File name: Pandora103s1_Downsview_20190219_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T030100.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190219_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190219T121713.0Z 6989.511956 221 1 32.01 2 89.75 105.96 89.58 288.99 0.00 1 0.00 1 0 15 1.060e-01 9.873e-02 1.074e-01 1.039e-01 2.330761e+03 5.921217e+03 5.170662e+02 -6.000000e+00 5.271653e+03 272.13 -2.00 20.00 -2.00 505.16 0.00e+00 3.456917e-03 2.694462e-03 1.942858e-04 -6.000000e+00 2.831488e-03 272.13 -2.00 20.00 -2.00 499.78 0.00e+00 -1.971794e-01 2.095590e+00 6.853928e-02 -6.000000e+00 2.050745e+00 224.80 -2.00 3.57 -2.00 501.44 0.00e+00 20.390 0.165 489.00 513.00 1 1.0267e+01 1.5965e-01 3.7178e-02 -6.0000e+00 1.5598e-01 2.1653e-01 4.2603e-02 2.1055e-03 -6.0000e+00 4.1686e-02 3.8133e-06 2.3803e-03 7.8143e-03 7.2793e-05 -6.0000e+00 8.2664e-03 4.0986e-02 -2.6923e-04 12 8 8 10 0 0 -7.02 15.00 9.43 0.04099 0.05750 8 1 1 4 0 4000.000 21.69 15.00 18.47 -7234 3992 -9271 -6593 -5559 6516 2549 -6011 14677 5193 3065 -1725 1980 -9275 670 -8328 21321 -496 4255 -10869 -1043 -5304 1687 2875 9527 13582 18352 2057 3798 -10181 -15754 9148 6790 2880 -10773 -3533 -3233 17233 -3173 8492 -4461 -4088 679 -1069 2130 7376 11646 -3257 2631 6694 -2075 -14012 14388 -4193 23613 -3464 11805 732 -3089 3905 -3057 24753 16126 -2767 3919 -11831 -21661 3289 -8514 -2576 -7803 397 4997 -924 -6674 6788 1993 6168 7765 13536 6224 -6941 -2518 7285 -6909 6424 3361 917 -2571 -3854 -8001 3353 14157 -1941 23053 6866 1228 -5967 12302 13490 8560 4358 -10445 -19603 6075 8333 5016 -3978 76 5922 -14984 21290 2020 -14677 5009 -7244 16782 31191 5109 18122 -13821 25578 -5792 17546 -22521 12822 -6248 -1033 -4340 1493 -15122 -6547 -4452 -412 20380 -11419 29138 -1580 17815 -7283 15593 -15103 341 10066 14219 -3968 3154 -1957 -4969 -2830 -7746 3886 -10606 -7662 -6559 6953 2884 -7470 14898 5682 3346 -1945 2117 -10851 704 -9527 18471 -543 4591 -13763 -1194 -6318 1873 3159 9896 13597 17445 2275 4035 -11813 -18700 8535 6582 3020 -13427 -4136 -3715 15993 -3536 8353 -4973 -4575 734 -1193 2333 7712 11624 -3703 2777 6637 -2163 -15896 12179 -4258 18893 -3744 11297 787 -3434 4023 -3361 20949 14914 -3066 4037 -13945 -27496 3229 -9277 -2606 -8164 384 4668 -928 -7194 6381 1912 5547 6807 11163 5511 -7047 -2458 6485 -7139 5884 3165 880 -2536 -3846 -8346 3180 12380 -2000 18418 6283 1162 -5883 9881 10423 6837 3658 -10425 -22392 5566 7430 4532 -3833 69 5146 -16270 16592 1924 -16593 4695 -7660 14158 22983 4791 14682 -14939 18534 -5627 13752 -26202 10571 -6189 -968 -4173 1363 -16105 -6258 -4075 -357 14326 -11042 19590 -1452 13706 -7198 12381 -16097 314 8476 11510 -3798 2752 -1731 -4392 -2435 SO 20190219T122114.0Z 6989.514745 225 1 32.01 2 89.06 106.65 90.25 289.64 0.00 1 0.00 1 0 22 5.658e-02 5.608e-02 5.602e-02 5.500e-02 -5.535600e+03 2.864694e+03 7.205349e+02 -6.000000e+00 2.813100e+03 272.13 -2.00 20.00 -2.00 505.16 0.00e+00 3.170718e-03 1.444600e-03 1.494278e-04 -6.000000e+00 1.510958e-03 272.13 -2.00 20.00 -2.00 499.83 0.00e+00 3.558292e+00 1.096897e+00 4.060268e-02 -6.000000e+00 1.093962e+00 224.80 -2.00 3.57 -2.00 501.50 0.00e+00 19.000 0.134 489.00 513.00 1 9.5519e+00 8.3686e-02 3.2680e-02 -6.0000e+00 8.3216e-02 1.3287e-01 2.2219e-02 1.8161e-03 -6.0000e+00 2.2226e-02 7.3763e-06 2.5491e-03 4.1627e-03 1.0233e-04 -6.0000e+00 4.4111e-03 8.7668e-03 -3.9845e-05 12 8 8 10 0 0 3.49 15.00 5.83 0.00877 0.02645 8 1 1 4 0 4000.000 21.69 15.00 18.47 4174 -13816 -206 -2063 7280 -5810 8841 -2973 8213 2787 111 -5240 -1940 -3745 -864 -7353 2981 -4764 1403 4578 -4467 8715 -7138 12361 979 10579 -2397 5512 -7405 6605 -2967 3464 -1072 5647 1371 6526 -4537 -1068 3300 3080 -11210 -733 3286 -5585 1308 2476 664 -3304 8770 -3700 805 -3116 -333 -5272 3446 118 -5158 1653 4921 9537 1261 10897 4433 3860 -9729 1806 3651 2866 -7280 3214 -2481 9537 -2264 1617 -7125 2166 -3112 7287 -2356 -1755 -6423 2336 1603 -369 6139 -2398 1953 -542 -96 -2900 10231 -1422 -4865 -12168 1490 3111 1097 -11249 2523 902 5896 -846 6674 383 2097 3326 4758 -1381 -6276 -5694 7484 17771 -5107 -2226 244 1745 -2578 4961 -4856 4255 -5738 5800 -2401 7715 9969 -2979 9768 1450 4414 2519 -2258 -971 13258 -5651 -6271 2619 -5199 -8928 2233 5569 -5372 -6184 2099 -7008 9001 -8001 1660 4902 -462 1746 3911 -15642 -211 -2251 7444 -6869 9261 -3534 8745 3080 123 -6052 -2134 -4117 -914 -8286 3068 -5419 1553 4982 -5283 9065 -8644 12408 1108 10926 -2794 5916 -8804 6537 -3127 3432 -1129 5805 1530 6973 -5317 -1191 3474 3210 -13423 -798 3484 -6537 1449 2722 738 -3760 8723 -4053 815 -3172 -323 -5390 3334 122 -5782 1746 5017 9212 1315 10411 4529 3953 -11264 1833 3561 2772 -7683 3007 -2410 8246 -2214 1545 -7512 2071 -3047 6293 -2214 -1631 -6261 2113 1463 -344 5411 -2311 1801 -510 -90 -2801 8728 -1378 -4996 -13615 1458 2984 1066 -12029 2283 804 4931 -760 5708 361 1967 3022 4151 -1249 -5871 -5345 6319 13907 -5116 -2209 239 1688 -2600 4615 -4880 3834 -5626 5031 -2253 6656 8470 -2862 8295 1330 3924 2297 -2147 -893 10374 -5209 -5745 2227 -4919 -8954 2033 4941 -5296 -6126 1929 -7104 7852 -8185 1507 4146 -400 1472 SO 20190219T122511.0Z 6989.517488 229 1 32.01 2 88.37 107.34 90.90 290.29 0.00 1 0.00 1 0 22 3.392e-02 3.308e-02 3.248e-02 3.208e-02 4.888150e+02 1.687337e+03 8.876516e+01 -6.000000e+00 1.686739e+03 272.13 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