File name: Pandora103s1_Downsview_20190118_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023954.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190118_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190118T125345.0Z 6957.537326 365 1 32.01 2 89.78 119.30 111.80 330.99 0.00 1 0.00 1 0 43 1.295e-01 1.150e-01 1.169e-01 1.118e-01 4.658233e+03 6.816020e+03 1.455316e+02 -6.000000e+00 6.429029e+03 271.77 -2.00 20.00 -2.00 505.16 0.00e+00 1.435560e-03 2.870546e-03 8.673720e-05 -6.000000e+00 3.456007e-03 271.77 -2.00 20.00 -2.00 499.82 0.00e+00 -1.353321e+00 2.247541e+00 8.645639e-02 -6.000000e+00 2.499962e+00 223.52 -2.00 3.57 -2.00 501.46 0.00e+00 20.443 0.166 489.00 513.00 1 1.0456e+01 1.6983e-01 3.7374e-02 -6.0000e+00 1.9019e-01 2.3430e-01 4.5617e-02 2.4979e-03 -6.0000e+00 5.0758e-02 3.4925e-06 -1.2294e-02 8.2358e-03 4.3600e-05 -6.0000e+00 1.0093e-02 -6.7706e-02 4.5019e-04 12 8 8 10 0 0 -0.09 15.00 6.44 -0.06771 -0.15298 8 1 1 4 0 4000.000 21.69 15.00 18.45 -13853 114 6927 -11441 1106 -2559 -8697 695 -12617 -6773 16057 10008 20107 830 5990 12030 -4957 -5439 -20548 6590 -4785 -642 11248 7407 -2763 7902 4918 2300 10569 4778 -9455 -10234 15071 -4648 13615 7806 5786 -2000 13665 -1808 243 -4247 6123 -269 11139 -2444 18067 -9126 -8591 -5490 9065 -2727 11495 -6178 2996 12954 -4181 7509 -599 10275 -9128 -18430 -3 15967 -8234 -6155 5028 6039 1941 4794 -23060 3559 1910 6813 3572 378 -1600 23638 23365 -457 10782 -5459 13693 5412 17019 -4458 27498 3756 26842 -15833 16150 -20160 20423 -3043 6436 -16676 38853 -11807 8896 3367 46686 12621 -12462 -9881 7780 -11317 -15039 -12355 5617 20147 -7730 11536 5099 11058 -15505 25962 -878 10512 4877 -5993 13336 213 -2910 5399 -2582 -563 9272 428 12889 -6678 -904 -18587 15676 -2231 43373 -17496 -606 -2534 18633 3179 1889 -9485 18544 -11420 34571 -7970 6722 4531 -24692 -1579 -16083 114 6585 -13449 1198 -2936 -10773 802 -16722 -8460 15813 10240 18413 899 6061 11372 -5514 -6150 -27589 7027 -5753 -738 11508 7841 -3230 8398 5373 2562 10791 5023 -10871 -11551 13362 -5073 13002 8188 6208 -2273 13163 -1993 260 -4730 6221 -294 11030 -2788 16967 -11054 -10197 -6218 8695 -2829 10095 -6331 2822 11477 -4535 7453 -647 9947 -10572 -23326 -3 14666 -9540 -6926 4987 5811 1917 4564 -28225 3327 1819 6259 3445 382 -1630 18365 17818 -434 9148 -5434 11452 4924 13927 -4553 20821 3569 20320 -17991 13485 -24009 16711 -3184 6153 -19519 25998 -12521 7506 2918 26077 9692 -12379 -9953 6958 -12512 -17154 -13488 5041 15508 -7852 9918 4732 9786 -17811 19990 -877 9493 4671 -6305 11398 202 -2781 4723 -2466 -529 7909 397 10530 -6546 -841 -20298 11973 -1982 24588 -17683 -530 -2319 14106 2817 1710 -9598 14324 -11820 23053 -7987 5787 3882 -27070 -1351 SO 20190118T125743.0Z 6957.540081 369 1 32.01 2 89.16 119.99 112.12 331.88 0.00 1 0.00 1 0 15 8.128e-02 7.759e-02 7.664e-02 7.440e-02 1.273949e+02 3.959711e+03 3.227274e+02 -6.000000e+00 4.034957e+03 271.77 -2.00 20.00 -2.00 505.15 0.00e+00 2.167244e-03 1.943348e-03 1.268904e-04 -6.000000e+00 2.169459e-03 271.77 -2.00 20.00 -2.00 499.66 0.00e+00 2.362476e+00 1.482439e+00 7.934253e-02 -6.000000e+00 1.570470e+00 223.52 -2.00 3.57 -2.00 501.33 0.00e+00 19.256 0.139 489.00 513.00 1 9.9306e+00 1.1297e-01 3.3687e-02 -6.0000e+00 1.1945e-01 1.6798e-01 3.0229e-02 2.0676e-03 -6.0000e+00 3.1928e-02 5.3354e-06 2.0653e-03 5.6196e-03 4.0975e-05 -6.0000e+00 6.3364e-03 1.9452e-02 -1.6375e-04 12 8 8 10 0 0 5.78 15.00 6.71 0.01945 0.03378 8 1 1 4 0 4000.000 21.69 15.00 18.46 -1140 7619 -12971 683 4317 9573 -14294 9503 -7214 4143 -119 5650 -4584 -4851 -2577 12698 -287 -344 5941 -4177 2900 12078 -3654 10750 8403 -4923 4355 -11996 9029 2482 5083 1198 1426 -6920 -151 -11161 3024 9522 -4385 7728 -4070 2000 -4432 2302 -9227 5860 -4779 2224 5069 -7282 5833 -537 -9655 -83 6597 2903 -4637 535 6239 -2302 6412 10665 6768 -1757 10870 -3904 4677 -12413 -7449 14868 -514 4554 6276 -1602 20087 5173 -2402 1847 -4944 11072 -2971 2512 -6159 9554 -13030 8251 -5921 2118 -9305 534 -6974 16913 -1547 -11868 -10138 7422 -1386 -1122 1544 938 9414 17395 3872 -8311 16797 -5211 7077 -8036 -898 3192 5740 -5884 576 8954 12003 -6847 2191 12733 7940 4610 -7534 -3611 490 -4510 1598 7487 -12846 3480 -5120 -6722 -5960 -3462 -14991 16932 -6079 -3737 4157 18850 -2322 13356 4586 22655 16174 -6318 -4206 12747 -1598 -65 -4074 -17268 -1154 7167 -15395 740 4640 9946 -19129 10222 -9129 4626 -136 6004 -5295 -5513 -2834 12017 -311 -381 6408 -5053 3262 12413 -4365 11170 8999 -6017 4837 -15525 9328 2608 5039 1232 1484 -8124 -173 -14378 3345 9725 -5052 7807 -4600 2143 -5111 2515 -11412 6283 -5650 2421 5274 -8343 5676 -538 -10351 -81 6206 2942 -5189 575 6316 -2509 6392 10256 6790 -1911 10368 -4220 4550 -14015 -7927 12527 -494 4160 5683 -1588 16389 4849 -2360 1696 -4794 9134 -2808 2275 -6086 8118 -13933 7236 -5953 1961 -9581 499 -7039 13708 -1534 -13129 -10920 6627 -1324 -1041 1355 805 7326 12630 3296 -8322 13549 -5169 6104 -7841 -804 2761 4939 -5777 541 7834 10248 -7033 2072 10890 7035 4135 -7466 -3385 438 -4277 1441 6362 -13292 3061 -4869 -6524 -5723 -3172 -15018 12255 -5443 -3309 3511 14096 -2155 10749 4029 16687 12744 -6231 -4077 10427 -1469 -56 -3592 -17182 SO 20190118T130130.0Z 6957.542708 373 1 32.01 2 88.57 120.65 112.42 332.74 0.00 1 0.00 1 0 22 6.044e-02 5.928e-02 5.443e-02 5.331e-02 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