File name: Pandora103s1_Downsview_20181231_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T021830.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181231_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181231T125838.0Z 6939.540718 380 1 32.01 2 89.80 123.11 53.27 179.14 0.00 1 0.00 1 0 85 1.507e-01 1.365e-01 1.424e-01 1.356e-01 5.709403e+03 8.238507e+03 7.250657e+02 -6.000000e+00 7.509327e+03 272.73 -2.00 20.00 -2.00 505.15 0.00e+00 5.502359e-03 3.542825e-03 2.358189e-04 -6.000000e+00 4.029169e-03 272.73 -2.00 20.00 -2.00 499.84 0.00e+00 -1.987614e+00 2.714707e+00 7.394066e-02 -6.000000e+00 2.900493e+00 222.80 -2.00 3.57 -2.00 501.48 0.00e+00 20.446 0.167 489.00 513.00 1 1.0635e+01 2.0686e-01 3.7558e-02 -6.0000e+00 2.2082e-01 2.5113e-01 5.4712e-02 2.0994e-03 -6.0000e+00 5.8798e-02 2.8514e-06 4.8864e-03 1.0214e-02 8.9837e-05 -6.0000e+00 1.1748e-02 -1.8341e-02 2.7127e-04 12 8 8 10 0 0 91.24 15.00 8.70 -0.01834 0.01555 8 1 1 4 0 4000.000 21.69 15.00 18.43 -11482 6809 -6366 12423 16994 -6327 -4983 -9924 9408 17786 -13461 -7646 3343 -9616 4945 -15803 29795 -19698 11204 7769 21663 -3774 21942 -339 -1463 2829 106 -10591 11594 -13730 21606 2752 -13685 20564 -122 15638 15364 -4773 -13487 4896 -455 16422 9292 4635 -10990 20031 -9017 -1622 -5710 9121 1362 6464 7303 2854 12042 5983 12630 16835 19581 -16162 -12558 21047 -13153 21284 3527 5773 -19251 10789 -1188 -25571 23284 -3876 5462 42594 -7028 25033 -6328 5014 -8418 -4617 -12314 3296 -14831 14115 -2633 -862 12268 -3811 55186 5184 -14767 8298 -7955 13415 43995 14026 16575 5381 -10193 -23291 6877 1855 6323 -21536 24995 -27126 17712 22864 -9815 8400 264 24863 -4584 4014 21095 -2222 -6296 14303 4270 13739 2777 2569 -5124 -3584 17936 5887 9335 37372 2193 -13112 3131 -4787 -10657 -16833 -1930 -17073 11515 25622 29114 1333 19316 -21922 5852 -11781 2978 -19520 13447 7983 6389 -1529 -13000 6591 -7267 12300 16423 -7781 -6160 -12936 10102 17237 -17240 -9122 3518 -11260 4984 -19461 23928 -26128 11330 8160 19769 -4394 19893 -383 -1683 3123 119 -13108 11217 -16162 17738 2721 -16208 18333 -137 15046 14574 -5416 -16425 4957 -488 15123 9302 4926 -13750 18625 -11014 -1818 -6544 8824 1372 6039 6688 2764 11074 6050 12235 15734 17756 -20545 -15448 18912 -16490 19098 3711 5833 -24273 10055 -1229 -32849 18488 -4015 5231 29073 -7792 20103 -6681 4655 -8830 -4646 -13386 3109 -16672 12083 -2679 -866 10806 -3885 31769 4811 -16727 7687 -8803 12070 28912 11971 13434 4716 -10099 -25522 5596 1610 5465 -25499 19294 -34255 14261 17156 -10006 7307 254 19180 -4746 3847 17174 -2271 -6760 12634 4096 11767 2582 2342 -5012 -3498 14299 5256 8056 24478 2004 -13921 2799 -4486 -10367 -17157 -1699 -17727 9298 18244 20212 1216 14812 -24949 5111 -12197 2665 -21382 10415 6289 5000 -1294 SO 20181231T130236.0Z 6939.543472 384 1 32.01 2 89.20 123.80 53.28 180.33 0.00 1 0.00 1 0 22 1.130e-01 1.072e-01 9.525e-02 9.180e-02 -3.091405e+02 4.883826e+03 1.217657e+02 -6.000000e+00 5.627701e+03 272.73 -2.00 20.00 -2.00 505.14 0.00e+00 3.979740e-03 2.405734e-03 2.555498e-04 -6.000000e+00 3.021574e-03 272.73 -2.00 20.00 -2.00 499.81 0.00e+00 2.797789e+00 1.844956e+00 4.273553e-02 -6.000000e+00 2.176831e+00 222.80 -2.00 3.57 -2.00 501.46 0.00e+00 19.328 0.141 489.00 513.00 1 1.0072e+01 1.4157e-01 3.3998e-02 -6.0000e+00 1.6569e-01 1.4560e-01 3.7159e-02 1.9139e-03 -6.0000e+00 4.4186e-02 4.2814e-06 1.2530e-03 6.9701e-03 6.0399e-05 -6.0000e+00 8.8094e-03 1.0741e-02 9.5957e-06 12 8 8 10 0 0 97.21 15.00 3.26 0.01074 0.01943 8 1 1 4 0 4000.000 21.69 15.00 18.45 -15903 -12834 -1767 25301 6911 11341 9897 11831 5836 -11050 2806 2984 -11648 1818 8299 -10046 11406 -9091 3223 19269 6749 -10225 -4460 -8278 4907 -6732 9267 9480 18502 -3056 11766 8370 -3393 2218 -20783 -6365 197 6400 -8042 29606 -6153 14106 2440 18045 8211 -143 1864 3142 -4225 -9230 2679 21659 6469 -21878 17486 13168 13376 -1439 -1401 -16853 3135 -10719 1543 10289 -3983 -5847 4000 -3478 -3657 8346 3731 11563 -13171 -972 -181 9096 3700 9924 -2852 3177 -17605 15007 -21740 567 -6814 499 -13462 7098 8893 7568 1278 13585 1370 -6244 7384 2117 -5826 -676 -578 -4455 21205 -7451 -4585 -14254 13076 -12212 10943 11358 31087 907 3768 -4833 142 -4314 12056 7245 -5900 9726 -11727 23978 684 930 1090 11093 -22195 946 3633 10067 -1536 12637 1986 1698 14127 6721 8174 -1623 2482 11804 13230 -297 9134 -14756 7312 3629 -5147 16434 -18006 -16192 40998 -9761 -18319 -14553 -1864 21437 7175 11477 10373 12311 6424 -14092 3061 3206 -14186 1909 8097 -11698 10896 -10847 3524 18284 7192 -12831 -5284 -10201 5370 -8270 9703 9850 17207 -3340 10810 7954 -3673 2370 -28897 -7746 222 6672 -9509 24054 -7062 13418 2632 16965 8596 -163 2072 3399 -4826 -10803 2696 17601 5976 -26671 15006 12246 12723 -1593 -1543 -21377 3267 -12861 1651 10088 -4440 -6515 3964 -3647 -3798 7579 3483 10009 -14600 -972 -182 8290 3457 8522 -2741 2864 -19421 12191 -25235 531 -6921 475 -14635 6290 7708 6644 1197 11462 1331 -6601 6778 2014 -5885 -633 -524 -4074 14925 -6966 -4287 -15261 10985 -12956 9089 9183 20519 808 3339 -4752 135 -4360 10466 6610 -6143 8709 -12755 18112 636 849 989 9261 -25773 877 3284 8520 -1449 10460 1813 1519 10967 5516 6556 -1451 2195 9726 10868 -281 7883 -16016 6445 3338 -5167 13305 -19837 -16902 24000 -9276 SO 20181231T130623.0Z 6939.546100 388 1 32.00 2 88.63 124.46 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