File name: Pandora103s1_Downsview_20190201_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T024005.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190201_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190201T124120.0Z 6971.528704 441 1 32.01 2 89.78 114.25 73.21 146.74 0.00 1 0.00 1 0 15 5.497e-02 5.272e-02 5.635e-02 5.534e-02 6.294779e+02 2.915178e+03 1.966275e+02 -6.000000e+00 2.729043e+03 271.77 -2.00 20.00 -2.00 505.18 0.00e+00 3.021171e-03 1.435600e-03 1.836538e-04 -6.000000e+00 1.468577e-03 271.77 -2.00 20.00 -2.00 499.87 0.00e+00 2.652332e+00 1.104073e+00 6.177169e-02 -6.000000e+00 1.067853e+00 224.08 -2.00 3.57 -2.00 501.52 0.00e+00 20.436 0.166 489.00 513.00 1 9.4242e+00 8.4020e-02 3.7245e-02 -6.0000e+00 8.1116e-02 1.4804e-01 2.2587e-02 2.1641e-03 -6.0000e+00 2.1866e-02 7.2845e-06 -3.2266e-03 4.2106e-03 5.1919e-05 -6.0000e+00 4.2935e-03 5.3698e-03 -2.5565e-04 12 8 8 10 0 0 17.11 15.01 5.22 0.00537 -0.01701 8 1 1 4 0 4000.000 21.58 15.01 18.38 900000 -3227 191 75 8996 -1819 -6717 1973 6838 -4191 1131 55 163 -964 2629 -9482 -1285 2500 27 -3661 -3125 -3019 2629 6894 -27 12169 -2221 2498 460 -1794 -3591 -2865 3452 -43 -3151 -4849 1819 -5368 6372 -3737 7468 -3624 4862 1226 6558 3591 4086 317 3703 8319 -1428 7489 7991 -7613 8696 -6144 1309 -7296 3942 -5201 -3325 8147 -3536 3982 376 -1747 -4175 -4564 -3295 1421 -4979 -4022 -3113 -3142 3409 8456 -3033 -1509 -703 7946 5625 4627 -5832 -4478 5294 -5055 4591 -6497 10500 630 -879 10330 -559 -5545 3042 -5135 4375 -2232 -7471 -2405 -3819 6753 -4088 10252 -1953 -988 -1327 12824 -7864 -6462 -15400 8216 2723 6987 6161 4251 6587 -1819 7134 5478 6926 -3299 -1823 -2841 2844 8826 -4622 5412 7165 -1469 -1314 -6435 4645 -3028 10543 -3899 11750 -6493 -2639 -7188 327 -4242 -5729 4265 -5969 -1510 3470 12462 -3729 -418 900000 -3240 190 78 8877 -2034 -8038 2211 7357 -4987 1252 60 176 -1037 2690 -10847 -1361 2593 30 -4275 -3645 -3505 2886 7251 -30 12328 -2583 2762 514 -1979 -3848 -3000 3423 -45 -3580 -5772 2020 -6280 6558 -4182 7437 -4030 5032 1330 6850 3897 4415 352 3913 8250 -1512 7013 7251 -7943 7838 -6645 1362 -8414 4088 -5851 -3643 7996 -3916 4103 400 -1872 -4486 -4822 -3393 1381 -5045 -3996 -3080 -3142 3253 7743 -3055 -1454 -659 6796 4900 4093 -5756 -4363 4717 -5038 4181 -6564 8943 589 -835 8852 -543 -5768 2913 -5243 4003 -2131 -7288 -2168 -3405 5406 -3697 8376 -1874 -950 -1260 10389 -7621 -6136 -16203 7021 2502 6257 5613 3959 6021 -1815 6512 5000 6114 -3162 -1695 -2674 2570 7548 -4498 4779 6184 -1379 -1238 -6293 3978 -2743 8258 -3507 9292 -6302 -2505 -7206 307 -4165 -5713 3885 -6040 -1464 3167 10122 -3421 -364 SO 20190201T124511.0Z 6971.531377 445 1 32.01 2 89.15 114.92 72.85 147.57 0.00 1 0.00 1 0 22 3.704e-02 3.757e-02 3.414e-02 3.387e-02 -1.086055e+03 1.739755e+03 2.891283e+01 -6.000000e+00 1.839025e+03 271.77 -2.00 20.00 -2.00 505.27 0.00e+00 2.040064e-03 8.830914e-04 8.956635e-05 -6.000000e+00 9.891950e-04 271.77 -2.00 20.00 -2.00 500.28 0.00e+00 2.485993e+00 6.580257e-01 3.291173e-02 -6.000000e+00 7.183477e-01 224.08 -2.00 3.57 -2.00 501.90 0.00e+00 19.220 0.138 489.00 513.00 1 9.1161e+00 5.0010e-02 3.3187e-02 -6.0000e+00 5.4586e-02 9.5660e-02 1.3386e-02 1.8708e-03 -6.0000e+00 1.4683e-02 1.2106e-05 2.8204e-03 2.5880e-03 2.3840e-05 -6.0000e+00 2.8923e-03 7.7363e-03 -1.4561e-04 12 8 8 10 0 0 72.55 14.99 2.54 0.00774 0.02730 8 1 1 4 0 4000.000 21.69 14.99 18.40 900000 1864 -186 -3677 -3279 -3513 -1306 -234 4377 975 -4202 -119 7306 1652 6906 483 280 -4961 5173 2089 -1384 -5014 -7137 212 487 4487 -331 9047 -877 -6157 -805 2534 1806 -3918 1899 8354 6356 754 -806 -2392 3980 2514 -8501 -2466 1624 -2758 492 -3201 3239 -1930 2002 -2353 -343 -9972 -3341 5099 4205 -3490 1319 2113 199 613 1584 2170 2441 921 81 1905 -3976 5027 -2230 4979 -8923 5407 1998 2078 -2506 1299 3973 -2812 887 3384 1092 2665 306 -6082 826 2045 -2455 3369 4790 -216 6086 -1957 1935 -1530 7183 -3622 -2925 -46 889 -2241 2551 583 -1352 -3797 -2632 4314 54 815 4404 -7425 3163 -6787 5775 2219 401 5432 1349 -8043 -3049 207 -4643 -549 3366 667 478 -322 -8754 6311 -4108 599 4074 346 1062 4782 -1189 1307 -696 1059 775 3945 1491 -493 -3178 1543 -776 -348 -1561 -1340 900000 1697 -178 -3816 -3488 -3813 -1419 -255 4575 1041 -4619 -124 6989 1641 6450 480 281 -5376 5256 2228 -1524 -5716 -8299 230 531 4725 -363 9032 -946 -6685 -803 2445 1781 -4251 2034 8508 6512 803 -860 -2559 3997 2577 -9815 -2720 1743 -3106 535 -3556 3326 -2038 1966 -2334 -327 -10442 -3373 4937 4222 -3816 1373 2165 207 639 1645 2239 2494 939 82 1853 -4057 4626 -2164 4504 -9324 4993 1938 2008 -2470 1203 3545 -2668 813 3060 1016 2445 290 -6207 789 1924 -2406 3126 4400 -211 5727 -2018 1907 -1539 6547 -3580 -2787 -41 782 -2048 2288 557 -1352 -3863 -2594 3885 50 751 4003 -7736 3031 -7271 5514 2201 407 5255 1344 -8608 -3059 198 -4629 -533 3174 645 463 -314 -9216 5776 -4155 567 3646 316 953 4189 -1138 1249 -687 1038 765 3771 1468 -499 -3318 1533 -773 -333 -1467 -1248 SO 20190201T124907.1Z 6971.534110 449 1 32.15 2 88.50 115.61 72.48 148.42 0.00 1 0.00 1 0 15 2.301e-02 2.286e-02 2.109e-02 2.100e-02 9.738413e+02 1.095259e+03 2.666735e+01 -6.000000e+00 1.142005e+03 271.77 -2.00 20.00 -2.00 505.28 0.00e+00 3.139491e-03 5.463409e-04 1.628291e-04 -6.000000e+00 6.138738e-04 271.77 -2.00 20.00 -2.00 500.32 0.00e+00 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