File name: Pandora103s1_Downsview_20181217_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T021730.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181217_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181217T125315.0Z 6925.536979 467 1 32.01 2 89.78 123.56 134.30 0.89 0.00 1 0.00 1 0 40 1.310e-01 1.187e-01 1.187e-01 1.146e-01 -6.835974e+03 5.840060e+03 1.033504e+03 -6.000000e+00 6.545388e+03 273.60 -2.00 20.00 -2.00 505.43 0.00e+00 7.109494e-03 3.053257e-03 3.015634e-04 -6.000000e+00 3.515673e-03 273.60 -2.00 20.00 -2.00 500.83 0.00e+00 6.249873e+00 2.178292e+00 1.960993e-01 -6.000000e+00 2.536976e+00 222.24 -2.00 3.57 -2.00 502.39 0.00e+00 20.418 0.166 489.00 513.00 1 9.8527e+00 1.6656e-01 3.9884e-02 -6.0000e+00 1.9284e-01 -3.5336e-02 4.2971e-02 2.9841e-03 -6.0000e+00 5.1996e-02 3.4216e-06 1.5938e-02 8.6417e-03 1.6629e-04 -6.0000e+00 1.0232e-02 2.2110e-02 -4.1371e-04 12 8 8 10 0 0 13.57 15.00 10.08 0.02211 0.13266 8 1 1 4 0 4000.000 21.69 15.00 18.51 900000 6902 26725 -14215 -6563 12781 8519 -10533 -5396 16044 3116 -12593 -14475 -8229 10330 16969 -12191 8088 15878 12266 3065 -3761 66 2252 16150 21812 -10056 -1068 -4189 7918 -4054 -8145 11241 -3399 -6195 2853 18387 -18222 -11286 -19043 6075 -962 42332 6045 14006 16317 2191 -8092 15107 25860 -1990 -10398 6832 11048 -23724 -924 -1481 16267 -7815 11 3008 8065 1184 8920 -2336 -9008 8361 9187 -5542 12705 4578 -1967 -4046 7948 20185 3161 21874 -10352 9769 -2714 -15051 550 -9834 -10082 1826 -14398 13517 3088 -5796 -8339 -12658 12315 1798 -3888 -4771 -2582 -15734 5486 2938 36697 5014 40922 -3361 25781 10393 13031 26756 -2071 -4455 -11768 -4104 -2619 -9570 -16498 28967 -848 2603 8047 4319 2585 3429 2418 13302 -10624 25745 4385 22676 -16134 24208 -9617 -4037 -19192 12118 -8482 4076 12991 5013 -5393 14435 -449 -13870 22954 -5868 -4635 -1232 13949 -12619 -1991 577 19342 900000 5589 18693 -15358 -6733 11124 7884 -11798 -5716 13547 2929 -13621 -15693 -8291 8672 13444 -12999 7316 13698 11012 2997 -3940 66 2255 14315 18368 -11493 -1110 -4338 6986 -3963 -8361 9856 -3605 -6950 2921 15977 -22263 -12758 -23133 5845 -1006 29696 6115 13294 15184 2321 -9333 13704 20588 -2003 -11094 6120 9669 -30162 -977 -1605 14908 -9000 11 3113 8020 1261 8785 -2531 -10207 7861 8462 -5811 10955 4223 -1942 -4120 7326 16653 3021 16994 -10785 8343 -2609 -16399 520 -10241 -10550 1717 -15852 11329 2851 -5836 -8641 -13799 10806 1796 -4164 -5163 -2741 -18811 5197 2757 24234 4450 25982 -3352 19941 9266 11039 19398 -1946 -4287 -12433 -4145 -2693 -10856 -20432 23416 -919 2724 7902 4314 2590 3388 2404 12058 -12354 21190 4448 19357 -20013 20497 -11380 -4488 -24205 11081 -9305 3950 11827 5087 -6173 13801 -498 -17496 20320 -6937 -5479 -1417 13702 -15530 -2133 592 16728 SO 20181217T125726.0Z 6925.539884 471 1 32.01 2 89.16 124.29 134.27 2.29 0.00 1 0.00 1 0 15 1.764e-02 1.731e-02 1.410e-02 1.391e-02 5.642889e+03 7.927109e+02 3.464992e+02 -6.000000e+00 8.816929e+02 273.60 -2.00 20.00 -2.00 505.51 0.00e+00 5.122524e-03 3.695636e-04 2.783464e-04 -6.000000e+00 4.728721e-04 273.60 -2.00 20.00 -2.00 501.40 0.00e+00 1.733119e+00 2.570274e-01 7.350619e-02 -6.000000e+00 3.397501e-01 222.24 -2.00 3.57 -2.00 502.84 0.00e+00 19.226 0.138 489.00 513.00 1 8.1948e+00 1.9512e-02 3.4319e-02 -6.0000e+00 2.5863e-02 -4.0292e-02 5.0472e-03 2.2655e-03 -6.0000e+00 6.9045e-03 3.0358e-05 -1.8090e-03 1.0636e-03 8.7572e-05 -6.0000e+00 1.3753e-03 3.6359e-02 -2.2959e-04 12 8 8 10 0 0 8.31 15.00 3.00 0.03636 0.02381 8 1 1 4 0 4000.000 21.69 15.00 18.52 -2372 112 -4584 -58 746 -375 1390 3076 3265 -1322 2293 -5036 455 -1405 1492 701 -2217 -1375 822 1666 2923 -858 2034 661 1243 969 1650 597 -888 -725 -3306 872 -2391 883 103 921 -1088 862 -800 -75 -1502 580 -236 1591 -603 3290 157 4234 -1077 848 301 -2556 -3302 -1031 1192 -2363 761 -18 613 -220 1147 400 1899 440 2290 736 1403 183 -616 330 -460 -607 -4577 -1895 311 -1032 292 -537 -2357 -2164 -2422 -478 -33 1989 -1275 926 -395 -1462 -1501 3212 -3151 1873 -2122 -75 923 2991 -394 -1743 -2056 -2707 566 -2909 -14 -1566 1715 -134 2996 -1682 -1422 -1969 1649 -2463 2501 83 1653 2783 2083 4453 -424 -737 1531 1118 1308 324 -1425 2069 607 740 -425 785 -988 1118 -41 -529 -1920 -397 -899 1692 77 -404 1326 166 1237 -1733 1487 -525 433 -1327 -492 -2939 -1858 87 -3837 -49 643 -333 1244 2756 2930 -1228 2017 -4696 397 -1230 1259 595 -1956 -1231 746 1532 2657 -809 1869 618 1170 923 1561 570 -848 -664 -2998 758 -2178 810 100 903 -1078 828 -772 -72 -1449 555 -232 1558 -614 3261 161 4129 -1091 829 287 -2435 -3112 -952 1106 -2368 765 -19 628 -226 1163 411 1946 458 2337 753 1400 182 -613 321 -444 -586 -4640 -1902 312 -1049 287 -520 -2295 -2095 -2349 -460 -32 1888 -1264 910 -394 -1467 -1497 3058 -3203 1841 -2225 -78 946 2942 -392 -1709 -1972 -2551 508 -2718 -13 -1564 1731 -138 2981 -1720 -1431 -2005 1663 -2644 2607 90 1773 2969 2263 4794 -479 -823 1643 1184 1366 345 -1570 2213 661 808 -467 858 -1102 1201 -44 -560 -2047 -422 -990 1860 88 -465 1517 193 1429 -2076 1735 -624 501 -1521 -545 -3305 SO 20181217T130112.6Z 6925.542507 475 1 15.25 2 88.60 124.95 134.23 3.55 0.00 1 0.00 1 0 15 1.136e-02 1.109e-02 1.152e-03 1.144e-03 6.530941e+03 6.599115e+01 4.504939e+02 -6.000000e+00 5.679474e+02 273.60 -2.00 20.00 -2.00 505.45 0.00e+00 6.066184e-03 3.036516e-05 3.176826e-04 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