File name: Pandora103s1_Downsview_20181203_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T021733.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181203_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181203T124053.0Z 6911.528391 414 1 32.01 2 89.78 121.70 53.95 151.08 0.00 1 0.00 1 0 43 1.169e-01 1.092e-01 1.021e-01 9.851e-02 -7.600959e+03 5.184232e+03 8.853056e+02 -6.000000e+00 5.877059e+03 275.11 -2.00 20.00 -2.00 505.17 0.00e+00 1.354607e-03 2.601734e-03 5.866842e-05 -6.000000e+00 3.144116e-03 275.11 -2.00 20.00 -2.00 499.76 0.00e+00 4.760694e+00 1.950360e+00 2.058681e-02 -6.000000e+00 2.247340e+00 222.33 -2.00 3.57 -2.00 501.45 0.00e+00 20.378 0.165 489.00 513.00 1 9.8964e+00 1.4834e-01 3.6652e-02 -6.0000e+00 1.7121e-01 1.2934e-01 3.9262e-02 2.0540e-03 -6.0000e+00 4.5618e-02 3.9977e-06 5.8746e-03 7.4230e-03 1.0099e-04 -6.0000e+00 9.1145e-03 2.9749e-02 -9.6472e-05 12 8 8 10 0 0 -2.49 15.00 2.56 0.02975 0.07050 8 1 1 4 0 4000.000 21.69 15.00 18.51 -1176 -14867 -7083 -5357 -2002 -11970 2290 5575 12516 -11007 12324 -6534 13702 5653 -1428 -19447 -4872 7730 16936 3566 1372 -7284 -6825 12922 -12586 16121 -10204 6170 -6296 -1738 -1224 6553 4961 22831 -155 29532 6342 19999 7360 -4621 17041 -7762 5491 -6640 24693 -9051 -1419 -5084 20485 -11897 -2111 -21390 5304 -11111 16578 -643 10286 -591 3095 -1306 1569 -3298 10664 13400 6409 -11009 1489 3388 4900 19982 -1983 32974 2141 14255 7931 5001 -7355 32304 3961 -12929 2243 -14722 -14633 26272 839 4888 -504 -4473 -4044 -7001 15388 -967 27014 -18144 12763 6385 -5464 426 11476 -9631 345 -2937 65 -5075 1770 16443 -5373 -9209 -11205 7768 -6575 13395 7541 17018 -7514 24557 -9191 10517 -3111 -293 -4743 3119 8777 19020 4916 -3948 13182 10676 -9931 6161 2220 1774 -3845 -3341 -3684 -19187 -1341 1916 8522 -15185 -3555 -10721 21187 -20168 3301 17934 18981 -9117 6749 -9887 -1179 -17368 -7978 -6172 -2280 -15303 2604 6194 12952 -14047 12329 -7755 13141 5768 -1550 -25211 -5567 8058 16652 4019 1573 -9089 -8457 13286 -16677 16155 -13117 6713 -7487 -1889 -1298 6485 5103 20696 -181 25818 6820 18551 7597 -5298 15866 -9241 5815 -7999 22173 -11249 -1621 -5918 18277 -14096 -2191 -25995 4905 -12165 14375 -682 9995 -640 3209 -1398 1633 -3618 10235 12464 6292 -12525 1470 3237 4556 15744 -1905 22723 2005 12069 7196 4597 -7401 21746 3476 -13308 2007 -15672 -15556 18893 778 4378 -475 -4373 -3947 -7061 12564 -940 20506 -21511 11212 5960 -5671 406 9505 -9512 307 -2732 61 -5114 1669 13108 -5145 -8940 -10989 6431 -6386 10997 6711 14049 -7913 19037 -9824 9175 -3030 -272 -4570 2764 7409 14753 4373 -3814 10798 8911 -10131 5415 2009 1577 -3530 -2993 -3290 -20312 -1233 1742 7348 -16537 -3451 -11147 16349 -23426 3069 14341 14571 -8824 5476 -9446 SO 20181203T124502.0Z 6911.531273 418 1 32.01 2 89.15 122.42 53.61 152.26 0.00 1 0.00 1 0 8 8.217e-02 7.815e-02 7.545e-02 7.332e-02 -2.684269e+03 3.929108e+03 7.055067e+01 -6.000000e+00 4.132060e+03 275.11 -2.00 20.00 -2.00 505.18 0.00e+00 5.404994e-03 1.935036e-03 3.297199e-04 -6.000000e+00 2.211094e-03 275.11 -2.00 20.00 -2.00 499.73 0.00e+00 4.172995e+00 1.474768e+00 8.451507e-02 -6.000000e+00 1.580552e+00 222.33 -2.00 3.57 -2.00 501.41 0.00e+00 19.171 0.137 489.00 513.00 1 9.7405e+00 1.1296e-01 3.4392e-02 -6.0000e+00 1.2040e-01 1.2840e-01 2.9949e-02 2.1704e-03 -6.0000e+00 3.2093e-02 5.4360e-06 -3.4725e-04 5.5536e-03 8.1414e-05 -6.0000e+00 6.4071e-03 -2.3911e-02 2.0277e-04 12 8 8 10 0 0 1.75 15.00 2.65 -0.02391 -0.02632 8 1 1 4 0 4000.000 21.69 15.00 18.52 11620 -18398 1182 435 7128 3702 5848 -3511 5949 12783 1198 846 2541 -4488 7614 -4802 -9380 14110 7085 -5943 -8858 -5537 -3449 -1198 -5901 6453 -782 2879 -5631 3563 -5294 2773 1815 -907 -4203 4252 9913 2124 11175 -7663 4617 2827 158 7359 -4383 -2399 -6241 7562 5739 -12090 4231 -1293 2229 -7742 -3277 -2138 11961 -2778 11576 7512 4500 6777 9662 11413 -10996 -5015 -5515 -5443 -18199 22371 4791 -350 -7160 10199 -5411 9788 1611 -1214 -108 -5852 5240 -3722 -3704 -293 -1169 6929 -3431 -17812 1005 10491 11998 -6087 4174 21071 2801 8185 63 -7715 10083 -1610 -8958 7415 491 -6576 12962 6846 7213 8420 -4472 -5386 113 6503 -13773 722 -6722 -4987 -2209 14638 -7394 4041 -6885 20485 2140 2813 -6355 -6169 3084 1062 34 -3879 6967 -12413 9334 -6371 22573 -1197 14962 2410 12079 -3738 13305 -8579 -3226 -9233 -3679 6072 3849 -11131 314 20330 10263 -21967 1206 467 7382 4034 6375 -4245 6561 13002 1333 930 2706 -5020 7487 -5314 -10931 13373 7418 -7183 -10969 -6627 -4039 -1375 -7157 6981 -904 3197 -6659 3680 -5750 2779 1861 -992 -4955 4674 10167 2311 10985 -8934 4775 3001 174 7681 -5200 -2807 -7553 7896 5995 -14682 4237 -1323 2159 -8251 -3433 -2303 11546 -3124 11298 7560 4641 6874 9576 11094 -13174 -5564 -6011 -5821 -21780 17747 4417 -338 -7439 9068 -5675 8811 1529 -1153 -101 -5706 4586 -3581 -3568 -272 -1105 6088 -3324 -19719 922 8778 9924 -6077 3866 16840 2665 7316 60 -7768 8271 -1433 -8396 5944 430 -6397 10648 5890 6038 6807 -4036 -4944 101 5577 -14718 683 -6898 -5055 -2187 12286 -7578 3633 -6777 15276 1897 2511 -6263 -6063 2775 973 32 -3740 6036 -12708 7567 -5906 15626 -1052 11582 2153 9942 -3615 10923 -8682 -3113 -9518 -3613 5399 3417 -11009 269 14285 SO 20181203T124902.0Z 6911.534051 422 1 32.01 2 88.54 123.12 53.31 153.41 0.00 1 0.00 1 0 15 6.302e-02 6.036e-02 5.576e-02 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