File name: Pandora103s1_Downsview_20181010_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015644.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20181010_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181010T113218.4Z 6857.480768 441 1 32.75 2 89.74 99.58 104.59 88.31 0.00 1 0.00 1 0 29 4.708e-02 4.619e-02 1.791e-02 1.769e-02 2.888641e+04 1.376150e+03 1.707694e+03 -6.000000e+00 2.432263e+03 281.74 -2.00 20.00 -2.00 505.52 0.00e+00 3.921367e-03 4.755865e-04 2.415403e-04 -6.000000e+00 1.286721e-03 281.74 -2.00 20.00 -2.00 500.80 0.00e+00 1.412701e+00 3.389936e-01 1.947022e-01 -6.000000e+00 9.040830e-01 226.05 -2.00 3.57 -2.00 502.34 0.00e+00 20.131 0.159 489.00 513.00 1 8.4822e+00 2.5822e-02 3.9824e-02 -6.0000e+00 6.9037e-02 5.9570e-03 6.5357e-03 5.0263e-03 -6.0000e+00 1.8324e-02 1.9817e-05 -4.5417e-03 1.1277e-03 1.5194e-04 -6.0000e+00 3.6721e-03 1.2259e-02 2.7276e-04 12 9 9 12 4 4 99.21 37.12 7.15 0.01226 -0.01924 10 2 1 4 0 3274.780 43.19 37.12 40.05 -2075 -8518 -6884 -2649 197 -1421 10690 -6903 1453 10066 -1948 3129 432 -4618 -3326 6152 1076 2533 -11009 -3994 -4238 3189 3094 1194 -3795 10592 -961 12702 -7334 -76 -419 1726 -8078 4124 2869 5089 -6079 824 3841 4591 4361 -974 4358 -193 222 7697 1235 811 -1786 -2028 -959 -4809 -6767 2207 344 2062 3112 -497 -3664 1216 8940 1152 1641 5549 2615 -807 245 1217 50 -7118 -1269 -5301 1518 -3996 -1875 669 1608 2946 -4266 3056 -3365 5592 -6299 1757 281 13540 -302 -2523 1563 3403 1616 5398 1051 1708 -3820 1515 252 989 7156 -5228 6420 -5045 -3992 1848 1404 -8697 4029 2909 1655 -3248 6584 -7064 9900 -5562 5490 6035 879 -2708 -3841 -69 2126 -3931 689 -2865 2266 3462 5134 -1889 -5255 -866 153 5984 -6881 6403 -5269 9228 6935 -5174 -7514 -5494 5002 3699 -4234 -81 -2307 2252 1804 -2168 216 -48 900000 -1768 -7833 -6458 -2496 186 -1391 9534 -7400 1441 9080 -1934 2927 409 -4520 -3189 5388 1000 2381 -12193 -4214 -4475 3141 3052 1205 -4062 9941 -1006 11632 -7988 -74 -397 1605 -8393 3975 2927 5145 -6760 847 3792 4459 4252 -1010 4358 -205 239 7754 1322 862 -1919 -2141 -971 -4904 -6917 2077 340 2088 3211 -538 -4080 1285 8762 1228 1755 5721 2757 -866 255 1236 51 -7661 -1272 -5532 1498 -4225 -1975 685 1590 2801 -4285 2832 -3297 5055 -6421 1672 277 11887 -302 -2548 1490 3147 1525 4993 1034 1655 -3727 1322 210 788 5311 -4305 4670 -4178 -3453 1638 1338 -9419 3872 2785 1582 -3285 6206 -7685 9134 -5915 5217 5711 897 -2966 -4323 -74 2168 -4095 669 -2894 2218 3374 4961 -1960 -5601 -890 156 5574 -7139 5879 -5447 8499 6729 -5697 -8550 -6274 5263 3986 -4952 -90 -2631 2445 1943 -2380 229 -50 900000 SO 20181010T113635.1Z 6857.483740 445 1 32.21 2 88.98 100.33 103.86 89.04 0.00 1 0.00 1 0 22 1.174e-02 1.153e-02 3.412e-03 3.387e-03 2.743554e+04 2.556162e+02 1.804148e+03 -6.000000e+00 6.061677e+02 281.74 -2.00 20.00 -2.00 505.49 0.00e+00 4.891928e-03 9.120376e-05 2.873276e-04 -6.000000e+00 3.206902e-04 281.74 -2.00 20.00 -2.00 500.85 0.00e+00 1.621888e+00 6.456061e-02 1.569146e-01 -6.000000e+00 2.253959e-01 226.05 -2.00 3.57 -2.00 502.38 0.00e+00 18.630 0.126 489.00 513.00 1 6.8481e+00 4.9203e-03 3.4932e-02 -6.0000e+00 1.7210e-02 -1.6902e-02 1.2476e-03 4.4247e-03 -6.0000e+00 4.5707e-03 1.2230e-04 4.0802e-04 2.1823e-04 1.7966e-04 -6.0000e+00 9.1535e-04 7.6375e-02 -1.4368e-04 12 9 9 12 4 4 81.80 37.11 2.02 0.07638 0.07921 10 2 1 4 0 3220.020 43.32 37.11 40.07 -2040 -1304 -1739 193 663 1276 900 -471 965 586 2264 -651 768 -1157 -401 -159 1909 -932 1810 348 67 352 1099 818 871 1564 1192 -1015 -760 -2393 -2180 -1711 -617 19 1498 618 -1992 -336 606 -94 -1458 -614 -49 1114 1876 1056 -208 411 -315 399 -891 -1158 -1880 416 -1235 -663 1200 547 451 311 1405 624 1237 146 1643 -762 -601 342 905 -2383 -471 -1211 -1729 -1883 435 864 -687 -992 -1931 -1312 -409 905 691 1641 -51 924 -1599 -821 -663 -435 -834 1068 599 1058 1086 640 -1 409 31 -1366 -1711 -3623 -2224 -600 391 2082 1163 -364 -827 -1977 -251 1011 -646 655 1775 986 1083 1427 1365 -385 -1582 -109 -330 338 2703 2068 489 -946 244 -109 380 -1643 -150 -289 -1427 -232 -607 827 345 1123 20 -654 188 780 738 855 774 -359 -2447 -566 900000 -1752 -1135 -1575 179 625 1218 880 -470 950 570 2138 -624 718 -1086 -372 -148 1766 -907 1769 347 67 351 1091 820 881 1578 1205 -1040 -759 -2330 -2083 -1639 -598 19 1537 640 -2084 -343 608 -94 -1490 -630 -51 1160 1965 1119 -222 432 -329 405 -889 -1133 -1831 402 -1249 -691 1258 580 478 328 1473 664 1318 157 1730 -806 -625 349 912 -2431 -468 -1217 -1762 -1952 447 875 -688 -975 -1896 -1270 -392 863 663 1577 -50 916 -1610 -811 -643 -418 -810 1039 593 1027 1008 566 -1 337 25 -1113 -1392 -3072 -1969 -562 382 2039 1144 -357 -809 -1984 -254 1019 -659 658 1759 989 1117 1509 1453 -409 -1652 -109 -326 336 2670 2065 499 -976 248 -112 385 -1652 -148 -287 -1440 -237 -637 864 366 1209 22 -730 209 863 812 935 835 -384 -2636 -603 900000 SO 20181010T114042.9Z 6857.486608 449 1 33.86 2 88.25 101.05 103.15 89.74 0.00 1 0.00 1 0 22 7.995e-03 7.784e-03 1.678e-03 1.670e-03 2.623949e+04 1.241544e+02 1.768888e+03 -6.000000e+00 4.129532e+02 281.74 -2.00 20.00 -2.00 505.43 0.00e+00 4.432820e-03 4.491236e-05 2.519646e-04 -6.000000e+00 2.185702e-04 281.74 -2.00 20.00 -2.00 500.70 0.00e+00 1.435645e+00 3.195983e-02 1.395426e-01 -6.000000e+00 1.537744e-01 226.05 -2.00 3.57 -2.00 502.25 0.00e+00 16.735 0.091 489.00 513.00 1 6.2526e+00 2.4356e-03 2.9932e-02 -6.0000e+00 1.1739e-02 -8.7737e-03 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