File name: Pandora103s1_Downsview_20190313_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T030139.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190313_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190313 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190313T114008.0Z 7011.486204 424 1 32.01 2 89.74 94.31 116.69 17.53 0.00 1 0.00 1 0 22 1.217e-01 1.142e-01 1.102e-01 1.068e-01 -1.114930e+03 5.509105e+03 7.411925e+01 -6.000000e+00 6.090691e+03 273.73 -2.00 20.00 -2.00 505.45 0.00e+00 9.512106e-03 2.826582e-03 5.034505e-04 -6.000000e+00 3.262681e-03 273.73 -2.00 20.00 -2.00 501.00 0.00e+00 4.102275e+00 2.056633e+00 8.278232e-02 -6.000000e+00 2.352579e+00 225.67 -2.00 3.57 -2.00 502.52 0.00e+00 20.341 0.164 489.00 513.00 1 9.8817e+00 1.5716e-01 3.9028e-02 -6.0000e+00 1.7906e-01 -1.5683e-02 4.0430e-02 2.2393e-03 -6.0000e+00 4.7774e-02 3.7612e-06 -7.2074e-04 8.1750e-03 1.2329e-04 -6.0000e+00 9.4893e-03 -3.0810e-02 2.4756e-04 12 8 8 10 0 0 0.36 14.99 11.16 -0.03081 -0.03581 8 1 1 4 0 4000.000 21.69 14.99 18.52 -4303 2221 4248 14470 4156 -5998 9613 12984 14518 -357 10540 9272 -21264 -849 -13489 -2093 -1866 11923 -2143 -14600 -10777 11809 -17598 -3335 12707 11015 5990 -1910 -3561 -10573 9175 -1285 19438 -474 -4206 11193 5371 -8426 21649 -6151 22101 -15576 23213 13873 1279 -3497 2594 7210 -6374 8561 -5912 25448 -10215 4929 -14258 42330 5772 16701 -7529 -7264 -572 18721 -15539 14263 -2275 6283 11488 -5952 -796 10629 2004 -17022 -3618 6724 -4834 -5999 7600 -7038 -7406 -20493 5290 -9851 8494 -13242 28600 -3818 513 -4056 29182 9995 10054 1224 -7943 7470 -11080 15050 -8925 31203 2606 4921 -16934 22902 -11814 -1508 -9242 -216 9560 12311 6085 -3266 -11195 26337 -5540 11318 -2289 11282 -11637 5502 18407 3043 7241 1668 22390 -21859 8652 -13947 10451 13371 4451 -4575 -677 -1652 14085 -2450 9445 -6140 7214 4534 -5472 10101 -18923 -862 5988 -1975 6560 1292 9537 6242 -19112 15215 -3696 1814 3530 11416 3741 -6074 8567 11360 12527 -350 9107 7998 -24282 -783 -13912 -1932 -1733 9898 -2103 -16461 -11673 10279 -20385 -3384 11202 9985 5705 -1959 -3648 -11098 7689 -1190 14977 -460 -4437 10333 5185 -9167 17448 -6435 17696 -18210 19029 12689 1346 -3895 2728 7181 -7140 8149 -6278 19411 -10816 4520 -16194 29058 5807 15331 -8744 -8373 -617 16925 -19719 13578 -2526 6323 10774 -6502 -819 9645 1941 -19779 -3723 6343 -5178 -6481 7032 -7321 -7655 -23928 4814 -10461 7573 -14538 21117 -3877 498 -4089 21221 8740 8831 1191 -8699 7203 -12793 13383 -9900 22996 2455 4397 -18308 16868 -12406 -1487 -10038 -213 8403 10333 5370 -3199 -12191 20553 -6049 10743 -2512 10950 -14202 5701 16680 3143 7087 1703 18683 -28448 8505 -17123 10188 12694 4605 -5213 -744 -1798 12893 -2592 8821 -6738 7165 4727 -6364 10207 -25416 -971 6343 -2281 7020 1450 9682 6317 -24013 13664 SO 20190313T114421.0Z 7011.489132 428 1 32.01 2 88.98 95.04 116.46 18.56 0.00 1 0.00 1 0 22 1.686e-01 1.480e-01 1.466e-01 1.386e-01 1.773237e+03 7.839460e+03 2.140695e+02 -6.000000e+00 8.436812e+03 273.73 -2.00 20.00 -2.00 505.35 0.00e+00 7.668415e-03 3.684360e-03 3.431859e-04 -6.000000e+00 4.526618e-03 273.73 -2.00 20.00 -2.00 500.23 0.00e+00 5.921711e+00 2.746751e+00 1.032927e-01 -6.000000e+00 3.282479e+00 225.67 -2.00 3.57 -2.00 501.86 0.00e+00 18.797 0.129 489.00 513.00 1 1.0246e+01 2.1122e-01 3.3854e-02 -6.0000e+00 2.4936e-01 1.3201e-02 5.4683e-02 2.3120e-03 -6.0000e+00 6.7356e-02 2.8456e-06 6.4489e-03 1.0423e-02 1.0331e-04 -6.0000e+00 1.3175e-02 3.3883e-02 -5.5048e-04 12 8 8 10 0 0 -2.77 15.00 5.92 0.03388 0.07862 8 1 1 4 0 4000.000 21.69 15.00 18.53 900000 2050 -4966 23497 -22350 13923 -6294 -1439 17529 27074 10150 19794 -12863 21861 8905 3508 14223 13895 -461 -863 411 -777 -8701 -22810 6269 -14487 20511 4730 3197 -6904 21600 12249 21970 8399 -13085 13467 -14887 5900 -1860 -102 -21438 -8916 -5823 3847 -3306 7527 27012 4363 -2584 9262 -8499 -9713 -18633 26168 2367 32296 340 18925 15698 2570 3363 25573 12271 9123 -3139 -19444 24974 -7085 59823 -8991 -5842 -14709 -7039 -706 -24 -20465 13863 -1839 7347 -6745 5239 -39565 41165 15449 994 -5314 -4732 30794 9992 4013 -11497 2395 -23281 33437 -981 19828 5749 -850 -17577 68122 -9634 1412 -2249 26942 -17508 28666 -2643 12458 12646 2405 2310 1285 119 -8330 31142 -15150 41856 12502 3154 979 10072 -4458 8339 7067 9590 3180 -12683 98 -6227 3897 6255 11694 -15714 13174 -8521 2452 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88.22 95.78 116.21 19.60 0.00 1 0.00 1 0 8 8.944e-02 8.711e-02 9.165e-02 8.963e-02 -7.374367e+02 4.724632e+03 5.232826e+02 -6.000000e+00 4.476573e+03 273.73 -2.00 20.00 -2.00 505.25 0.00e+00 5.615620e-03 2.365231e-03 2.579361e-04 -6.000000e+00 2.399678e-03 273.73 -2.00 20.00 -2.00 500.07 0.00e+00 4.093988e+00 1.770163e+00 9.983083e-02 -6.000000e+00 1.736104e+00 225.68 -2.00 3.57 -2.00 501.71 0.00e+00 16.765 0.092 489.00 513.00 1 1.0261e+01 1.3541e-01 2.8315e-02 -6.0000e+00 1.3198e-01 7.0670e-02 3.5635e-02 1.8502e-03 -6.0000e+00 3.5497e-02 4.5022e-06 1.6084e-03 6.8403e-03 9.3507e-05 -6.0000e+00 6.9843e-03 1.3630e-02 -1.8137e-04 12 8 8 10 0 0 92.30 15.00 3.68 0.01363 0.02479 8 1 1 4 0 4000.000 21.69 15.00 18.53 900000 -10878 6327 -10130 7793 4315 -11659 265 355 4656 10560 -3004 -21335 9433 -2263 -2689 -2511 9128 15318 29860 -8944 4035 1273 1809 -1210 -14745 14084 2525 -5531 -1659 14220 -3559 3588 -9833 -2820 -2816 3968 12277 -475 -1470 9916 3738 -6271 5103 6595 -9240 -1948 12046 -1295 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