 -2730 -4014 -1199 -304 -2409 -2578 709 460 1209 714 845 2236 -351 -667 -1476 824 4275 -305 3282 -372 -723 1517 -2941 1141 422 38 199 541 -3690 -1312 -1949 -5250 195 -469 -1532 531 1111 197 2664 -271 -397 2647 1221 -1881 1816 1054 -749 -734 1469 -1594 -277 -685 -4160 -1280 2428 783 1408 -153 -515 -2152 1379 -3435 -216 -2174 -872 67 1587 853 2092 537 820 -241 -200 -1348 2974 363 3575 1135 -2549 3250 2312 845 -1574 -2097 1024 -731 -891 1770 -1614 -116 2858 -257 -2589 -2107 1052 881 -280 2340 -1163 209 -613 900000 -1515 -242 568 -1269 435 3337 -2595 1254 848 1858 -307 5068 175 -2441 -553 -491 -3505 -5 -1130 1141 482 1035 1473 617 2157 -191 783 2862 74 -1319 -553 -2757 -988 2573 -1339 3003 1974 -456 -2764 -3508 -2429 188 524 -1256 641 1185 755 958 3185 -2841 -4095 -1158 -287 -2327 -2571 714 476 1256 744 874 2281 -370 -710 -1584 860 4255 -311 3191 -371 -714 1446 -2929 1106 419 38 200 529 -3668 -1263 -1876 -5213 186 -452 -1501 518 1090 195 2561 -266 -389 2528 1200 -1943 1817 1037 -725 -689 1311 -1434 -241 -592 -3773 -1175 2282 780 1406 -153 -509 -2132 1334 -3548 -220 -2274 -906 69 1617 888 2188 570 854 -248 -201 -1352 2894 367 3507 1143 -2653 3189 2301 849 -1580 -2078 980 -710 -882 1760 -1683 -121 2933 -274 -2832 -2307 1123 942 -301 2413 -1206 209 -617 900000 SO 20180929T112659.7Z 6846.477080 284 1 7.40 2 88.35 95.05 46.64 245.54 0.00 1 0.00 1 0 22 8.618e-03 8.490e-03 3.129e-04 3.121e-04 1.080636e+04 1.969321e+01 7.447115e+02 -6.000000e+00 4.475656e+02 283.12 -2.00 20.00 -2.00 505.39 0.00e+00 4.025041e-03 8.429252e-06 2.195230e-04 -6.000000e+00 2.363940e-04 283.12 -2.00 20.00 -2.00 500.92 0.00e+00 1.407291e+00 5.871011e-03 7.699830e-02 -6.000000e+00 1.658167e-01 227.37 -2.00 3.57 -2.00 502.44 0.00e+00 16.963 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