File name: Pandora103s1_Downsview_20190104_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023909.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190104_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190104T125845.0Z 6943.540799 497 1 32.01 2 89.79 122.57 78.85 135.00 0.00 1 0.00 1 0 15 2.582e-02 2.554e-02 2.763e-02 2.729e-02 1.966409e+03 1.530346e+03 8.733018e+01 -6.000000e+00 1.285273e+03 272.48 -2.00 20.00 -2.00 505.22 0.00e+00 3.535723e-03 7.120816e-04 1.692807e-04 -6.000000e+00 6.903341e-04 272.48 -2.00 20.00 -2.00 499.94 0.00e+00 2.569911e+00 5.392764e-01 3.758808e-02 -6.000000e+00 4.982165e-01 222.96 -2.00 3.57 -2.00 501.59 0.00e+00 20.439 0.166 489.00 513.00 1 8.6959e+00 4.1048e-02 3.7089e-02 -6.0000e+00 3.7908e-02 1.3670e-01 1.0890e-02 2.1028e-03 -6.0000e+00 1.0126e-02 1.5030e-05 2.3690e-03 2.0553e-03 4.2636e-05 -6.0000e+00 2.0129e-03 1.2572e-02 -9.9906e-05 12 8 8 10 0 0 4.61 15.00 3.75 0.01257 0.02900 8 1 1 4 0 4000.000 21.69 15.00 18.47 3157 -1187 -878 -3392 4670 -2400 -292 -1584 -2629 550 1028 467 1697 -1834 956 -176 -3219 1087 -1392 2681 3944 -4540 -1124 2706 3250 156 -3726 3597 1898 -87 3200 2028 -508 -1656 341 2811 3073 -4917 221 835 1524 -3042 1143 -1885 -980 844 1110 -3543 1972 -1360 -4080 -236 5537 374 -1559 1223 -3816 1784 -308 3326 -1664 1814 93 -2570 633 2743 -275 3092 -3400 171 3938 1388 -1052 1899 1023 -419 -1268 -2289 -2398 4585 608 -1743 -1264 2362 2503 -4001 4768 -1993 62 -5265 426 -1318 3946 1643 -1441 -1990 3059 2914 -3102 -5648 2921 -2498 5615 -3160 2319 1261 -5795 1015 -4195 3339 -1357 1796 2114 306 4028 -989 -727 3006 -24 -1738 1553 987 2736 3932 -1962 -3693 1468 2906 5574 307 -2896 -4476 153 1998 263 -1240 -2007 -2305 -3727 1163 -1591 -2216 1095 2693 1926 1532 -558 28 -1404 367 2930 -1164 -888 -3673 4803 -2691 -327 -1824 -3056 610 1112 501 1771 -1946 976 -182 -3455 1146 -1553 2920 4226 -5277 -1263 2933 3536 176 -4334 3877 2036 -91 3135 2009 -524 -1799 378 3078 3308 -5630 238 881 1597 -3358 1227 -2113 -1103 938 1224 -4032 2092 -1456 -4329 -234 5089 362 -1583 1257 -4229 1889 -332 3430 -1795 1905 99 -2825 669 2788 -281 3015 -3495 166 3639 1315 -1029 1832 1010 -417 -1239 -2202 -2283 4054 559 -1654 -1197 2164 2315 -3973 4341 -1926 58 -5217 400 -1279 3723 1600 -1429 -1944 2788 2587 -2835 -5147 2413 -2195 4696 -3015 2159 1181 -5700 914 -3915 2919 -1270 1663 1984 295 3770 -975 -720 2886 -23 -1698 1443 906 2448 3521 -1879 -3594 1360 2647 4924 288 -2785 -4271 137 1729 229 -1113 -1870 -2196 -3640 1095 -1544 -2162 1040 2534 1831 1453 -528 26 -1258 322 SO 20190104T130237.0Z 6943.543484 501 1 32.01 2 89.20 123.25 78.38 135.75 0.00 1 0.00 1 0 15 2.088e-02 2.073e-02 1.835e-02 1.817e-02 2.883931e+03 1.038751e+03 2.703254e+02 -6.000000e+00 1.039427e+03 272.48 -2.00 20.00 -2.00 505.22 0.00e+00 3.525050e-03 4.739040e-04 1.698263e-04 -6.000000e+00 5.582772e-04 272.48 -2.00 20.00 -2.00 499.99 0.00e+00 1.356204e+00 3.589172e-01 2.512977e-02 -6.000000e+00 4.028857e-01 222.96 -2.00 3.57 -2.00 501.63 0.00e+00 19.341 0.141 489.00 513.00 1 8.5169e+00 2.7304e-02 3.3680e-02 -6.0000e+00 3.0655e-02 1.4835e-01 7.2626e-03 1.8782e-03 -6.0000e+00 8.1873e-03 2.2884e-05 -4.6875e-04 1.3738e-03 5.2873e-05 -6.0000e+00 1.6278e-03 4.6723e-04 -1.9377e-05 12 8 8 10 0 0 -13.98 15.00 1.39 0.00047 -0.00278 8 1 1 4 0 4000.000 21.69 15.00 18.48 -3838 12 -3021 2389 -2308 2840 -1902 1774 -1388 -467 -4210 -32 1077 334 -85 -2116 2839 1289 880 -199 1428 -1800 1830 970 3133 -2462 2371 -1965 2014 885 1765 -162 683 -1544 229 713 468 55 91 -1345 -2625 -1355 -672 2405 407 2330 -1854 749 -1251 642 -546 1806 -1505 1079 -3822 63 715 2168 1378 -117 -1815 -137 3632 -487 2108 -3430 3724 -1369 190 -3023 3082 -3217 84 -3279 3301 252 3382 -8 -393 416 210 8 -564 877 1517 3384 -1209 2136 -6166 3884 -2428 706 6197 -122 721 4235 2697 -1331 -3619 -1482 -991 2744 918 -1074 -986 -1932 -103 -1707 1697 -3192 -81 -619 1173 962 1155 -489 554 -2166 2077 -1231 1516 -564 588 703 -318 2583 -31 -3447 -2163 -1158 -4 854 -1039 2964 -1468 -88 -682 962 -4261 1919 -3163 2480 3920 1354 75 516 1457 -2580 -105 -3552 -3810 12 -3096 2426 -2525 3009 -2155 1967 -1588 -524 -4782 -35 1129 346 -88 -2212 2850 1341 949 -221 1558 -2022 1982 1060 3381 -2818 2580 -2220 2151 915 1743 -162 687 -1648 251 790 513 60 98 -1440 -2838 -1457 -727 2558 447 2531 -2091 814 -1363 672 -560 1752 -1477 1030 -3921 65 752 2278 1456 -124 -1954 -146 3757 -524 2198 -3710 3681 -1397 190 -3057 2884 -3192 82 -3327 3196 251 3190 -8 -370 385 194 7 -535 820 1426 3155 -1178 2004 -6230 3554 -2369 676 5759 -122 708 3937 2491 -1244 -3361 -1311 -857 2301 805 -1007 -956 -1893 -97 -1606 1519 -3006 -76 -592 1121 932 1121 -484 546 -2207 2020 -1213 1427 -532 541 652 -302 2379 -29 -3360 -2069 -1101 -3 778 -943 2550 -1306 -78 -625 886 -4171 1789 -3110 2308 3611 1286 73 493 1353 -2409 -93 -3218 SO 20190104T130624.0Z 6943.546111 505 1 32.01 2 88.63 123.91 77.92 136.49 0.00 1 0.00 1 0 22 1.178e-02 1.169e-02 7.888e-03 7.864e-03 5.572367e+03 4.626598e+02 3.989296e+02 -6.000000e+00 5.862669e+02 272.48 -2.00 20.00 -2.00 505.36 0.00e+00 4.366374e-03 2.064191e-04 2.226905e-04 -6.000000e+00 3.149453e-04 272.48 -2.00 20.00 -2.00 500.61 0.00e+00 1.764366e+00 1.507356e-01 5.467142e-02 -6.000000e+00 2.273300e-01 222.96 -2.00 3.57 -2.00 502.18 0.00e+00 17.914 0.112 489.00 513.00 1 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