File name: Pandora103s1_Downsview_20181127_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T015953.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181127_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181127T123403.0Z 6905.523646 335 1 32.01 2 89.78 120.25 48.94 257.19 0.00 1 0.00 1 0 15 1.512e-01 1.383e-01 1.364e-01 1.299e-01 3.009971e+03 7.467195e+03 6.913942e+02 -6.000000e+00 7.627577e+03 275.79 -2.00 20.00 -2.00 505.18 0.00e+00 -6.113416e-04 3.457746e-03 3.679057e-05 -6.000000e+00 4.074586e-03 275.79 -2.00 20.00 -2.00 499.97 0.00e+00 2.271599e+00 2.552738e+00 7.071322e-02 -6.000000e+00 2.904390e+00 222.41 -2.00 3.57 -2.00 501.60 0.00e+00 20.363 0.165 489.00 513.00 1 1.0362e+01 1.9709e-01 3.6909e-02 -6.0000e+00 2.2137e-01 1.3121e-01 5.1217e-02 2.1043e-03 -6.0000e+00 5.8882e-02 3.0049e-06 -2.3872e-03 9.5860e-03 6.3106e-05 -6.0000e+00 1.1791e-02 -5.9338e-02 5.2191e-04 12 8 8 10 0 0 -8.20 15.00 8.75 -0.05934 -0.07590 8 1 1 4 0 4000.000 21.69 15.00 18.45 -7730 -18648 -5184 426 6148 -19150 8241 21228 -6125 7338 25302 21025 10812 -16896 9467 17232 -3917 6351 2998 18422 8919 -5153 -1852 8687 7646 14060 -27145 -3979 3015 -6771 13489 -7859 26100 -20128 -2916 6398 18079 -4935 -6433 4401 20879 -13973 19969 3468 5326 2101 -763 -6214 -5880 13824 1061 5031 -6492 24513 -8927 26269 2983 1451 -10457 20347 696 11513 930 3491 10941 4198 -20888 4143 -2601 16437 -7851 -14836 -6783 8802 10653 45 -4144 -11386 20733 -5750 27362 -3208 -12639 -5199 -14676 -15245 30292 -10540 10772 -8150 3921 8881 30274 -6226 7934 40510 11373 -6064 -13738 -6139 10579 -2118 -27782 20700 8332 21474 9752 -3046 2113 16492 12148 -9420 6795 1772 -13326 7252 7881 1755 -17281 -3056 23173 -13117 22942 -9900 -7950 -9559 3827 -18630 18269 25944 15761 12187 54867 6719 24812 -4588 17520 -3020 40549 20724 -1454 13745 4346 4536 -11834 18562 -24069 14575 -30782 6110 -8037 -21733 -5473 444 6248 -25276 8543 19731 -7432 7738 22029 18853 10550 -21153 9094 15348 -4317 6495 3280 17736 9399 -6218 -2161 9156 8193 14202 -40575 -4732 3293 -7778 12319 -8798 21375 -26709 -3425 6960 17354 -5817 -7585 4606 18561 -17432 18128 3729 5687 2323 -863 -7303 -6771 12869 1079 4759 -6714 18782 -9678 21111 3082 1536 -12387 17756 730 10936 983 3596 10415 4193 -26020 3988 -2645 13709 -8129 -16421 -7012 7958 9620 45 -4196 -12044 15907 -5653 19594 -3113 -13519 -5198 -16294 -17221 22118 -11361 9422 -8553 3674 8025 22719 -6678 7313 26707 9684 -5938 -14090 -5710 8280 -1896 -32925 16203 7616 17332 8670 -2995 1941 13227 10338 -10025 6262 1726 -15048 6727 7324 1742 -20482 -3100 17921 -14098 17244 -10299 -8195 -9989 3515 -21173 14472 19192 12827 10038 29446 5644 17403 -4328 13792 -2957 26463 16554 -1446 11828 4119 4321 -13233 15428 -29589 11960 -38029 5258 SO 20181127T123810.1Z 6905.526505 339 1 32.15 2 89.14 120.97 49.65 258.00 0.00 1 0.00 1 0 29 8.098e-02 7.803e-02 8.373e-02 8.173e-02 6.611484e+03 5.223513e+03 4.118301e+02 -6.000000e+00 4.083960e+03 275.79 -2.00 20.00 -2.00 505.25 0.00e+00 2.905527e-03 2.118913e-03 2.380056e-04 -6.000000e+00 2.181721e-03 275.79 -2.00 20.00 -2.00 499.91 0.00e+00 1.537765e+00 1.619528e+00 6.628131e-02 -6.000000e+00 1.555519e+00 222.41 -2.00 3.57 -2.00 501.57 0.00e+00 19.148 0.137 489.00 513.00 1 1.0062e+01 1.2293e-01 3.3756e-02 -6.0000e+00 1.1855e-01 1.4419e-01 3.2169e-02 2.2087e-03 -6.0000e+00 3.1551e-02 4.8775e-06 1.3035e-02 6.1107e-03 7.3210e-05 -6.0000e+00 6.3155e-03 4.1602e-02 -1.1086e-04 12 8 8 10 0 0 -0.75 15.00 3.24 0.04160 0.13202 8 1 1 4 0 4000.000 21.69 15.00 18.46 -4591 -2117 9711 -2621 529 16390 2951 -4041 -9711 5980 -918 2566 -12067 6330 -11516 18536 4128 2114 -2656 -11721 -16659 -3199 6620 1586 194 -1335 2209 3133 15600 -5794 10679 -800 1507 -5893 1089 -3063 14985 7210 7089 4173 4197 7368 5440 8801 -1112 10931 -6790 1313 9383 6859 -8329 -566 -6904 -12436 -10144 3738 -8135 6805 7051 1618 5535 -1846 -2651 -584 1850 -2096 -5057 712 -3978 -9490 -5591 3349 -2624 2997 13999 -3508 6562 -8240 7194 769 7752 20763 -6843 4617 5153 16730 1351 5792 -7488 -11969 4112 -846 4185 1207 -7568 10255 -9308 2201 2435 13996 2776 19305 -2100 9576 -16227 9036 -1034 -8077 -4722 15563 141 3198 3631 -8558 450 -13989 20228 -7059 18119 327 10900 -7265 -1929 35 1747 -2577 6730 -9196 8243 9006 -2208 -137 -4128 -7474 1334 1415 -11611 4764 156 6812 2259 587 -6159 6659 -10890 2809 -709 6548 -10295 18353 -4689 -2177 9286 -2913 580 15734 3277 -4809 -12064 6241 -1010 2690 -14311 6204 -13377 16235 4243 2290 -3073 -14774 -21970 -3703 6968 1767 220 -1530 2434 3362 14203 -6257 9793 -830 1588 -6980 1222 -3533 14294 7307 7100 4286 4343 7469 5697 9038 -1266 11021 -8028 1412 9132 6616 -9001 -555 -7184 -14028 -11630 3858 -9532 6880 7065 1700 5633 -2030 -2939 -630 1915 -2208 -5389 710 -4086 -10100 -5712 3166 -2665 2931 12277 -3555 5875 -8394 6272 712 6756 16046 -6921 4228 4746 13771 1282 5224 -7648 -12796 3808 -840 3993 1165 -7734 8575 -9123 1879 2021 10224 2276 13928 -1962 8327 -18242 7852 -970 -7969 -4524 12510 134 2984 3400 -9035 436 -15737 16529 -7496 14814 311 9144 -7160 -1819 32 1610 -2478 5904 -9345 7103 7695 -2055 -122 -3782 -7023 1165 1271 -12059 4267 148 6098 2117 561 -6316 6037 -11643 2582 -654 5467 -10035 13729 SO 20181127T124205.0Z 6905.529225 343 1 32.01 2 88.54 121.66 50.33 258.77 0.00 1 0.00 1 0 22 6.619e-02 6.447e-02 6.230e-02 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